Spent coffee grounds: A review on current utilization

Abstract Coffee, one of the world’s most popular beverages, carries with it a large economic and environmental burden in the form of spent coffee grounds (SCG), the unutilized portion of the coffee bean left after brewing. However, while currently unrealized, this waste stream has the potential to be converted to various high-value bio-products. Potential uses for SCG range from energy, to nutraceuticals, and construction materials. This paper outlines the possible uses of SCG as a promising green source and reviews the most recent results from studies being done to valorize SCG.

[1]  Mejdi Jeguirim,et al.  Performance and emissions characteristics of compressed spent coffee ground/wood chip logs in a residential stove , 2015 .

[2]  R. Campos-Vega,et al.  Spent coffee grounds, an innovative source of colonic fermentable compounds, inhibit inflammatory mediators in vitro. , 2016, Food chemistry.

[3]  Chin-San Wu Modulation of the interface between polyester and spent coffee grounds in polysaccharide membranes: Preparation, cell proliferation, antioxidant activity and tyrosinase activity. , 2017, Materials science & engineering. C, Materials for biological applications.

[4]  Yu-Shen Cheng,et al.  Optimization of High Solids Dilute Acid Hydrolysis of Spent Coffee Ground at Mild Temperature for Enzymatic Saccharification and Microbial Oil Fermentation , 2016, Applied Biochemistry and Biotechnology.

[5]  S. Pastoriza,et al.  Revalorization of coffee by-products. Prebiotic, antimicrobial and antioxidant properties , 2015 .

[6]  C. P. Neto,et al.  Spent coffee grounds as a renewable source for ecopolyols production , 2015 .

[7]  Stephen J. Livesley,et al.  Applying spent coffee grounds directly to urban agriculture soils greatly reduces plant growth , 2016 .

[8]  G. Bollas,et al.  The effect of temperature, heating rate, and ZSM-5 catalyst on the product selectivity of the fast pyrolysis of spent coffee grounds , 2015 .

[9]  N. E. Dávila-Guzmán,et al.  Copper Biosorption by Spent Coffee Ground: Equilibrium, Kinetics, and Mechanism , 2013 .

[10]  R. Ravindran,et al.  Two-step sequential pretreatment for the enhanced enzymatic hydrolysis of coffee spent waste. , 2017, Bioresource technology.

[11]  Jaai Kim,et al.  Ulva biomass as a co-substrate for stable anaerobic digestion of spent coffee grounds in continuous mode. , 2017, Bioresource technology.

[12]  M. Kaltschmitt,et al.  Oil extracted from spent coffee grounds as a renewable source for fatty acid methyl ester manufacturing , 2012 .

[13]  A. Arulrajah,et al.  Stiffness and deformation properties of spent coffee grounds based geopolymers , 2017 .

[14]  J. Lopes,et al.  Rapid assessment of bioactive phenolics and methylxanthines in spent coffee grounds by FT-NIR spectroscopy. , 2016, Talanta.

[15]  E. Loffredo,et al.  A Two-Step Approach to Eliminate Pesticides and Estrogens from a Wastewater and Reduce Its Phytotoxicity: Adsorption onto Plant-Derived Materials and Fungal Degradation , 2016, Water, Air, & Soil Pollution.

[16]  M. Jeguirim,et al.  Characterization of coffee residues pellets and their performance in a residential combustor , 2016 .

[17]  J. Sargolzaei,et al.  EXTRACTION OF LIPIDS FROM SPENT COFFEE GROUNDS USING ORGANIC SOLVENTS AND SUPERCRITICAL CARBON DIOXIDE , 2013 .

[18]  Synthesis of fatty acid methyl esters via direct transesterification with methanol/carbon dioxide mixtures from spent coffee grounds feedstock , 2011 .

[19]  M. Misra,et al.  Characterization of Wastes and Coproducts from the Coffee Industry for Composite Material Production , 2016 .

[20]  L. Goya,et al.  High Antioxidant Action and Prebiotic Activity of Hydrolyzed Spent Coffee Grounds (HSCG) in a Simulated Digestion-Fermentation Model: Toward the Development of a Novel Food Supplement. , 2017, Journal of agricultural and food chemistry.

[21]  Stanislav Obruca,et al.  Utilization of oil extracted from spent coffee grounds for sustainable production of polyhydroxyalkanoates , 2014, Applied Microbiology and Biotechnology.

[22]  J. Coutinho,et al.  Effect of different rates of spent coffee grounds (SCG) on composting process, gaseous emissions and quality of end-product. , 2017, Waste management.

