Writing monolithic integrated circuits on a two-dimensional semiconductor with a scanning light probe

The development of complex electronics based on two-dimensional (2D) materials will require the integration of a large number of 2D devices into circuits. However, a practical method of assembling such devices into integrated circuits remains elusive. Here we show that a scanning visible light probe can be used to directly write electrical circuitry onto the 2D semiconductor molybdenum ditelluride (2H-MoTe2). Laser light illumination over metal patterns deposited onto 2D channels of 2H-MoTe2 can convert the channels from an n-type semiconductor to a p-type semiconductor, by creating adatom–vacancy clusters in the host lattice. With this process, diffusive doping profiles can be controlled at the submicrometre scale and doping concentrations can be tuned, allowing the channel sheet resistance to be varied over four orders of magnitudes. Our doping method can be used to assemble both n- and p-doped channels within the same atomic plane, which allows us to fabricate 2D device arrays of n–p–n (p–n–p) bipolar junction transistor amplifiers and radial p–n photovoltaic cells.A laser can be used to locally dope two-dimensional molybdenum ditelluride channels, allowing both n- and p-doped channels to be assembled within the same atomic plane and for device arrays of n–p–n bipolar junction transistor amplifiers and radial p–n photovoltaic cells to be fabricated.

[1]  I. Musevic,et al.  STM/AFM investigations of β-MoTe2, α-MoTe2 and WTe2 , 1996 .

[2]  A. Radenović,et al.  Single-layer MoS2 transistors. , 2011, Nature nanotechnology.

[3]  N. Peres,et al.  Field-Effect Tunneling Transistor Based on Vertical Graphene Heterostructures , 2011, Science.

[4]  Timothy C. Berkelbach,et al.  Grains and grain boundaries in highly crystalline monolayer molybdenum disulphide. , 2013, Nature Materials.

[5]  K. Novoselov,et al.  Strong Light-Matter Interactions in Heterostructures of Atomically Thin Films , 2013, Science.

[6]  J. Grossman,et al.  Broad-range modulation of light emission in two-dimensional semiconductors by molecular physisorption gating. , 2013, Nano letters.

[7]  SUPARNA DUTTASINHA,et al.  Van der Waals heterostructures , 2013, Nature.

[8]  Jing Guo,et al.  Degenerate n-doping of few-layer transition metal dichalcogenides by potassium. , 2013, Nano letters.

[9]  M. Jo,et al.  Atomic layer-by-layer thermoelectric conversion in topological insulator bismuth/antimony tellurides. , 2014, Nano letters.

[10]  Wilman Tsai,et al.  Chloride molecular doping technique on 2D materials: WS2 and MoS2. , 2014, Nano letters.

[11]  T. Mueller,et al.  Solar-energy conversion and light emission in an atomic monolayer p-n diode. , 2013, Nature Nanotechnology.

[12]  Gautam Gupta,et al.  Phase-engineered low-resistance contacts for ultrathin MoS2 transistors. , 2014, Nature materials.

[13]  Jun Lou,et al.  Vertical and in-plane heterostructures from WS2/MoS2 monolayers. , 2014, Nature materials.

[14]  J. Idrobo,et al.  Heteroepitaxial Growth of Two-Dimensional Hexagonal Boron Nitride Templated by Graphene Edges , 2014, Science.

[15]  P. Jarillo-Herrero,et al.  Optoelectronic devices based on electrically tunable p-n diodes in a monolayer dichalcogenide. , 2013, Nature nanotechnology.

[16]  A. M. van der Zande,et al.  Atomically thin p-n junctions with van der Waals heterointerfaces. , 2014, Nature nanotechnology.

[17]  Myoung-Jae Lee,et al.  Rotation‐Misfit‐Free Heteroepitaxial Stacking and Stitching Growth of Hexagonal Transition‐Metal Dichalcogenide Monolayers by Nucleation Kinetics Controls , 2015, Advanced materials.

[18]  Myoung-Jae Lee,et al.  Interlayer orientation-dependent light absorption and emission in monolayer semiconductor stacks , 2015, Nature Communications.

[19]  A. Suslu,et al.  Environmental Changes in MoTe2 Excitonic Dynamics by Defects-Activated Molecular Interaction. , 2015, ACS nano.

[20]  Pinshane Y. Huang,et al.  High-mobility three-atom-thick semiconducting films with wafer-scale homogeneity , 2015, Nature.

[21]  E. Pop,et al.  Bright visible light emission from graphene. , 2015, Nature nanotechnology.

[22]  Jr-hau He,et al.  Epitaxial growth of a monolayer WSe2-MoS2 lateral p-n junction with an atomically sharp interface , 2015, Science.

[23]  Junsong Yuan,et al.  Exploring atomic defects in molybdenum disulphide monolayers , 2015, Nature Communications.

[24]  Suyeon Cho,et al.  Phase patterning for ohmic homojunction contact in MoTe2 , 2015, Science.

[25]  Moon-Ho Jo,et al.  Thermoelectric materials by using two-dimensional materials with negative correlation between electrical and thermal conductivity , 2016, Nature Communications.

[26]  Point Defects and Grain Boundaries in Rotationally Commensurate MoS2 on Epitaxial Graphene , 2016, 1604.00682.

[27]  G. Eda,et al.  Effect of oxygen and ozone on p-type doping of ultra-thin WSe2 and MoSe2 field effect transistors. , 2016, Physical chemistry chemical physics : PCCP.

[28]  D. Muller,et al.  Large-scale chemical assembly of atomically thin transistors and circuits. , 2016, Nature nanotechnology.

[29]  M. Jo,et al.  1s-intraexcitonic dynamics in monolayer MoS2 probed by ultrafast mid-infrared spectroscopy , 2016, Nature Communications.

[30]  Alexander W. Holleitner,et al.  Contact morphology and revisited photocurrent dynamics in monolayer MoS2 , 2017, npj 2D Materials and Applications.

[31]  Hyeong Rae Noh,et al.  Coplanar semiconductor-metal circuitry defined on few-layer MoTe2 via polymorphic heteroepitaxy. , 2017, Nature nanotechnology.

[32]  R. Ruoff,et al.  Carrier‐Type Modulation and Mobility Improvement of Thin MoTe2 , 2017, Advances in Materials.

[33]  Wei Ji,et al.  Defect Structure of Localized Excitons in a WSe_{2} Monolayer. , 2017, Physical review letters.

[34]  Kazuhito Tsukagoshi,et al.  Reversible and Precisely Controllable p/n‐Type Doping of MoTe2 Transistors through Electrothermal Doping , 2018, Advanced materials.