A review of BiPO4, a highly efficient oxyacid-type photocatalyst, used for environmental applications

Semiconductor photocatalysts used for environmental applications have attracted a lot of attention due to their ability to completely convert pollutants into CO2 and H2O. For a simple and economical treatment, more efficient photocatalysts are highly desired compared to widely used TiO2. A non-metallic oxyacid type photocatalyst, BiPO4, was first discovered by the author's group and is now commonly accepted as a superior photocatalyst compared to TiO2 in the UV region. Because of its excellence, this paper has reviewed the recent progress on BiPO4, specifically on the efforts from the author's group, including the preparation as well as the modification methods involved in activity enhancement. The description of the physical properties and typical degradation pathways of the photocatalyst are also given for better comprehension of the origin of its high activity. Furthermore, as a represented non-metallic oxyacid photocatalyst, research into BiPO4 will offer guidelines for designing effective photocatalysts of the same type for environmental applications.

[1]  S. Yin,et al.  Hydrothermal Synthesis and Photocatalytic Properties of BiPO4/Ag3PO4 Heterostructure for Phenol Decomposition , 2014 .

[2]  Julián Blanco,et al.  Photocatalysis with solar energy at a pilot-plant scale: an overview , 2002 .

[3]  Wenzhong Wang,et al.  Role of graphene on the surface chemical reactions of BiPO4-rGO with low OH-related defects. , 2013, Nanoscale.

[4]  Shicheng Zhang,et al.  Electron spin resonance spin-trapping detection of radical intermediates in N-doped TiO2-assisted photodegradation of 4-chlorophenol. , 2006, The journal of physical chemistry. B.

[5]  Xiujian Zhao,et al.  Tuning the relative concentration ratio of bulk defects to surface defects in TiO2 nanocrystals leads to high photocatalytic efficiency. , 2011, Journal of the American Chemical Society.

[6]  Zheng Xu,et al.  A Host Crystal for the Rare-Earth Ion Dopants: Synthesis of Pure and Ln-Doped Urchinlike BiPO4 Structure and Its Photoluminescence , 2008 .

[7]  Yongfa Zhu,et al.  Enhanced Photocatalytic Performance for the BiPO4–x Nanorod Induced by Surface Oxygen Vacancy , 2013 .

[8]  Yong Zhu,et al.  Degradation and mineralization mechanism of phenol by BiPO4 photocatalysis assisted with H2O2 , 2013 .

[9]  Z. Li,et al.  Template-free hydrothermal synthesis and photocatalytic performances of novel Bi2SiO5 nanosheets. , 2009, Inorganic chemistry.

[10]  Yueping Fang,et al.  Novel mesoporous g-C3N4 and BiPO4 nanorods hybrid architectures and their enhanced visible-light-driven photocatalytic performances , 2014 .

[11]  Limin Chang,et al.  Fabrication and efficient visible light-induced photocatalytic activity of Bi2MoO6/BiPO4 composite , 2015 .

[12]  Liping Li,et al.  pH-driven hydrothermal synthesis and formation mechanism of all BiPO4 polymorphs , 2012 .

[13]  R. C. L. Mooney-Slater Polymorphic forms of bismuth phosphate , 1962 .

[14]  Jianjun Liu,et al.  Electronic structure and optical properties of Ag3PO4 photocatalyst calculated by hybrid density functional method , 2011 .

[15]  Jing Cao,et al.  Ag3PO4 quantum dot sensitized BiPO4: A novel p–n junction Ag3PO4/BiPO4 with enhanced visible-light photocatalytic activity , 2013 .

[16]  M. Vicente,et al.  Phenol degradation in water through a heterogeneous photo-Fenton process catalyzed by Fe-treated laponite. , 2009, Water research.

[17]  Yiying Wu,et al.  Preparation, characterization and enhanced visible-light photocatalytic activities of BiPO4/BiVO4 composites , 2013 .

[18]  Stavros G. Demos,et al.  Electronic structure calculations of an oxygen vacancy in KH2PO4 , 2005 .

[19]  Jincai Zhao,et al.  Dramatic visible photocatalytic degradation performances due to synergetic effect of TiO2 with PANI. , 2008, Environmental science & technology.

[20]  M. Gholami,et al.  A novel p–n junction Ag 3 PO 4 /BiPO 4 -based stabilized Pickering emulsion for highly efficient photocatalysis , 2015 .

