论文信息 - The first aluminium‐bridged [1.1]ferrocenophane

The first aluminium‐bridged [1.1]ferrocenophane

The structure of the title compound, bis(μ-ferrocene-1,1′-diyl)bis[chloro(N,N,N′N′-tetramethylethylenediamine)aluminium], [Al2Fe2Cl2(C5H4)4(C6H16N2)2], possesses a center of inversion and an anti conformation. Bound to each Al atom in the bridging position are one Cl atom and one molecule of N,N,N′N′-tetramethylethylenediamine (TMEDA). The angle between the least-squares planes of the two cyclopentadienyl (Cp) ligands is 3.6 (3)°. The five C atoms in the Cp rings are staggered on average at an angle of 10.3 (5)°.

J. Quail | Jens Müller | J. Schachner | Clinton L. Lund

[1] J. Quail,et al. Synthesis and Characterization of the First Aluminum-Bridged [1]Ferrocenophane† , 2005 .

[2] P. Jutzi,et al. A digalla[1.1]ferrocenophane and its coordination chemistry: Synthesis and structure of [{Fe(eta(5)-C5H4)(2)}(2){GaMe}(2)] and of the adducts [{Fe(eta(5)-C5H4)(2)}(2)GaMe(D)}(2)] (D = monodentate donor) and [Fe(eta(5)-C5H4)(2)}(2){GaMe}(2)D] (D = bidentate donor) , 2003 .

[3] M. Wagner,et al. [1.1]Diborataferrocenophane: a highly efficient Li+ scavenger. , 2003, Angewandte Chemie.

[4] P. Jutzi,et al. The First 1,1‘-Digallylferrocene and a Rodlike, Polymeric Donor−Acceptor Complex: Synthesis, Properties, and Structure of [Fe(η5-C5H4GaMe2)2]n and [Fe(η5-C5H4GaMe2)2(C12H8N2)]n†,1 , 2002 .

[5] T. Spies,et al. Synthesis and structure of an alkylgallium bridged [1,1]ferrocenophane , 2001 .

[6] Maria Cristina Burla,et al. SIR97: a new tool for crystal structure determination and refinement , 1999 .

[7] Louis J. Farrugia,et al. ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI) , 1997 .

[8] Horace Traubel. Collect , 1904 .

The first aluminium‐bridged [1.1]­ferrocenophane

The first aluminium‐bridged [1.1]ferrocenophane