Hydroelectric power plant on a paper strip.

We exploit the combinatorial advantage of electrokinetics and tortuosity of a cellulose-based paper network on laboratory grade filter paper for the development of a simple, inexpensive, yet extremely robust (shows constant performance for 12 days) 'paper-and-pencil'-based device for energy harvesting applications. We successfully achieve harvesting of a maximum output power of ∼640 pW in a single channel, while the same is significantly improved (by ∼100 times) with the use of a multichannel microfluidic array (maximum of up to 20 channels). Furthermore, we also provide theoretical insights into the observed phenomenon and show that the experimentally predicted trends agree well with our theoretical calculations. Thus, we envisage that such ultra-low cost devices may turn out to be extremely useful in energizing analytical microdevices in resource limited settings, for instance, in extreme point of care diagnostic applications.

[1]  C. Dekker,et al.  Streaming currents in a single nanofluidic channel. , 2005, Physical review letters.

[2]  Orawon Chailapakul,et al.  Electrochemical detection of glucose from whole blood using paper-based microfluidic devices. , 2013, Analytica chimica acta.

[3]  A. Mansouri,et al.  Transient streaming potential in a finite length microchannel. , 2005, Journal of colloid and interface science.

[4]  Lei Jiang,et al.  Energy Harvesting with Single‐Ion‐Selective Nanopores: A Concentration‐Gradient‐Driven Nanofluidic Power Source , 2010 .

[5]  Shantimoy Kar,et al.  Capillarity-driven blood plasma separation on paper-based devices. , 2015, The Analyst.

[6]  S. Kjelstrup,et al.  Evaluation of Nanoporous Polymer Membranes for Electrokinetic Energy Conversion in Power Applications , 2013 .

[7]  Tae-Hyeong Kim,et al.  Paper on a disc: balancing the capillary-driven flow with a centrifugal force. , 2011, Lab on a chip.

[8]  K. Mawatari,et al.  Streaming potential/current measurement system for investigation of liquids confined in extended-nanospace. , 2010, Lab on a chip.

[9]  S. Chakraborty,et al.  Giant augmentations in electro-hydro-dynamic energy conversion efficiencies of nanofluidic devices using viscoelastic fluids , 2012 .

[10]  Scott T. Phillips,et al.  "Fluidic batteries" as low-cost sources of power in paper-based microfluidic devices. , 2012, Lab on a chip.

[11]  George M Whitesides,et al.  Electrochemical sensing in paper-based microfluidic devices. , 2010, Lab on a chip.

[12]  Shantimoy Kar,et al.  Microfluidics-based Low-Cost Medical Diagnostic Devices: Some Recent Developments , 2016 .

[13]  J. S. Pedersen,et al.  High electrokinetic energy conversion efficiency in charged nanoporous nitrocellulose/sulfonated polystyrene membranes. , 2015, Nano letters.

[14]  C. Dekker,et al.  Power generation by pressure-driven transport of ions in nanofluidic channels. , 2007, Nano letters.

[15]  A. Bhardwaj,et al.  In situ click chemistry generation of cyclooxygenase-2 inhibitors , 2017, Nature Communications.

[16]  Meng Zhang,et al.  Three-dimensional paper-based electrochemiluminescence device for simultaneous detection of Pb2+ and Hg2+ based on potential-control technique. , 2013, Biosensors & bioelectronics.

[17]  M Safdar,et al.  Microfluidic fuel cells for energy generation. , 2016, Lab on a chip.

[18]  J. Eijkel,et al.  Filling of charged cylindrical capillaries. , 2014, Physical review. E, Statistical, nonlinear, and soft matter physics.

[19]  N. Zhang,et al.  A paper triboelectric nanogenerator for self-powered electronic systems. , 2017, Nanoscale.

[20]  Basile F. E. Curchod,et al.  Dye-sensitized solar cells with 13% efficiency achieved through the molecular engineering of porphyrin sensitizers. , 2014, Nature chemistry.

