Efficacy of nanolime in restoration procedures of salt weathered limestone rock

Salt crystallisation process is one of the most powerful weathering agents in stone materials, especially in the coastal areas, where sea-spray transports large amount of salts on the stone surface. The consolidation of such degraded stone material represents a critical issue in the field of restoration of cultural heritage. In this paper, the nanolime consolidation behaviour in limestone degraded by salt crystallization has been assessed. For this purpose, a stone material taken from a Sicilian historical quarry and widely used in the eastern Sicilian Baroque architecture has been artificially degraded by the salt crystallization test. Then degraded samples have been treated with NanoRestore®, a suspension of nanolime in isopropyl alcohol. To evaluate the consolidating effectiveness, the peeling test and point load test were performed. Moreover, mercury intrusion porosimetry has been executed to evaluate the variations induced by treatment, while colorimetric measurements have been aimed to assess aesthetical issues.

[1]  A. Goudie Encyclopedia of Geomorphology , 2003 .

[2]  Piero Baglioni,et al.  Soft and hard nanomaterials for restoration and conservation of cultural heritage. , 2006, Soft matter.

[3]  G. M. Crisci,et al.  ZnO and ZnTiO3 nanopowders for antimicrobial stone coating , 2010 .

[4]  Piero Baglioni,et al.  Colloidal Particles of Ca(OH)2: Properties and Applications to Restoration of Frescoes , 2001 .

[5]  Zuzana Slížková,et al.  Standardization of peeling tests for assessing the cohesion and consolidation characteristics of historic stone surfaces , 2011, Materials and Structures.

[6]  Luigi Dei,et al.  Synthesis of Ca(OH)2 Nanoparticles from Diols , 2001 .

[7]  Ronan Hébert,et al.  Salt crystallization in pores: quantification and estimation of damage , 2007 .

[8]  Piero Baglioni,et al.  A New Method for Consolidating Wall Paintings Based on Dispersions of Lime in Alcohol , 2000 .

[9]  D. H. Everett The thermodynamics of frost damage to porous solids , 1961 .

[10]  Piero Baglioni,et al.  Stable dispersions of Ca(0H)2 in aliphatic alcohols: properties and application in cultural heritage conservation , 2001 .

[11]  Piero Baglioni,et al.  Nanotechnologies for Conservation of Cultural Heritage: Paper and Canvas Deacidification , 2002 .

[12]  R. Rossi-Manaresi,et al.  Pore structure and the disruptive or cementing effect of salt crystallization in various types of stone , 1991 .

[13]  L. Anania,et al.  The stones in monumental masonry buildings of the “Val di Noto” area: New data on the relationships between petrographic characters and physical–mechanical properties , 2012 .

[14]  H. W. Wellman,et al.  Salt weathering or fretting , 1968 .

[15]  Salvador Ordóñez,et al.  Role of pore structure in salt crystallisation in unsaturated porous stone , 2004 .

[16]  P. Mazzoleni,et al.  Application of protective products to “Noto” calcarenite (south-eastern Sicily): a case study for the conservation of stone materials , 2011 .

[17]  Raimondo Quaresima,et al.  The nanolimes in Cultural Heritage conservation: Characterisation and analysis of the carbonatation process , 2008 .

[18]  Gino Mirocle Crisci,et al.  Multifunctional TiO2 coatings for Cultural Heritage , 2012 .

[19]  Antonia Moropoulou,et al.  Criteria and methodology for the evaluation of conservation interventions on treated porous stone susceptible to salt decay , 2003 .

[20]  R. Flatt,et al.  A commented translation of the paper by C.W. Correns and W. Steinborn on crystallization pressure , 2007 .

[21]  Rafael Fort,et al.  Thermodynamic modelling of changes induced by salt pressure crystallisation in porous media of stone , 1999 .

[22]  Giuseppe Montana,et al.  Study of the effects of salt crystallisation on degradation of limestone rocks , 2013 .

[23]  Michael Steiger,et al.  Crystal growth in porous materials—I: The crystallization pressure of large crystals , 2005 .