Predictive mapping of air pollution involving sparse spatial observations.

A limited number of sample points greatly reduces the availability of appropriate spatial interpolation methods. This is a common problem when one attempts to accurately predict air pollution levels across a metropolitan area. Using ground-level ozone concentrations in the Tucson, Arizona, region as an example, this paper discusses the above problem and its solution, which involves the use of linear regression. A large range of temporal variability is used to compensate for sparse spatial observations (i.e. few ozone monitors). Gridded estimates of emissions of ozone precursor chemicals, which are developed, stored, and manipulated within a geographic information system, are the core predictor variables in multiple linear regression models. Cross-validation of the pooled models reveals an overall R2 of 0.90 and approximately 7% error. Composite ozone maps predict that the highest ozone concentrations occur in a monitor-less area on the eastern edge of Tucson. The maps also reveal the need for ozone monitors in industrialized areas and in rural, forested areas.

[1]  P. Burrough,et al.  Comparison of spatial prediction methods for mapping floodplain soil pollution , 1990 .

[2]  D. Griffith,et al.  A Casebook for Spatial Statistical Data Analysis: A Compilation of Different Thematic Data Sets , 1999 .

[3]  H. Knudsen,et al.  The use of kriging to estimate monthly ozone exposure parameters for the Southeastern United States. , 1988, Environmental pollution.

[4]  S. Rouhani,et al.  Geostatistical analysis and visualization of hourly ozone data , 1994 .

[5]  Qing Yang,et al.  Modeling the effects of meteorology on ozone in Houston using cluster analysis and generalized additive models , 1998 .

[6]  George B. Frisvold,et al.  Agricultural exposure to ozone and acid precipitation , 1994 .

[7]  W. Chameides,et al.  An observation-based model for analyzing ozone precursor relationships in the urban atmosphere. , 1995, Journal of the Air & Waste Management Association.

[8]  Thomas K. Peucker,et al.  Regression Analysis and Geographic Models , 1978 .

[9]  D. Greenland,et al.  The Spatial Distribution of Particulate Concentrations in the Denver Metropolitan Area , 1985 .

[10]  A. Comrie Comparing Neural Networks and Regression Models for Ozone Forecasting , 1997 .

[11]  Gerard B. M. Heuvelink,et al.  Propagation of errors in spatial modelling with GIS , 1989, Int. J. Geogr. Inf. Sci..

[12]  David P. Chock,et al.  Time-series analysis of Riverside, California air quality data , 1975 .

[13]  A. Comrie,et al.  Integrating Remote Sensing and Local Vegetation Information for a High-Resolution Biogenic Emissions Inventory— Application to an Urbanized, Semiarid Region , 2000, Journal of the Air & Waste Management Association.

[14]  Noel A Cressie,et al.  Statistics for Spatial Data. , 1992 .

[15]  Andrew C. Comrie,et al.  Climatology and forecast modeling of ambient carbon monoxide in Phoenix, Arizona , 1999 .

[16]  A. Comrie,et al.  Allocating anthropogenic pollutant emissions over space: application to ozone pollution management. , 2001, Journal of environmental management.

[17]  C. Willmott ON THE VALIDATION OF MODELS , 1981 .

[18]  A. J. Rossini,et al.  Use of kriging models to predict 12-hour mean ozone concentrations in Metropolitan Toronto—A pilot study , 1996 .

[19]  David M. Holland,et al.  Estimation of regional trends in sulfur dioxide over the eastern United States , 2000 .

[20]  Donald E. Myers,et al.  Interpolation and estimation with spatially located data , 1991 .

[21]  Allen S. Lefohn,et al.  An Evaluation of the Kriging Method to Predict 7-h Seasonal Mean Ozone Concentrations for Estimating Crop Losses , 1987 .

[22]  B. Godzik Ground Level Ozone Concentrations in the Kraków Region, Southern Poland , 1997 .

[23]  N. Lam Spatial Interpolation Methods: A Review , 1983 .

[24]  M. Tayanç,et al.  An assessment of spatial and temporal variation of sulfur dioxide levels over Istanbul, Turkey. , 2000, Environmental pollution.

[25]  Some Problems with the Use of Regression Analysis in Geography , 1984 .

[26]  Donald E. Myers,et al.  Spatial interpolation: an overview , 1994 .

[27]  Wilfried Winiwarter,et al.  Estimating the spatial distribution of ozone concentrations in complex terrain , 1994 .

[28]  Terry L. Clark,et al.  Application of Prognostic Meteorological Variables to Forecasts of Daily Maximum One-Hour Ozone Concentrations in the Northeastern United States , 1982 .

[29]  L. Anselin Spatial Econometrics: Methods and Models , 1988 .

[30]  Scott M. Lesch,et al.  Spatial Prediction of Soil Salinity Using Electromagnetic Induction Techniques: 1. Statistical Prediction Models: A Comparison of Multiple Linear Regression and Cokriging , 1995 .

[31]  C. Geron,et al.  Reassessment of biogenic volatile organic compound emissions in the Atlanta area , 1995 .

[32]  John R. Miron,et al.  Spatial Autocorrelation in Regression Analysis: A Beginner’s Guide , 1984 .

[33]  P. Elliott,et al.  A regression-based method for mapping traffic-related air pollution: application and testing in four contrasting urban environments. , 2000, The Science of the total environment.

[34]  C. Daly,et al.  A Statistical-Topographic Model for Mapping Climatological Precipitation over Mountainous Terrain , 1994 .

[35]  S. Sillman The relation between ozone, NOx and hydrocarbons in urban and polluted rural environments , 1999 .

[36]  William H. Crown,et al.  Statistical Models for the Social and Behavioral Sciences: Multiple Regression and Limited-Dependent Variable Models , 1998 .

[37]  Richard J. Aspinall,et al.  Adapting Regression Equations to Minimize the Mean Squared Error of Predictions Made Using Covariate Data from a GIS , 1997, Int. J. Geogr. Inf. Sci..

[38]  Donald L. Phillips,et al.  USE OF AUXILIARY DATA FOR SPATIAL INTERPOLATION OF OZONE EXPOSURE IN SOUTHEASTERN FORESTS , 1997 .

[39]  A. Comrie,et al.  Air Quality, Climate, and Policy: A Case Study of Ozone Pollution in Tucson, Arizona , 2001 .

[40]  A. Comrie,et al.  Integrating remote sensing and local vegetation information for a high-resolution biogenic emissions inventory--application to an urbanized, semiarid region. , 2000, Journal of the Air & Waste Management Association.

[41]  Cort J. Willmott,et al.  Spatial statistics and models , 1984 .

[42]  Michael O. Rodgers,et al.  Ozone precursor relationships in the ambient atmosphere , 1992 .

[43]  A. Russell,et al.  Temporal and spatial distributions of ozone in Atlanta: regulatory and epidemiologic implications. , 1998, Journal of the Air & Waste Management Association.

[44]  Simon Kingham,et al.  Mapping Urban Air Pollution Using GIS: A Regression-Based Approach , 1997, Int. J. Geogr. Inf. Sci..

[45]  D. Griffith What is spatial autocorrelation? Reflections on the past 25 years of spatial statistics , 1992 .