[23]  A. Arulrajah,et al.  Compressive strength and microstructural properties of spent coffee grounds-bagasse ash based geopolymers with slag supplements , 2017 .

[24]  M. Salavati‐Niasari,et al.  Photodegradation and removal of organic dyes using cui nanostructures, green synthesis and characterization , 2017 .

[25]  R. Agudelo,et al.  Spent coffee ground mass solubilisation by steam explosion and enzymatic hydrolysis , 2015 .

[26]  Fang Yuan,et al.  Antioxidative phenolics obtained from spent coffee grounds (Coffea arabica L.) by subcritical water extraction , 2015 .

[27]  Dong-Wan Cho,et al.  Carbon dioxide assisted sustainability enhancement of pyrolysis of waste biomass: A case study with spent coffee ground. , 2015, Bioresource technology.

[28]  Teresa M. Mata,et al.  Spent coffee grounds for biodiesel production and other applications , 2014, Clean Technologies and Environmental Policy.

[29]  K. Ramalakshmi,et al.  A Perception on Health Benefits of Coffee , 2008, Critical reviews in food science and nutrition.

[30]  J. J. Pis,et al.  Post-combustion CO2 capture adsorbents from spent coffee grounds , 2013 .

[31]  Nancy Elizabeth Dávila Guzmán,et al.  Studies of Adsorption of Heavy Metals onto Spent Coffee Ground: Equilibrium, Regeneration, and Dynamic Performance in a Fixed-Bed Column , 2016 .

[32]  Arul Arulrajah,et al.  Spent Coffee Grounds–Fly Ash Geopolymer Used as an Embankment Structural Fill Material , 2016 .

[33]  M. Hakkarainen,et al.  Coffee Grounds to Multifunctional Quantum Dots: Extreme Nanoenhancers of Polymer Biocomposites. , 2017, ACS applied materials & interfaces.

[34]  Arul Arulrajah,et al.  Engineering and environmental evaluation of spent coffee grounds stabilized with industrial by-products as a road subgrade material , 2016, Clean Technologies and Environmental Policy.

[35]  J. Pereira,et al.  Antioxidant activity and bioactive compounds of lettuce improved by espresso coffee residues. , 2014, Food chemistry.

[36]  W. Kiatkittipong,et al.  Oil extracted from spent coffee grounds for bio-hydrotreated diesel production , 2016 .

[37]  M. Hakkarainen,et al.  Coffee-Ground-Derived Quantum Dots for Aqueous Processable Nanoporous Graphene Membranes , 2017 .

[38]  J. Pereira,et al.  Carotenoids of Lettuce (Lactuca sativa L.) Grown on Soil Enriched with Spent Coffee Grounds , 2012, Molecules.

[39]  M. Salavati‐Niasari,et al.  Green synthesis and characterization of Dy2Ce2O7 ceramic nanostructures with good photocatalytic properties under visible light for removal of organic dyes in water , 2018, Journal of Cleaner Production.

[40]  Leandro S. Oliveira,et al.  Kinetics and equilibrium studies of methylene blue adsorption by spent coffee grounds. , 2009 .

[41]  H. Yen,et al.  Ni(II) removal from wastewater by solar energy-degreased spent coffee grounds , 2016 .

[42]  F. Fernandes,et al.  Ultrasound-assisted production of biodiesel and ethanol from spent coffee grounds. , 2014, Bioresource technology.

[43]  Naif Abdullah Al-Dhabi,et al.  Development and validation of ultrasound-assisted solid-liquid extraction of phenolic compounds from waste spent coffee grounds. , 2017, Ultrasonics sonochemistry.

[44]  H. Yen,et al.  Adsorption of Cd(II) from wastewater using spent coffee grounds by Taguchi optimization , 2016 .

[45]  A. Go,et al.  Recovery of Sugars and Lipids from Spent Coffee Grounds: A New Approach , 2016 .

[46]  S. Mussatto,et al.  Characterization of polysaccharides extracted from spent coffee grounds by alkali pretreatment. , 2015, Carbohydrate polymers.

[47]  C. Saffron,et al.  Pyrolysis of spent coffee grounds using a screw-conveyor reactor , 2015 .

[48]  A. Arulrajah,et al.  Strength and microstructure properties of spent coffee grounds stabilized with rice husk ash and slag geopolymers , 2017 .

[49]  Antonio Zuorro,et al.  Spent coffee grounds as a valuable source of phenolic compounds and bioenergy , 2012 .

[50]  V. Strezov,et al.  Energy recovery potential analysis of spent coffee grounds pyrolysis products , 2014 .

