Numerical simulations of self-propelled jumping upon drop coalescence on non-wetting surfaces

Abstract Coalescing drops spontaneously jump out of plane on a variety of biological and synthetic superhydrophobic surfaces, with potential applications ranging from self-cleaning materials to self-sustained condensers. To investigate the mechanism of self-propelled jumping, we report three-dimensional phase-field simulations of two identical spherical drops coalescing on a flat surface with a contact angle of 180°. The numerical simulations capture the spontaneous jumping process, which follows the capillary–inertial scaling. The out-of-plane directionality is shown to result from the counter-action of the substrate to the impingement of the liquid bridge between the coalescing drops. A viscous cutoff to the capillary–inertial velocity scaling is identified when the Ohnesorge number of the initial drops is around 0.1, but the corresponding viscous cutoff radius is too small to be tested experimentally. Compared to experiments on both superhydrophobic and Leidenfrost surfaces, our simulations accurately predict the nearly constant jumping velocity of around 0.2 when scaled by the capillary–inertial velocity. By comparing the simulated drop coalescence processes with and without the substrate, we attribute this low non-dimensional velocity to the substrate intercepting only a small fraction of the expanding liquid bridge.

[1]  Y. Shikhmurzaev,et al.  Coalescence of liquid drops: Different models versus experiment , 2012, 1211.7212.

[2]  Zhong Lan,et al.  Analysis of droplet jumping phenomenon with lattice Boltzmann simulation of droplet coalescence , 2013 .

[3]  E. Benilov,et al.  Contact lines with a $18{0}^{\circ } $ contact angle , 2013, Journal of Fluid Mechanics.

[4]  J. Yeomans,et al.  Drop dynamics on hydrophobic and superhydrophobic surfaces. , 2010, Faraday discussions.

[5]  Xuemei Chen,et al.  Multimode multidrop serial coalescence effects during condensation on hierarchical superhydrophobic surfaces. , 2013, Langmuir : the ACS journal of surfaces and colloids.

[6]  E. Trinh,et al.  Large-amplitude free and driven drop-shape oscillations: experimental observations , 1982, Journal of Fluid Mechanics.

[7]  Jolanta A Watson,et al.  Self-cleaning of superhydrophobic surfaces by self-propelled jumping condensate , 2013, Proceedings of the National Academy of Sciences.

[8]  David Quéré,et al.  Non-sticking drops , 2005 .

[9]  Hors Equilibre,et al.  Maximal deformation of an impacting drop , 2004 .

[10]  James J. Feng,et al.  Self-propelled jumping upon drop coalescence on Leidenfrost surfaces , 2014, Journal of Fluid Mechanics.

[11]  J. E. Hilliard,et al.  Free Energy of a Nonuniform System. I. Interfacial Free Energy and Free Energy of a Nonuniform System. III. Nucleation in a Two‐Component Incompressible Fluid , 2013 .

[12]  Evelyn N Wang,et al.  Effect of droplet morphology on growth dynamics and heat transfer during condensation on superhydrophobic nanostructured surfaces. , 2012, ACS nano.

[13]  Osman A. Basaran,et al.  Nonlinear oscillations of viscous liquid drops , 1992, Journal of Fluid Mechanics.

[14]  J. Boreyko,et al.  Self-propelled dropwise condensate on superhydrophobic surfaces. , 2009, Physical review letters.

[15]  Shuhuai Yao,et al.  Why condensate drops can spontaneously move away on some superhydrophobic surfaces but not on others. , 2012, ACS applied materials & interfaces.

[16]  S. Zaleski,et al.  Coalescence of liquid drops by surface tension. , 2001, Physical review. E, Statistical, nonlinear, and soft matter physics.

[17]  John R. Lister,et al.  Coalescence of liquid drops , 1999, Journal of Fluid Mechanics.

[18]  J. Boreyko,et al.  Self-propelled jumping drops on superhydrophobic surfaces , 2010 .

[19]  P. Hao,et al.  Condensation and jumping relay of droplets on lotus leaf , 2013, 1305.2032.

[20]  Daniel Beysens,et al.  Coalescence of sessile drops , 2002, Journal of Fluid Mechanics.

[21]  Zhifeng Ren,et al.  Dropwise condensation on superhydrophobic surfaces with two-tier roughness , 2007 .

[22]  P. Gaskell,et al.  Morphology and dynamics of droplet coalescence on a surface. , 2007, Physical review. E, Statistical, nonlinear, and soft matter physics.

[23]  Evelyn N Wang,et al.  Jumping-droplet-enhanced condensation on scalable superhydrophobic nanostructured surfaces. , 2012, Nano letters.

[24]  H. Stone,et al.  Coalescence of spreading droplets on a wettable substrate. , 2005, Physical review letters.

[25]  R. A. Wentzell,et al.  Hydrodynamic and Hydromagnetic Stability. By S. CHANDRASEKHAR. Clarendon Press: Oxford University Press, 1961. 652 pp. £5. 5s. , 1962, Journal of Fluid Mechanics.

[26]  C. Clanet,et al.  Dynamical superhydrophobicity. , 2010, Faraday discussions.

[27]  J. Chen,et al.  Anti-icing surfaces based on enhanced self-propelled jumping of condensed water microdroplets. , 2013, Chemical communications.

[28]  E. Wang,et al.  Condensation heat transfer on superhydrophobic surfaces , 2013 .

