Metallocene catalysts for olefin polymerization

[1]  M. Arndt,et al.  C1-symmetric metallocenes for olefin polymerisation, 1 catalytic performance of [Me2C(3-tertBuCp)(Flu)]ZrCl2 in ethene/norbornene copolymerisation , 1998 .

[2]  W. Kaminsky,et al.  Ethene/propene copolymerisation by [Me2C(3‐RCp)(Flu)]ZrCl2/MAO (R = H, Me, isoPr, tertBu) , 1998 .

[3]  W. Kaminsky,et al.  Fluorinated Half-Sandwich Complexes as Catalysts in Syndiospecific Styrene Polymerization , 1997 .

[4]  R. Fröhlich,et al.  Internal Fluorocarbon Coordination as a Tool for the Protection of Active Catalytic Sites: Experimental Characterization of the Zr···F−C Interaction in the Group 4 Metallocene(butadiene)/B(C6F5)3 Betaine Ziegler Catalyst Systems , 1997 .

[5]  M. Thornton-Pett,et al.  Synthesis of Cyclopentadienyl-, Indenyl-, and Fluorenylbis(pentafluorophenyl)boranes as Ligands in Titanium and Zirconium Half-Sandwich Complexes. The Crystal Structures of C13H9B(C6F5)2·t-BuNH2, C13H8SiMe3B(C6F5)2, and {η5-C5H4B(C6F5)2}TiCl3 , 1997 .

[6]  A. Segre,et al.  Full assignment of the 13C NMR spectra of regioregular polypropylenes : Methyl and methylene region , 1997 .

[7]  T. Takata,et al.  Syndiospecific propene polymerization with polymer-supported metallocene catalyst , 1997 .

[8]  A. Lough,et al.  η3-, η4- and η6-Co-ordination complexes of the weakly co-ordinating anion tetrakis[3,5-bis(trifluoromethyl)phenyl]borate , 1997 .

[9]  Walter Kaminsky,et al.  New polymers by metallocene catalysis , 1996 .

[10]  S. Bott,et al.  Alumoxanes as Cocatalysts in the Palladium-Catalyzed Copolymerization of Carbon Monoxide and Ethylene: Genesis of a Structure−Activity Relationship , 1996 .

[11]  G. Hlatky,et al.  Supported Ionic Metallocene Polymerization Catalysts , 1996 .

[12]  H. Sinn.  Proposals for structure and effect of methylalumoxane based on mass balances and phase separation experiments , 1995 .

[13]  R. Mülhaupt,et al.  Modified syndiotactic polypropene: Poly(propene-co-octene) and blends with atactic oligopropene , 1995 .

[14]  H. Cherdron,et al.  Cycloolefin-copolymere: Eine neue klasse transparenter thermoplaste† , 1994 .

[15]  B. Bachmann,et al.  The Influence of Aromatic Substituents on the Polymerization Behavior of Bridged Zirconocene Catalysts , 1994 .

[16]  P. Montag,et al.  Elementary processes of the Ziegler catalysis, 7. Ethylene, α‐olefin and norbornene copolymerization with the stereorigid catalyst systems ipr[flucp]zrcl2/mao and me2si[ind]2zrcl2/mao , 1993 .

[17]  J. Eisch,et al.  Organometallic compounds of Group III. 52. Active sites for ethylene polymerization with titanium(IV) catalysts in homogeneous media: multinuclear NMR study of ion-pair equilibria and their relation to catalyst activity , 1993 .

[18]  U. Thewalt,et al.  Zirkonocenkomplexe mit einem funktionalisierten Cyclopentadienylliganden. Molekülstruktur von (η5-C5H5)(η5:η2-C5H4CMe2C9H7)Zr(PMe3) , 1993 .

[19]  W. Kaminsky,et al.  Polymerization of olefins in the presence of metal powders with homogeneous catalysts , 1993 .

[20]  W. Kaminsky,et al.  High melting polypropenes by silica‐supported zirconocene catalysts , 1993 .

[21]  K. Soga,et al.  Polymerization of propene with the heterogeneous catalyst system Et[IndH4]2ZrCl2/MAO/SiO2 combined with trialkylaluminium , 1992 .

[22]  Tobin J. Marks,et al.  Group 4 metallocene-alumoxane olefin polymerization catalysts. CPMAS-NMR spectroscopic observation of cation-like zirconocene alkyls , 1992 .

[23]  Scott Collins,et al.  The microstructure of poly(cyclopentene) produced by polymerization of cyclopentene with homogeneous Ziegler-Natta catalysts , 1992 .

[24]  J. Chien,et al.  Olefin copolymerization with metallocene catalysts. III. Supported metallocene/methylaluminoxane catalyst for olefin copolymerization , 1991 .

[25]  W. Kaminsky,et al.  New polymers by homogenous zirconocene/aluminoxane catalysts , 1991 .

[26]  G. Coates,et al.  Enantioselective cyclopolymerization: optically active poly(methylene-1,3-cyclopentane) , 1991 .

[27]  K. Soga,et al.  Polymerization of propene with the catalyst systems composed of Al2O3‐ or MgCl2‐supported Et[IndH4]2ZrCl2 and AlR3 (R = CH3, C2H5) , 1991 .

[28]  W. Kaminsky,et al.  Asymmetric Oligomerization of Propene and 1-Butene with a Zirconocene/Alumoxane Catalyst†‡ , 1989 .

[29]  W. Kaminsky,et al.  Asymmetrische Oligomerisation von Propen und 1‐Buten mit einem Zirconocen/Aluminoxan‐Katalysator , 1989 .

[30]  C. Pellecchia,et al.  Soluble catalysts for syndiotactic polymerization of styrene , 1989 .

[31]  W. Kaminsky,et al.  Copolymerization of cycloalkenes with ethylene in presence of chiral zirconocene catalysts , 1989 .

[32]  N. Ishihara,et al.  Stereospecific polymerization of styrene giving the syndiotactic polymer , 1988 .

[33]  A. Razavi,et al.  Syndiospecific propylene polymerizations with Group IVB metallocenes. , 1988, Journal of the American Chemical Society.

[34]  W. Kaminsky,et al.  Transition metals and organometallics as catalysts for olefin polimerization , 1988 .

[35]  G. C. Ofunne,et al.  Silica-supported cyclopentadienyl-rhodium(I), -cobalt(I), and -titanium(IV) complexes , 1986 .

[36]  R. F. Jordan,et al.  Reactive cationic dicyclopentadienyl zirconium(IV) complexes , 1986 .

[37]  W. Kaminsky,et al.  Polymerization of Propene and Butene with a Chiral Zirconocene and Methylalumoxane as Cocatalyst , 1985 .

[38]  J. Ewen.  Mechanisms of stereochemical control in propylene polymerizations with soluble Group 4B metallocene/methylalumoxane catalysts , 1984 .

[39]  L. Zsolnai,et al.  ansa-Metallocene Derivatives : IV. Synthesis and molecular structures of chiral ansa-titanocene derivatives with bridged tetrahydroindenyl ligands , 1982 .