[21]  Yongfa Zhu,et al.  Influence of OH-related defects on the performances of BiPO4 photocatalyst for the degradation of rhodamine B , 2012 .

[22]  Patrick Drogui,et al.  Modified TiO2 For Environmental Photocatalytic Applications: A Review , 2013 .

[23]  Yihe Zhang,et al.  Two Bi-based phosphate photocatalysts: Crystal structure, optical property and photocatalytic activity , 2014 .

[24]  Jinlong Zhang,et al.  Characterization of Fe–TiO2 photocatalysts synthesized by hydrothermal method and their photocatalytic reactivity for photodegradation of XRG dye diluted in water , 2004 .

[25]  Yueping Fang,et al.  Novel visible light-induced g-C3N4 quantum dot/BiPO4 nanocrystal composite photocatalysts for efficient degradation of methyl orange , 2014 .

[26]  H. Fu,et al.  Photocorrosion inhibition and enhancement of photocatalytic activity for ZnO via hybridization with C60. , 2008, Environmental science & technology.

[27]  Liejin Guo,et al.  Metal sulphide semiconductors for photocatalytic hydrogen production , 2013 .

[28]  Q. Ling,et al.  Enhancement of photocatalytic activity for BiPO4via phase junction , 2014 .

[29]  A. K. Tyagi,et al.  Ag incorporated nano BiPO4: sonochemical synthesis, characterization and improved visible light photocatalytic properties , 2014 .

[30]  Hongzhe Sun,et al.  Microwave synthesis of BiPO4 nanostructures and their morphology-dependent photocatalytic performances. , 2011, Journal of colloid and interface science.

[31]  Yan‐Zhen Zheng,et al.  Synthetic Bi2O2CO3 nanostructures: Novel photocatalyst with controlled special surface exposed , 2010 .

[32]  Yanfang Liu,et al.  Enhancement of visible light mineralization ability and photocatalytic activity of BiPO4/BiOI , 2015 .

[33]  Zhuo. Sun,et al.  Enhanced visible-light photocatalytic degradation of methyl orange by BiPO4–CdS composites synthesized using a microwave-assisted method , 2012 .

[34]  H. Fu,et al.  Visible-light-induced degradation of rhodamine B by nanosized Bi2WO6. , 2005, The journal of physical chemistry. B.

[35]  H. Fu,et al.  Photocatalytic properties of nanosized Bi2WO6 catalysts synthesized via a hydrothermal process , 2006 .

[36]  Xin Gao,et al.  Hydrothermal Synthesis of Disk-Like Bi2WO6-BiPO4 Heterojunctions and Enhanced Photocatalytic Performance for Rhodamine B Degradation , 2014 .

[37]  Yihe Zhang,et al.  Enhanced photocatalytic activity of Eu^3+- and Gd^3+-doped BiPO_4 , 2013 .

[38]  Z. Li,et al.  Photocatalytic performance of α-, β-, and γ-Ga2O3 for the destruction of volatile aromatic pollutants in air , 2007 .

[39]  Yongfa Zhu,et al.  Effects of distortion of PO4 tetrahedron on the photocatalytic performances of BiPO4 , 2011 .

[40]  H. Wan,et al.  Synthesis, characterization and photocatalytic property of AgBr/BiPO4 heterojunction photocatalyst. , 2012, Dalton transactions.

[41]  Y. Zhu,et al.  Synthesis and photocatalysis performances of bismuth oxynitrate photocatalysts with layered structures. , 2014, Physical chemistry chemical physics : PCCP.

[42]  Yongfa Zhu,et al.  A review of controllable synthesis and enhancement of performances of bismuth tungstate visible-light-driven photocatalysts , 2012 .

[43]  Yongfa Zhu,et al.  Synergetic degradation of rhodamine B at a porous ZnWO4 film electrode by combined electro-oxidation and photocatalysis. , 2006, Environmental science & technology.

[44]  Shicheng Zhang,et al.  Visible-light-driven photocatalyst of Bi2WO6 nanoparticles prepared via amorphous complex precursor and photocatalytic properties , 2006 .

[45]  Yanfang Liu,et al.  Surface oxygen vacancy induced photocatalytic performance enhancement of a BiPO4 nanorod , 2014 .

[46]  S. Bruque,et al.  Syntheses, Crystal Structures, and Characterization of Bismuth Phosphates , 1994 .

