MBE Growth of (In)GaN for LED Applications

We report on essential aspects of the growth of InGaN / GaN p-n junctions by gas-source molecular beam epitaxy (MBE) and present the first blue and green electroluminescence from such structures grown entirely by MBE. A study of the growth conditions for a GaN nucleation layer on sapphire and for the subsequent growth of undoped GaN points out the necessity for Ga-stabilized growth. Unintentionally doped GaN grown at 1 μm/h shows background doping levels below 1017 cm-3 and mobilities up to 320 cm2/Vsec (at 300K). Narrow photoluminescence with very low intensity in the yellow spectral range is observed. N- and p-type doping of GaN with Si and Mg yields layers with high mobilities (220 and 10 cm2/Vsec, respectively at 300K) at carrier densities typical for devices. Although incorporation of Indium is strongly temperature-dependent, InGaN-layers with In-contents of over 40% are obtained routinely. The optical properties of our InGaN layers typically exhibit the commonly observed, broad deep level luminescence. Finally, we present electroluminescence in the visible spectral range up to 540 nm from InGaN / GaN double-heterojunctions.

[1]  S. Nakamura,et al.  High-Brightness InGaN Blue, Green and Yellow Light-Emitting Diodes with Quantum Well Structures , 1995 .

[2]  J. Schetzina Growth and Properties of III-V Nitride Films, Quantum Well Structures and Integrated Heterostructure Devices , 1995 .

[3]  R. Vaudo,et al.  Atomic nitrogen production in a molecular‐beam epitaxy compatible electron cyclotron resonance plasma source , 1994 .

[4]  H. Tews,et al.  Blue and green electroluminescence from MBE grown GaN/InGaN heterostructures , 1996 .

[5]  R. M. Park,et al.  Growth of zinc blende‐GaN on β‐SiC coated (001) Si by molecular beam epitaxy using a radio frequency plasma discharge, nitrogen free‐radical source , 1993 .

[6]  T. Moustakas,et al.  A Comparative Study of GaN Films Grown on Different Faces of Sapphire by ECR-Assisted MBE , 1992 .

[7]  James S. Speck,et al.  Role of threading dislocation structure on the x‐ray diffraction peak widths in epitaxial GaN films , 1996 .

[8]  D. Rode,et al.  Electron Hall mobility of n‐GaN , 1995 .

[9]  H. Morkoç,et al.  Properties of GaN films grown under Ga and N rich conditions with plasma enhanced molecular beam epitaxy , 1995 .

[10]  R. Street,et al.  Activation of acceptors in Mg-doped GaN grown by metalorganic chemical vapor deposition , 1996 .

[11]  T. Moustakas,et al.  Electron transport mechanism in gallium nitride , 1993 .

[12]  S. Nakamura InGaN/AlGaN blue-light-emitting diodes , 1995 .

[13]  Kovalev,et al.  Exciton fine structure in undoped GaN epitaxial films. , 1996, Physical review. B, Condensed matter.