论文信息 - Synthesis and reactions of novel boron-phosphorus compounds - 字舞流文

Synthesis and reactions of novel boron-phosphorus compounds

Abstract Treatment of RBX2 with two equivalents of LiPHR', has resulted in the isolation and characterization of boron-phosphorus analogues of borazine as illustrated.

H. V. Rasika Dias | P. Power | M. Petrie | D. Pestana

[1] H. V. Rasika Dias,et al. Synthesis and spectroscopic and structural characterization of the monomeric diborylphosphine and diphosphinoborane compounds PhP(BMes2)2 and MesB(PPh2)2 (Mes=2,4,6-Me3C6H2) , 1988 .

[2] P. Power,et al. The structure of a monomeric phosphinoborane: synthesis and x-ray crystal structure of (diphenylphosphino)dimesitylborane , 1986 .

[3] P. Power,et al. Synthesis and characterization of the phosphinidene borate complexes [Li(Et2O)2PRB(Mes)2] and [Li(12-crown-4)2][RPB(Mes)2].cntdot.THF [R = Ph, C6H11 or Mes (Mes = 2,4,6-Me3C6H2)]: the first structurally characterized boron-phosphorus double bonds , 1986 .

[4] J. E. Boggs,et al. Production of a boraphosphene (RB:PR') in the vapor phase by thermolysis of a sterically encumbered diphosphadiboretane. , 1986, Journal of the American Chemical Society.

[5] H. Nöth,et al. Beiträge zur Chemie des Bors, 170. Synthese und Struktur eines 1,3,2,4‐Diphosphadiboretans , 1986 .

[6] A. Stock,et al. Borwasserstoffe, IX.: B3N3H6 , 1926 .

[7] H. V. Rasika Dias,et al. Boron-phosphorus analogs of benzene and cyclobutadiene. Synthesis and characterization of the boraphosphabenzenes (RBPR')3 (R = Mes, Ph; R' = Ph, Mes, C6H11, tert-Bu) and the diphosphadiboretane (thexylBPMes)2 , 1989 .