[47]  A. Kudo,et al.  A Novel Aqueous Process for Preparation of Crystal Form-Controlled and Highly Crystalline BiVO4 Powder from Layered Vanadates at Room Temperature and Its Photocatalytic and Photophysical Properties , 1999 .

[48]  Y. Horiuchi,et al.  Understanding TiO2 photocatalysis: mechanisms and materials. , 2014, Chemical reviews.

[49]  Y. Inoue,et al.  Photocatalytic Activity for Water Decomposition of RuO2-Dispersed Zn2GeO4 with d10 Configuration , 2004 .

[50]  H. Fu,et al.  Efficient TiO2 Photocatalysts from Surface Hybridization of TiO2 Particles with Graphite‐like Carbon , 2008 .

[51]  N. Umezawa,et al.  Facet effect of single-crystalline Ag3PO4 sub-microcrystals on photocatalytic properties. , 2011, Journal of the American Chemical Society.

[52]  Hongjie Zhang,et al.  Multicolor and bright white upconversion luminescence from rice-shaped lanthanide doped BiPO4 submicron particles. , 2013, Dalton transactions.

[53]  L. C. Gontard,et al.  Bifunctional, monodisperse BiPO4-based nanostars: Photocatalytic activity and luminescent applications , 2014 .

[54]  Jinhua Ye,et al.  Photocatalytic Decomposition of Organic Contaminants by Bi2WO6 Under Visible Light Irradiation , 2004 .

[55]  Yongfa Zhu,et al.  Enhanced Photocatalytic Activity of ZnWO4 Catalyst via Fluorine Doping , 2007 .

[56]  Liping Li,et al.  Synthesis, photoluminescence and photocatalytic performance of BiPO4 with different phase structures , 2013, Chemical Research in Chinese Universities.

[57]  Yong Zhu,et al.  Fluorine mediated photocatalytic activity of BiPO4 , 2014 .

[58]  Bin Yang,et al.  One step synthesis of Ag/Ag3PO4/BiPO4 double-heterostructured nanocomposites with enhanced visible-light photocatalytic activity and stability , 2014 .

[59]  H. Fan,et al.  Ag/BiPO4 heterostructures: synthesis, characterization and their enhanced photocatalytic properties. , 2013, Dalton transactions.

[60]  Hui Yang,et al.  An orthophosphate semiconductor with photooxidation properties under visible-light irradiation. , 2010, Nature materials.

[61]  Yihe Zhang,et al.  A novel Bi-based phosphomolybdate photocatalyst K2Bi(PO4)(MoO4): Crystal structure, electronic structure and photocatalytic activity , 2014 .

[62]  Xiaoping Zhou,et al.  Template-free Preparation and Characterization of Novel Hierarchical BiPO4 Six-angular Microcolumns , 2014 .

[63]  Karen L. Johnson,et al.  Oxidative decolorization of acid azo dyes by a Mn oxide containing waste. , 2010, Environmental science & technology.

[64]  Yongfa Zhu,et al.  New type of BiPO(4) oxy-acid salt photocatalyst with high photocatalytic activity on degradation of dye. , 2010, Environmental science & technology.

[65]  R. Asahi,et al.  Visible-Light Photocatalysis in Nitrogen-Doped Titanium Oxides , 2001, Science.

[66]  Xinchen Wang,et al.  Photocatalytic degradation of benzene in gas phase by nanostructured BiPO4 catalysts , 2012 .

[67]  Chuncheng Chen,et al.  Surface Modification of TiO2 by Phosphate: Effect on Photocatalytic Activity and Mechanism Implication , 2008 .

[68]  Yajun Wang,et al.  Dramatic Activity of C3N4/BiPO4 Photocatalyst with Core/Shell Structure Formed by Self‐Assembly , 2012 .

[69]  Jing Cao,et al.  Highly improved visible light photocatalytic activity of BiPO4 through fabricating a novel p–n heterojunction BiOI/BiPO4 nanocomposite , 2013 .

[70]  Hanyun Cheng,et al.  Synthesis of Porous Bi2WO6 Thin Films as Efficient Visible‐Light‐Active Photocatalysts , 2009 .

[71]  Yongfa Zhu,et al.  Size-controlled synthesis of BiPO4 nanocrystals for enhanced photocatalytic performance , 2011 .

