3D Printing of Interdigitated Li‐Ion Microbattery Architectures

3D interdigitated microbattery architectures (3D-IMA) are fabricated by printing concentrated lithium oxide-based inks. The microbatteries are composed of interdigitated, high-aspect ratio cathode and anode structures. Our 3D-IMA, which exhibit high areal energy and power densities, may find potential application in autonomously powered microdevices.

[1]  R. Huggins.  Solid State Ionics , 1989 .

[2]  C. R. Martin,et al.  Template Synthesis of Polypyrrole‐Coated Spinel LiMn2 O 4 Nanotubules and Their Properties as Cathode Active Materials for Lithium Batteries , 1997 .

[3]  Karim Zaghib,et al.  Electrochemistry of Anodes in Solid‐State Li‐Ion Polymer Batteries , 1998 .

[4]  J. Bates.  Thin-Film Lithium and Lithium-Ion Batteries , 2000 .

[5]  S. M. Spearing,et al.  Materials issues in microelectromechanical systems (MEMS) , 2000 .

[6]  J. Cesarano,et al.  Directed colloidal assembly of 3D periodic structures , 2002 .

[7]  Yet-Ming Chiang,et al.  Electronically conductive phospho-olivines as lithium storage electrodes , 2002, Nature materials.

[8]  Robert Langer,et al.  Small-scale systems for in vivo drug delivery , 2003, Nature Biotechnology.

[9]  J. Lewis,et al.  Direct writing in three dimensions , 2004 .

[10]  Bruce Dunn,et al.  Three-dimensional battery architectures. , 2004, Chemical reviews.

[11]  M. Nathan,et al.  Three-dimensional thin-film Li-ion microbatteries for autonomous MEMS , 2005, Journal of Microelectromechanical Systems.

[12]  Alfredo M. Morales,et al.  Microfabricated Deposition Nozzles for Direct‐Write Assembly of Three‐Dimensional Periodic Structures , 2005 .

[13]  Chunsun Zhang,et al.  PCR microfluidic devices for DNA amplification. , 2006, Biotechnology advances.

[14]  J. Cesarano,et al.  Direct Ink Writing of Three‐Dimensional Ceramic Structures , 2006 .

[15]  J. A. Lewis.  Direct Ink Writing of 3D Functional Materials , 2006 .

[16]  Karim Zaghib,et al.  Characterization of the carbon coating onto LiFePO4 particles used in lithium batteries , 2006 .

[17]  H. Craighead,et al.  Micro- and nanomechanical sensors for environmental, chemical, and biological detection. , 2007, Lab on a chip.

[18]  Jeffrey W Long,et al.  Architectural design, interior decoration, and three-dimensional plumbing en route to multifunctional nanoarchitectures. , 2007, Accounts of chemical research.

[19]  W. Shyy,et al.  Numerical Simulation of Intercalation-Induced Stress in Li-Ion Battery Electrode Particles , 2007 .

[20]  Fred Roozeboom,et al.  High Energy Density All‐Solid‐State Batteries: A Challenging Concept Towards 3D Integration , 2008 .

[21]  M. Armand,et al.  Building better batteries , 2008, Nature.

[22]  J. Wolfenstine,et al.  Electrical conductivity and charge compensation in Ta doped Li4Ti5O12 , 2008 .

[23]  Chunlei Wang,et al.  Fabrication and properties of a carbon/polypyrrole three-dimensional microbattery , 2008 .

[24]  John A. Rogers,et al.  Omnidirectional Printing of Flexible, Stretchable, and Spanning Silver Microelectrodes , 2009, Science.

[25]  T. Gustafsson,et al.  Self-supported three-dimensional nanoelectrodes for microbattery applications. , 2009, Nano letters.

[26]  Byoungwoo Kang,et al.  Battery materials for ultrafast charging and discharging , 2009, Nature.

[27]  R. Rosenfeld.  Nature , 2009, Otolaryngology--head and neck surgery : official journal of American Academy of Otolaryngology-Head and Neck Surgery.

[28]  B. H. Weiller,et al.  Practical chemical sensors from chemically derived graphene. , 2009, ACS nano.

[29]  Pierre-Louis Taberna,et al.  Nanoarchitectured 3D Cathodes for Li‐Ion Microbatteries , 2010, Advanced materials.

[30]  Thomas F. Marinis,et al.  Ultrahigh‐Energy‐Density Microbatteries Enabled by New Electrode Architecture and Micropackaging Design , 2010, Advanced materials.

[31]  Paul V. Braun,et al.  Three-dimensional bicontinuous ultrafast-charge and -discharge bulk battery electrodes. , 2011, Nature nanotechnology.

[32]  Yuji Suzuki,et al.  Effect of sol composition on solid electrode/solid electrolyte interface for all-solid-state lithium ion battery , 2011 .

[33]  Bruce Dunn,et al.  Three-dimensional electrodes and battery architectures , 2011 .

[34]  P. Ajayan,et al.  Building energy storage device on a single nanowire. , 2011, Nano letters.

[35]  R. Kohler,et al.  Laser-Printed and Processed LiCoO 2 CathodeThick Films for Li-Ion Microbatteries , 2012 .

[36]  H. Munakata,et al.  Fabrication of micro lithium-ion battery with 3D anode and 3D cathode by using polymer wall , 2012 .

[37]  P. Ajayan,et al.  3D nanoporous nanowire current collectors for thin film microbatteries. , 2012, Nano letters.

[38]  Diana Golodnitsky,et al.  Electrophoretic deposition of lithium iron phosphate cathode for thin-film 3D-microbatteries , 2012 .

[39]  Paul V Braun,et al.  High-power lithium ion microbatteries from interdigitated three-dimensional bicontinuous nanoporous electrodes , 2013, Nature Communications.