论文信息 - Transition-metal complex catalyzed polyfluoroalkylation. A facile synthesis of fluorine-containing oxiranes and enynes.

Transition-metal complex catalyzed polyfluoroalkylation. A facile synthesis of fluorine-containing oxiranes and enynes.

Palladium-catalyzed reaction of polyfluoroalkyl halides with allylic alcohols in the presence of potassium carbonate gives polyfluoroalkylmethyl-substituted oxiranes directly. Perfluoroalkyl-substituted enynes can be also prepared from perfluoroalkyl iodides and terminal alkynes under similar conditions.

T. Fuchikami | H. Urata | Y. Shibata

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