[72]  Yongfa Zhu,et al.  Photocatalytic and photoelectrochemical properties of in situ carbon hybridized BiPO4 films , 2012 .

[73]  Kazunari Domen,et al.  New Non-Oxide Photocatalysts Designed for Overall Water Splitting under Visible Light , 2007 .

[74]  S. Martin,et al.  Environmental Applications of Semiconductor Photocatalysis , 1995 .

[75]  Jian Xu,et al.  Removal of rhodamine B from aqueous solution by BiPO4 hierarchical architecture , 2013, Frontiers of Environmental Science & Engineering.

[76]  H. Jung,et al.  Synthesis of Cu2PO4OH Hierarchical Superstructures with Photocatalytic Activity in Visible Light , 2008 .

[77]  Haili Lin,et al.  One-pot hydrothermal synthesis of BiPO4/BiVO4 with enhanced visible-light photocatalytic activities for methylene blue degradation , 2014 .

[78]  Yongfa Zhu,et al.  Synthesis of Square Bi2WO6 Nanoplates as High-Activity Visible-Light-Driven Photocatalysts , 2005 .

[79]  A. Baruah,et al.  Synthesis of a novel and stable g-C3N4–Ag3PO4 hybrid nanocomposite photocatalyst and study of the photocatalytic activity under visible light irradiation , 2013 .

[80]  V. Chornii,et al.  Electronic structures and origin of intrinsic luminescence in Bi-containing oxide crystals BiPO4, K3Bi5(PO4)6, K2Bi(PO4)(MoO4), K2Bi(PO4)(WO4) and K5Bi(MoO4)4 , 2014 .

[81]  Jae Sung Lee,et al.  Phosphate doping into monoclinic BiVO4 for enhanced photoelectrochemical water oxidation activity. , 2012, Angewandte Chemie.

[82]  N. Saito,et al.  Photocatalytic water decomposition by RuO2-loaded antimonates, M2Sb2O7 (M=Ca, Sr), CaSb2O6 and NaSbO3, with d10 configuration , 2002 .

[83]  H. Fu,et al.  Synergetic effect of Bi2WO6 photocatalyst with C60 and enhanced photoactivity under visible irradiation. , 2007, Environmental science & technology.

[84]  Yu-Jun Zhao,et al.  Oxygen vacancy in LiTiPO5 and LiTi2(PO4)3: A first-principles study , 2011 .

[85]  Yongfa Zhu,et al.  Significantly enhanced photocatalytic performance of ZnO via graphene hybridization and the mechanism study , 2011 .

[86]  Ming Yan,et al.  A facile one-step solvothermal synthesis of bismuth phosphate-graphene nanocomposites with enhanced photocatalytic activity. , 2014, Journal of colloid and interface science.

[87]  Suwen Liu,et al.  Synthesis of Mesoporous BiPO4 Nanofibers by Electrospinning with Enhanced Photocatalytic Performances , 2014 .

[88]  Karim Zaghib,et al.  Structure and electrochemistry of FePO4·2H2O hydrate , 2005 .

[89]  A. K. Tyagi,et al.  Experimental and theoretical investigations on the polymorphism and metastability of BiPO4. , 2013, Dalton transactions.

[90]  Binesh Unnikrishnan,et al.  Controlled synthesis, characterization and photocatalytic activity of BiPO4 nanostructures with different morphologies , 2014 .

[91]  Yiying Wu,et al.  Hydrothermal synthesis and visible light photocatalytic activity enhancement of BiPO4/Ag3PO4 composites for degradation of typical dyes , 2014 .

[92]  W. Meng,et al.  Photocatalytic degradation of carbamazepine by tailored BiPO4: efficiency, intermediates and pathway , 2013 .

[93]  Yongfa Zhu,et al.  Controllable synthesis of Fe5(PO4)4(OH)3·2H2O as a highly efficient heterogeneous Fenton-like catalyst , 2011 .

[94]  Yongfa Zhu,et al.  Synthesis and photocatalytic performance of ZnWO4 catalyst , 2007 .

[95]  Mindong Chen,et al.  Controllable growth of novel BiPO4 dendrites by an innovative approach and high energy facets-dependent photocatalytic activity , 2014 .

[96]  A. Kudo,et al.  Heterogeneous photocatalyst materials for water splitting. , 2009, Chemical Society reviews.