Thermal process of fluff: preliminary tests on a full-scale treatment plant.

Until only recently fluff has been largely disposed of in controlled landfill sites. However, in Europe environmental regulations, including the EU Landfill Directive 1999/31/EC and ELV (End of Life Vehicle) Directive 2000/53/EC, have dramatically increased the pressure on all stakeholders to develop alternative solutions. As increasingly stringent legislation forces Shredder Residues (SR) to be diverted from landfilling, newly developed technologies will be in a position to compete for the market value of disposing of the waste. However, the fluff waste stream is so variable that it cannot be automatically assumed that processes developed for one type of fluff will prove to be suitable for other fluff streams. This situation has contributed towards convincing stakeholders to withhold investment funds or delay taking decisions as to how best to proceed; as a consequence, very few technologies have been fully developed on a commercial basis. It is of particular interest therefore that commercial alternatives to be used in dealing with this complex waste stream should be identified. The present paper illustrates the findings of a full-scale thermal treatment performed on SR samples obtained from various shredding plants. The outcome of the study provides an important contribution towards assessing the feasibility and reliability of the process, thus constituting a basic prerequisite for process performance evaluation. The full-scale plant, designed for the thermo-valorization of tyres, was purpose-modified to allow for fluff combustion. Three different fluff compositions (car fluff with different percentage of shredding, whites and 100% car fluff) were taken into consideration. Both the raw samples and solid products were thoroughly characterized. Combustion emissions were continuously analyzed during the test period, alternatively operating for tyre and fluff combustion. Classification of combustion residues for landfill disposal was carried out indicating only 2% (ashes) as hazardous waste. Preliminary results, obtained from a unsophisticated thermodynamic analysis of the process, indicated a value of 0.61 for energy efficiency parameter calculated in accordance with the Directive 2008/98/EC. To conclude, the thermal treatment investigated may be deemed an appropriate technique for use in managing fluff. Indeed, values obtained for all organic and inorganic contaminants released into the atmosphere were lower than legal limits prescribed, and a significant energy content was recovered from waste fractions.

[1]  Christian Roy,et al.  Vacuum pyrolysis of automobile shredder residues: use of the pyrolytic oil as a modifier for road bitumen , 1999 .

[2]  W. L. Dalmijn,et al.  The development of vehicle recycling in Europe: Sorting, shredding, and separation , 2007 .

[3]  Marcello Zolezzi,et al.  Conventional and fast pyrolysis of automobile shredder residues (ASR). , 2004, Waste management.

[4]  Daphne Mirabile,et al.  Thermal valorisation of automobile shredder residue: injection in blast furnace. , 2002, Waste management.

[5]  Marie K. Harder,et al.  Value from shredder waste: Ongoing limitations in the UK , 2006 .

[6]  S. Sakai,et al.  Leaching behavior of PCBs and PCDDs/DFs from some waste materials , 2000 .

[7]  Markus A. Reuter,et al.  Fundamental limits for the recycling of end-of-life vehicles , 2006 .

[8]  L. Delfosse,et al.  Laboratory scale studies on gaseous emissions generated by the incineration of an artificial automotive shredder residue presenting a critical composition , 1998 .

[9]  Markus A. Reuter,et al.  The optimization of end-of-life vehicle recycling in the european union , 2004 .

[10]  I. Hwang,et al.  Improving the quality of waste-derived char by removing ash. , 2008, Waste management.

[11]  Christian Roy,et al.  Vacuum pyrolysis of automobile shredder residues , 2001 .

[12]  Yong-Chil Seo,et al.  Distribution of dioxins, furans, and dioxin-like PCBs in solid products generated by pyrolysis and melting of automobile shredder residues. , 2007, Chemosphere.

[13]  Cedric Briens,et al.  Ultrapyrolysis of automobile shredder residue , 1995 .

[14]  S. Saxena,et al.  Combustion and co-combustion of auto fluff , 1995 .

[15]  Marie K. Harder,et al.  A critical review of developments in the pyrolysis of automotive shredder residue , 2007 .

[16]  V. K. Sharma,et al.  Pyrolysis process for treatment of automobile shredder residue: preliminary experimental results , 2001 .

[17]  F. E. Mark,et al.  Energy recovery from automotive shredder residue through co-combustion with municipal solid waste , 1998 .

[18]  M. Day,et al.  Pyrolysis of automobile shredder residue: an analysis of the products of a commercial screw kiln process☆ , 1996 .

[19]  L. Di Palma,et al.  Production of aggregate from non-metallic automotive shredder residues. , 2006, Journal of hazardous materials.

[20]  Arpad Horvath,et al.  Environmental assessment of shredder residue management , 2006 .

[21]  Heikki Jalkanen On the direct recycling of automotive shreddar residue and electronic scrap in metallurgical industry , 2006 .

[22]  Sujit Das,et al.  Automobile recycling in the United States: Energy impacts and waste generation , 1995 .

[23]  M. Singh,et al.  Diversion from landfill: quality products from valuable plastics , 2002 .

[24]  C. Pasel,et al.  Experimental investigations on reactor scale-up and optimisation of product quality in pyrolysis of shredder waste , 2003 .

[25]  K. Kakimoto,et al.  Use of fine-grained shredder dust as a cement admixture after a melting, rapid-cooling and pulverizing process , 2004 .

[26]  Massimiliano Giona,et al.  Pyrolysis of automotive shredder residues: a lumped kinetic characterization , 1998 .

[27]  Yong-Chil Seo,et al.  Management status of end-of-life vehicles and characteristics of automobile shredder residues in Korea. , 2004, Waste management.

[28]  Hwa Young Lee Characteristics and heavy metal leaching of ash generated from incineration of automobile shredder residue. , 2007, Journal of hazardous materials.

[29]  I. Marco,et al.  Recycling polymeric wastes by means of pyrolysis , 2002 .

[30]  I. Marco,et al.  Recycling of automobile shredder residues by means of pyrolysis , 2007 .

[31]  Menad Nourreddine,et al.  Recycling of auto shredder residue. , 2007, Journal of hazardous materials.

[32]  Shigekatsu Mori,et al.  Study of gasification characteristics of automobile shredder residue , 2001 .

[33]  P. Pollesel,et al.  Pyrolysis of automotive shredder residue (ASR) influence of temperature on the distribution of products , 1997 .

[34]  Thomas Malkow,et al.  Novel and innovative pyrolysis and gasification technologies for energy efficient and environmentally sound MSW disposal. , 2004, Waste management.