Investigation of hard magnetic properties in the Fe–Pt system by combinatorial deposition of thin film multilayer libraries

Abstract The magnetic properties of annealed Fe–Pt multilayer thin films with a broad composition range were investigated in order to identify the effects of composition and annealing temperature on the achievable coercive field, and to identify its maximum at low processing temperatures. Two types of multilayer systems were deposited as materials libraries to vary the composition from Fe20Pt80 to Fe75Pt25. The first type of multilayer was comprised of alternating opposing wedges, whereas the second type consisted of repeated uniform Fe and Pt layers interspersed periodically with Fe wedge layers. It was found that coercive fields μ0HC > 0.7 T can be achieved at an annealing temperature of about 300 °C (60 min) for both types of multilayers as long as the composition is close to 50:50. Higher annealing temperatures are needed for films, which deviate from this composition. Increasing the annealing temperature up to 700 °C leads to increased coercivity values. Multilayers with additional Fe layers showed increased remanence but reduced coercive fields.

[1]  C. Luo,et al.  Structural and magnetic properties of FePt:SiO2 granular thin films , 1999 .

[2]  K. Bussmann,et al.  Connecting disorder and magnetic properties in CoFe thin films. , 2000 .

[3]  G. Hadjipanayis,et al.  Permanent-magnet properties of thermally processed FePt and FePt-Fe multilayer films , 2002 .

[4]  Alfred Ludwig Combinatorial fabrication of magnetic multilayer films , 2004 .

[5]  E. Kneller,et al.  The exchange-spring magnet: a new material principle for permanent magnets , 1991 .

[6]  J. Liu,et al.  High energy products in rapidly annealed nanoscale Fe/Pt multilayers , 1998 .

[7]  K. Shibata FePt Magnetic Recording Media : Problems and Possibilities for Practical Use , 2003 .

[8]  S. Jaswal,et al.  Electronic structure and magnetic properties of hard/soft multilayers , 1998 .

[9]  Lawrence H. Bennett,et al.  Binary alloy phase diagrams , 1986 .

[10]  K. Hono,et al.  Microstructure and magnetic properties of FePt and Fe/FePt polycrystalline films with high coercivity , 2004 .

[11]  L. Schultz,et al.  Highly coercive electrodeposited FePt films by postannealing in hydrogen , 2004 .

[12]  N. Kikuchi,et al.  Lowering of ordering temperature for fct Fe–Pt in Fe/Pt multilayers , 2001 .

[13]  Takenobu Suzuki,et al.  Magnetic and structural properties of (CoxFe100−x)50Pt50 alloy thin films , 2000 .

[14]  Laura H. Lewis,et al.  On the relationship of high coercivity and L10 ordered phase in CoPt and FePt thin films , 1999 .

[15]  J. Mallett,et al.  Recrystallization texture, epitaxy, and magnetic properties of electrodeposited FePt on Cu(001) , 2004 .

[16]  C. Platt,et al.  Evolution of stress with L10 ordering in FePt and FeCuPt thin films , 2003 .

[17]  B. Warren,et al.  X-Ray Diffraction , 2014 .

[18]  D. Peng,et al.  Formation and magnetic properties of Fe-Pt alloy clusters by plasma-gas condensation , 2003 .