[21]  Miao Xu,et al.  Enhanced power-conversion efficiency in polymer solar cells using an inverted device structure , 2012, Nature Photonics.

[22]  Dennis Desheng Meng,et al.  Micropumping of liquid by directional growth and selective venting of gas bubbles. , 2008, Lab on a chip.

[23]  J. Lewis,et al.  Pen‐on‐Paper Flexible Electronics , 2011, Advanced materials.

[24]  D. Gillespie High energy conversion efficiency in nanofluidic channels. , 2012, Nano letters.

[25]  J. Eijkel,et al.  Highly enhanced energy conversion from the streaming current by polymer addition. , 2013, Lab on a chip.

[26]  Jun Zhou,et al.  Water-evaporation-induced electricity with nanostructured carbon materials. , 2017, Nature nanotechnology.

[27]  S. Jang,et al.  Simple and rapid fabrication of pencil-on-paper triboelectric nanogenerators with enhanced electrical performance. , 2017, Nanoscale.

[28]  Xiao Wang,et al.  Paper pump for passive and programmable transport. , 2013, Biomicrofluidics.

[29]  Arash Abadian,et al.  Paper-based digital microfluidics , 2014 .

[30]  Sharifah Rafidah Wan Alwi,et al.  A review on utilisation of biomass from rice industry as a source of renewable energy , 2012 .

[31]  A. Steckl,et al.  Electrowetting on paper for electronic paper display. , 2010, ACS applied materials & interfaces.

[32]  Kang Liu,et al.  Capillary driven electrokinetic generator for environmental energy harvesting , 2017 .

[33]  Charles S Henry,et al.  Development of a paper-based analytical device for colorimetric detection of select foodborne pathogens. , 2012, Analytical chemistry.

[34]  Zhong Lin Wang,et al.  Ultralight Cut-Paper-Based Self-Charging Power Unit for Self-Powered Portable Electronic and Medical Systems. , 2017, ACS nano.

[35]  Saurav Halder,et al.  A paper based self-pumping and self-breathing fuel cell using pencil stroked graphite electrodes. , 2014, Lab on a chip.

[36]  Seok-woo Hong,et al.  Dynamics of water imbibition through paper channels with wax boundaries , 2015 .

[37]  V. Remcho,et al.  Detection of water contamination from hydraulic fracturing wastewater: a μPAD for bromide analysis in natural waters. , 2015, The Analyst.

[38]  Sumit Joshi,et al.  Ultra-low-cost ‘paper-and-pencil’ device for electrically controlled micromixing of analytes , 2015 .

[39]  Fei Li,et al.  Advances in paper-based point-of-care diagnostics. , 2014, Biosensors & bioelectronics.

[40]  C. Xie,et al.  Establishing and storing of deterministic quantum entanglement among three distant atomic ensembles , 2017, Nature Communications.

[41]  Wai Ho Li,et al.  Uniform mixing in paper-based microfluidic systems using surface acoustic waves. , 2012, Lab on a chip.

[42]  G. Whitesides,et al.  Foldable Printed Circuit Boards on Paper Substrates , 2010 .

[43]  Debabrata Das,et al.  Instant power generation from an air-breathing paper and pencil based bacterial bio-fuel cell. , 2015, Lab on a chip.

[44]  S. Chakraborty,et al.  Electrokinetic energy conversion in nanofluidic channels: Addressing the loose ends in nanodevice efficiency , 2014, Electrophoresis.

[45]  G. Whitesides,et al.  Patterned paper as a platform for inexpensive, low-volume, portable bioassays. , 2007, Angewandte Chemie.

[46]  Neus Sabaté,et al.  Single-use paper-based hydrogen fuel cells for point-of-care diagnostic applications , 2017 .

[47]  Suman Chakraborty,et al.  Electrokinetics with "paper-and-pencil" devices. , 2012, Lab on a chip.