Synthesis and spectroscopic characterisation of new nickel (II) complexes with 5-methyl-3-formylpyrazole-3-piperidinylthiosemicarbazone (HMPz3Pi): X-ray structures of HMPz3Pi and [Ni(HMPz3Pi)2]Cl2 · 2H2O with indication for unusual rotation about the azomethine double bond of the free ligand on comp