[51]  S. Seo,et al.  Evaluation of nutritional and economic feed values of spent coffee grounds and Artemisia princeps residues as a ruminant feed using in vitro ruminal fermentation , 2015, PeerJ.

[52]  M. Coimbra,et al.  Microwave superheated water extraction of polysaccharides from spent coffee grounds. , 2013, Carbohydrate polymers.

[53]  N. Akgün,et al.  Extraction Behavior of Lipids Obtained from Spent Coffee Grounds Using Supercritical Carbon Dioxide , 2014 .

[54]  Rachel Burton,et al.  Evaluation of Two-Step Reaction and Enzyme Catalysis Approaches for Biodiesel Production from Spent Coffee Grounds , 2010 .

[55]  Solange I. Mussatto,et al.  Growth of fungal strains on coffee industry residues with removal of polyphenolic compounds , 2012 .

[56]  S. Theerakulpisut,et al.  Adsorption characteristics of activated carbon prepared from spent ground coffee , 2016, Clean Technologies and Environmental Policy.

[57]  D. Ronga,et al.  Use of Spent Coffee Ground Compost in Peat-Based Growing Media for the Production of Basil and Tomato Potting Plants , 2016 .

[58]  K. Cheng,et al.  Enrichment of two isoflavone aglycones in black soymilk by using spent coffee grounds as an immobiliser for β-glucosidase. , 2013, Food chemistry.

[59]  Solange I. Mussatto,et al.  A study on chemical constituents and sugars extraction from spent coffee grounds , 2011 .

[60]  Carlos M. Silva,et al.  Supercritical fluid extraction of spent coffee grounds: Measurement of extraction curves, oil characterization and economic analysis , 2014 .

[61]  R. Ravindran,et al.  Evaluation of ultrasound assisted potassium permanganate pre-treatment of spent coffee waste. , 2017, Bioresource technology.

[62]  R. Campos-Vega,et al.  Microbiota source impact in vitro metabolite colonic production and anti-proliferative effect of spent coffee grounds on human colon cancer cells (HT-29). , 2017, Food research international.

[63]  Marta G. Plaza,et al.  Valorisation of spent coffee grounds as CO2 adsorbents for postcombustion capture applications , 2012 .

[64]  Gilberto A. Romeiro,et al.  A study of pyrolysis oil from soluble coffee ground using low temperature conversion (LTC) process , 2012 .

[65]  Nattapong Tuntiwiwattanapun,et al.  The energy usage and environmental impact assessment of spent coffee grounds biodiesel production by an in-situ transesterification process , 2017 .

[66]  Hyeon‐Son Choi,et al.  Topical application of spent coffee ground extracts protects skin from ultraviolet B-induced photoaging in hairless mice , 2016, Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology.

[67]  A. Oladipo,et al.  Bifunctional composite from spent "Cyprus coffee" for tetracycline removal and phenol degradation: Solar-Fenton process and artificial neural network. , 2016, International journal of biological macromolecules.

[68]  Hyeon‐Son Choi,et al.  Spent coffee ground extract suppresses ultraviolet B-induced photoaging in hairless mice. , 2015, Journal of photochemistry and photobiology. B, Biology.

[69]  G. D’Errico,et al.  A Superior All-Natural Antioxidant Biomaterial from Spent Coffee Grounds for Polymer Stabilization, Cell Protection, and Food Lipid Preservation , 2016 .

[70]  W. Hu,et al.  Effect of oil extraction on properties of spent coffee ground–plastic composites , 2016, Journal of Materials Science.

[71]  Lina F. Ballesteros,et al.  Chemical, Functional, and Structural Properties of Spent Coffee Grounds and Coffee Silverskin , 2014, Food and Bioprocess Technology.

[72]  A. Zuorro Optimization of polyphenol recovery from espresso coffee residues using factorial design and response surface methodology , 2015 .

[73]  Diniara Soares,et al.  Bio-syngas production from agro-industrial biomass residues by steam gasification. , 2016, Waste management.

[74]  M. Ferchichi,et al.  Co-composting of spent coffee ground with olive mill wastewater sludge and poultry manure and effect of Trametes versicolor inoculation on the compost maturity. , 2012, Chemosphere.

[75]  S. Šiler-Marinković,et al.  Recovery of (−)-epigallocatechingallate (EGCG) from aqueous solution by selective adsorption onto spent coffee grounds , 2015, European Food Research and Technology.

[76]  S. Mussatto,et al.  Isolation of polyphenols from spent coffee grounds and silverskin by mild hydrothermal pretreatment , 2016, Preparative biochemistry & biotechnology.