[29]  James J. Feng,et al.  Simulations of the breakup of liquid filaments on a partially wetting solid substrate , 2012 .

[30]  Chung King Law,et al.  Regimes of coalescence and separation in droplet collision , 1997, Journal of Fluid Mechanics.

[31]  Andrei G. Fedorov,et al.  Visualization of droplet departure on a superhydrophobic surface and implications to heat transfer enhancement during dropwise condensation , 2010 .

[32]  Chunfeng Zhou,et al.  A computational study of the coalescence between a drop and an interface in Newtonian and viscoelastic fluids , 2006 .

[33]  James J. Feng,et al.  Enhanced slip on a patterned substrate due to depinning of contact line , 2009 .

[34]  J. Boreyko,et al.  Vapor chambers with jumping-drop liquid return from superhydrophobic condensers , 2013 .

[35]  D. Lohse,et al.  Microscopic structure influencing macroscopic splash at high Weber number , 2011 .

[36]  James J. Feng,et al.  A diffuse-interface method for simulating two-phase flows of complex fluids , 2004, Journal of Fluid Mechanics.

[37]  Robert Forchheimer,et al.  Rebounding Droplet‐Droplet Collisions on Superhydrophobic Surfaces: from the Phenomenon to Droplet Logic , 2012, Advanced materials.

[38]  Carsten Werner,et al.  Smart Skin Patterns Protect Springtails , 2011, PloS one.

[39]  P. Collier,et al.  Delayed frost growth on jumping-drop superhydrophobic surfaces. , 2013, ACS nano.

[40]  Lei Jiang,et al.  Hierarchically structured porous aluminum surfaces for high-efficient removal of condensed water , 2012 .

[41]  Seungwon Shin,et al.  Energy and hydrodynamic analyses of coalescence-induced jumping droplets , 2013 .

[42]  Evelyn N Wang,et al.  Condensation on superhydrophobic surfaces: the role of local energy barriers and structure length scale. , 2012, Langmuir : the ACS journal of surfaces and colloids.

[43]  Melissa Orme,et al.  EXPERIMENTS ON DROPLET COLLISIONS, BOUNCE, COALESCENCE AND DISRUPTION , 1997 .

[44]  Ronald J. Adrian,et al.  Leidenfrost Dynamics , 2013 .

[45]  T. Etoh,et al.  The coalescence speed of a pendent and a sessile drop , 2005, Journal of Fluid Mechanics.

[46]  Y. Pomeau,et al.  Take off of small Leidenfrost droplets. , 2012, Physical review letters.

[47]  J. E. Hilliard,et al.  Free Energy of a Nonuniform System. I. Interfacial Free Energy , 1958 .

[48]  Chunfeng Zhou,et al.  3D phase-field simulations of interfacial dynamics in Newtonian and viscoelastic fluids , 2010, J. Comput. Phys..

[49]  D. Quéré,et al.  Bouncing water drops , 2000 .

[50]  U. Grigull,et al.  Über das Abspringen von Tropfen bei der Kondensation von Quecksilber , 1969 .

[51]  Xiaojun Quan,et al.  Lattice Boltzmann simulations for self-propelled jumping of droplets after coalescence on a superhydrophobic surface , 2014 .

[52]  L. Scriven,et al.  Hydrodynamic Model of Steady Movement of a Solid / Liquid / Fluid Contact Line , 1971 .

[53]  W. H. Reid The oscillations of a viscous liquid drop , 1960 .

[54]  L. Rayleigh On the Capillary Phenomena of Jets , 1879 .

[55]  Ya-Pu Zhao,et al.  Size effect on the coalescence-induced self-propelled droplet , 2011 .

[56]  Chunfeng Zhou,et al.  Phase-field simulations of interfacial dynamics in viscoelastic fluids using finite elements with adaptive meshing , 2006, J. Comput. Phys..

[57]  Sam S. Yoon,et al.  Coalescence of two drops on partially wettable substrates. , 2012, Langmuir : the ACS journal of surfaces and colloids.

[58]  Sidney R Nagel,et al.  Viscous to inertial crossover in liquid drop coalescence. , 2010, Physical review letters.

[59]  Michael A. Nilsson,et al.  The effect of contact angle hysteresis on droplet coalescence and mixing. , 2011, Journal of colloid and interface science.

[60]  S. Yao,et al.  How nanorough is rough enough to make a surface superhydrophobic during water condensation , 2012 .

[61]  Ying Zhang Coalescence of Sessile Drops: the Role of Gravity, Interfacial Tension and Surface Wettability , 2016 .

[62]  Jiangtao Cheng,et al.  Condensation heat transfer on two-tier superhydrophobic surfaces , 2012 .

[63]  Yuejun Zhao,et al.  Planar Jumping-Drop Thermal Diodes , 2011 .

[64]  C. Béguin,et al.  Maximal deformation of an impacting drop , 2004, Journal of Fluid Mechanics.

[65]  Chunfeng Zhou,et al.  Spontaneous shrinkage of drops and mass conservation in phase-field simulations , 2007, J. Comput. Phys..

[66]  Wei Sun,et al.  Mechanism study of condensed drops jumping on super-hydrophobic surfaces , 2012 .

[67]  Jolanta A Watson,et al.  A dual layer hair array of the brown lacewing: repelling water at different length scales. , 2011, Biophysical journal.