论文信息 - A New Type of Hydrogen Bond

A New Type of Hydrogen Bond

Hydrogen bonding is responsible for a wide array of chemical properties, from the melting point of water to the behavior of enzymes. In his Perspective, Crabtree discusses recent work in which entirely new kinds of hydrogen bonds have been discovered. Understanding and controlling these new types of bonding may enable researchers to harness a variety of important catalytic processes.

Robert H. Crabtree | R. Crabtree

[1] R. Morris,et al. Switching On and Off a New Intramolecular Hydrogen-Hydrogen Interaction and the Heterolytic Splitting of Dihydrogen. Crystal and Molecular Structure of [Ir{H(.eta.1-SC5H4NH)}2(PCy3)2]BF4.cntdot.2.7CH2Cl2 , 1994 .

[2] T. Koetzle,et al. A new intermolecular interaction: unconventional hydrogen bonds with element-hydride bonds as proton acceptor. , 1996, Accounts of chemical research.

[3] Thomas F. Koetzle,et al. An attractive cis-effect of hydride on neighbor ligands: experimental and theoretical studies on the structure and intramolecular rearrangements of Fe(H)2(.eta.2-H2)(PEtPh2)3 , 1990 .