Air-bridged lateral growth of crack-free Al0.24Ga0.76N on highly relaxed porous GaN

We report on the strain reduction in AlGaN layers grown on porous GaN (P-GaN) by metalorganic chemical vapor deposition (MOCVD). The P-GaN was obtained by ultraviolet radiation-enhanced electroless wet chemical etching of thick hydride vapor phase epitaxial grown GaN (HVPE-GaN) templates over (001) sapphire substrates. By optimizing the growth conditions, lateral growth of AlGaN was enhanced resulting in air-bridge formation between the P-GaN and the AlGaN layers. X-ray diffraction studies showed significant strain relaxation in AlGaN layers primarily due to the strain sharing between P-GaN and the AlGaN layers. This allowed us to grow crack-free good optical quality layers with thickness exceeding the critical limits for AlGaN deposition on the conventional MOCVD GaN or HVPE-GaN. The obtained results demonstrate the potential of this approach for the development of efficient ultraviolet light emitters.

[1]  M. Asif Khan,et al.  AlN/AlGaN superlattices as dislocation filter for low-threading-dislocation thick AlGaN layers on sapphire , 2002 .

[2]  L. Canham Silicon quantum wire array fabrication by electrochemical and chemical dissolution of wafers , 1990 .

[3]  Hong Wang,et al.  Crack-free thick AlGaN grown on sapphire using AlN/AlGaN superlattices for strain management , 2002 .

[4]  Grigory Simin,et al.  Deep ultraviolet light-emitting diodes using quaternary AlInGaN multiple quantum wells , 2002 .

[5]  Grigory Simin,et al.  Lateral Current Crowding in Deep UV Light Emitting Diodes over Sapphire Substrates , 2002 .

[6]  V. Davydov,et al.  Strain relaxation in GaN layers grown on porous GaN sublayers , 1999 .

[7]  T. Unagami Formation Mechanism of Porous Silicon Layer by Anodization in HF Solution , 1980 .

[8]  Ron Jenkins,et al.  Introduction to X-ray powder diffractometry , 1996 .

[9]  I. Adesida,et al.  Morphology and luminescence of porous GaN generated via Pt-assisted electroless etching , 2002 .

[10]  Ephraim Suhir,et al.  New approach to the high quality epitaxial growth of lattice‐mismatched materials , 1986 .

[11]  Sangsig Kim,et al.  Optical Transmission, Photoluminescence, and Raman Scattering of Porous SiC Prepared from p-Type 6H SiC. , 2000 .

[12]  Isamu Akasaki,et al.  Strain Modification of GaN in AlGaN/GaN Epitaxial Films , 1999 .

[13]  Hong Wang,et al.  Pulsed atomic-layer epitaxy of ultrahigh-quality AlxGa1−xN structures for deep ultraviolet emissions below 230 nm , 2002 .

[14]  S. Arai,et al.  Fabrication of Vertical and Uniform-Size Porous InP Structure by Electrochemical Anodization , 1994 .

[15]  K. D. Mynbaev,et al.  Structural characterization and strain relaxation in porous GaN layers , 2000 .

[16]  Xiuling Li,et al.  In-plane bandgap control in porous GaN through electroless wet chemical etching , 2002 .

[17]  Grigory Simin,et al.  324 nm Light Emitting Diodes With MilliWatt Powers : Semiconductors , 2002 .

[18]  Grigory Simin,et al.  Milliwatt power deep ultraviolet light-emitting diodes over sapphire with emission at 278 nm , 2002 .

[19]  Ayumu Tsujimura,et al.  Improvement of Crystalline Quality in GaN Films by Air-Bridged Lateral Epitaxial Growth , 2000 .

[20]  C. D. Lee,et al.  Growth of GaN on porous SiC and GaN substrates , 2003 .

[21]  S. D. Collins,et al.  Porous silicon formation mechanisms , 1992 .

[22]  Jung Han,et al.  Control and elimination of cracking of AlGaN using low-temperature AlGaN interlayers , 2001 .