[77]  A. Arulrajah,et al.  Recycled glass as a supplementary filler material in spent coffee grounds geopolymers , 2017 .

[78]  Mejdi Jeguirim,et al.  Gaseous products and particulate matter emissions of biomass residential boiler fired with spent coffee grounds pellets , 2013 .

[79]  Sae Byul Kang,et al.  Characteristics of spent coffee ground as a fuel and combustion test in a small boiler (6.5 kW) , 2017 .

[80]  B. Um,et al.  Antioxidative polyphenolics obtained from spent coffee grounds by pressurized liquid extraction , 2017 .

[81]  Arul Arulrajah,et al.  Spent coffee grounds as a non-structural embankment fill material: engineering and environmental considerations , 2014 .

[82]  M. Konsolakis,et al.  Ultrasound-assisted removal of Acid Red 17 using nanosized Fe3O4-loaded coffee waste hydrochar. , 2017, Ultrasonics sonochemistry.

[83]  S. Zafar,et al.  Comparison between Field Effect Transistors and Bipolar Junction Transistors as Transducers in Electrochemical Sensors , 2017, Scientific Reports.

[84]  D. Chidambaram,et al.  Enhancing kinetics of biodiesel production using morpholine , 2016 .

[85]  M. Maraschin,et al.  Supercritical fluid extraction from spent coffee grounds and coffee husks: antioxidant activity and effect of operational variables on extract composition. , 2012, Talanta.

[86]  A. Stalmach,et al.  In vitro studies on the stability in the proximal gastrointestinal tract and bioaccessibility in Caco-2 cells of chlorogenic acids from spent coffee grounds , 2015, International journal of food sciences and nutrition.

[87]  P. Dutournié,et al.  Pyrolysis kinetics and physicochemical properties of agropellets produced from spent ground coffee blended with conventional biomass , 2014 .

[88]  M. Mesías,et al.  Use of spent coffee grounds as food ingredient in bakery products. , 2017, Food chemistry.

[89]  S. Enthaler,et al.  Spent coffee ground as source for hydrocarbon fuels , 2016 .

[90]  Ilker S. Bayer,et al.  Spent Coffee Bioelastomeric Composite Foams for the Removal of Pb2+ and Hg2+ from Water , 2016 .

[91]  Peng Li,et al.  Recovery of Bio-Oil from Industrial Food Waste by Liquefied Dimethyl Ether for Biodiesel Production , 2016 .

[92]  P. Simões,et al.  Supercritical fluid extraction of lipids from spent coffee grounds , 2009 .

[93]  M. Coimbra,et al.  Extractability and structure of spent coffee ground polysaccharides by roasting pre-treatments. , 2013, Carbohydrate polymers.

[94]  Sunil Kumar Ramasahayam,et al.  Phosphorous, nitrogen co‐doped carbon from spent coffee grounds for fuel cell applications , 2015 .

[95]  S. Mussatto,et al.  Production, chemical characterization, and sensory profile of a novel spirit elaborated from spent coffee ground , 2013 .

[96]  Yingjie Dai,et al.  Nitrobenzene-adsorption capacity of NaOH-modified spent coffee ground from aqueous solution , 2016 .

[97]  Jeongseok Park,et al.  In-situ transesterification of wet spent coffee grounds for sustainable biodiesel production. , 2016, Bioresource technology.

[98]  Zhengxiao Guo,et al.  Superior CO2 adsorption from waste coffee ground derived carbons , 2015 .

[99]  J. Görgens,et al.  Application of Endo-β-1,4,d-mannanase and Cellulase for the Release of Mannooligosaccharides from Steam-Pretreated Spent Coffee Ground , 2014, Applied Biochemistry and Biotechnology.

[100]  R. Jenkins,et al.  Production of Biodiesel from Vietnamese Waste Coffee Beans: Biofuel Yield, Saturation and Stability are All Elevated Compared with Conventional Coffee Biodiesel , 2017 .

[101]  J. B. Neris,et al.  Application of coconut shell, banana peel, spent coffee grounds, eucalyptus bark, piassava (Attalea funifera) and water hyacinth (Eichornia crassipes) in the adsorption of Pb2+ and Ni2+ ions in water , 2018 .

[102]  M. Salavati‐Niasari,et al.  Removal of malachite green (a toxic dye) from water by cobalt ferrite silica magnetic nanocomposite: Herbal and green sol-gel autocombustion synthesis , 2017 .

[103]  J. Lopes,et al.  FT-NIR spectroscopy as a tool for valorization of spent coffee grounds: Application to assessment of antioxidant properties , 2013 .

[104]  E. Loffredo,et al.  Adsorptive removal of ascertained and suspected endocrine disruptors from aqueous solution using plant-derived materials , 2017, Environmental Science and Pollution Research.

[105]  D. Kucera,et al.  Biotechnological conversion of spent coffee grounds into polyhydroxyalkanoates and carotenoids. , 2015, New biotechnology.

[106]  R. Campos-Vega,et al.  The fermented non-digestible fraction of spent coffee grounds induces apoptosis in human colon cancer cells (SW480) , 2017 .

[107]  R. Balart,et al.  Green composites based on polypropylene matrix and hydrophobized spend coffee ground (SCG) powder , 2015 .

[108]  I. Márová,et al.  Bioconversion of spent coffee grounds into carotenoids and other valuable metabolites by selected red yeast strains , 2014 .

[109]  R. Lavecchia,et al.  Recovery of natural antioxidants from spent coffee grounds. , 2013, Journal of agricultural and food chemistry.

[110]  H. Gavala,et al.  Integration of chlorogenic acid recovery and bioethanol production from spent coffee grounds , 2016 .

[111]  E. Kwon,et al.  Pyrolysis of FeCl3-pretreated spent coffee grounds using CO2 as a reaction medium , 2016 .

[112]  S. Šiler-Marinković,et al.  Optimization of microwave-assisted extraction of natural antioxidants from spent espresso coffee grounds by response surface methodology , 2014 .

[113]  C. Chuck,et al.  Effect of the Type of Bean, Processing, and Geographical Location on the Biodiesel Produced from Waste Coffee Grounds , 2014 .

[114]  S. Mussatto,et al.  Encapsulation of antioxidant phenolic compounds extracted from spent coffee grounds by freeze-drying and spray-drying using different coating materials. , 2017, Food chemistry.

[115]  P. Flores,et al.  Use of different organic wastes in reducing the potential leaching of propanil, isoxaben, cadusafos and pencycuron through the soil , 2014, Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes.

[116]  Qingshi Tu,et al.  Direct transesterification of spent coffee grounds for biodiesel production , 2017 .

[117]  Y. Jeon,et al.  Sequential co-production of biodiesel and bioethanol with spent coffee grounds. , 2013, Bioresource technology.

[118]  Carlos M. Silva,et al.  Optimization of the supercritical fluid coextraction of oil and diterpenes from spent coffee grounds using experimental design and response surface methodology , 2014 .

[119]  M. Coimbra,et al.  Sequential microwave superheated water extraction of mannans from spent coffee grounds. , 2014, Carbohydrate polymers.

[120]  S. Mussatto,et al.  Extraction of antioxidant phenolic compounds from spent coffee grounds , 2011 .

[121]  A. Brandelli,et al.  Total Polyphenols, Antioxidant, Antimicrobial and Allelopathic Activities of Spend Coffee Ground Aqueous Extract , 2017 .

[122]  M. Reis,et al.  Production of polyhydroxyalkanoates from spent coffee grounds oil obtained by supercritical fluid extraction technology. , 2014, Bioresource technology.

[123]  D. Makris,et al.  Kinetics of Ultrasound-Assisted Polyphenol Extraction from Spent Filter Coffee Using Aqueous Glycerol , 2016 .

[124]  D. Ahn,et al.  Antioxidant Effect of Extracts from the Coffee Residue in Raw and Cooked Meat , 2016, Antioxidants.

[125]  Wan Aizan Wan Abdul Rahman,et al.  Structural elucidation of tannins of spent coffee grounds by CP-MAS 13C NMR and MALDI-TOF MS , 2015 .

[126]  T. Astatkie,et al.  Hydrothermal liquefaction of biomass model components for product yield prediction and reaction pathways exploration , 2018, Applied Energy.

[127]  P. Simões,et al.  The green generation of sunscreens: Using coffee industrial sub-products , 2016 .

[128]  K. Corscadden,et al.  Co-liquefaction of spent coffee grounds and lignocellulosic feedstocks. , 2017, Bioresource technology.

[129]  M. P. Morales,et al.  Eco-fired clay bricks made by adding spent coffee grounds: a sustainable way to improve buildings insulation , 2016 .

[130]  B. Chun,et al.  Influence of pretreatment and modifiers on subcritical water liquefaction of spent coffee grounds: A green waste valorization approach , 2017 .

[131]  M. Salavati‐Niasari,et al.  Synthesis of graphene quantum dots from corn powder and their application in reduce charge recombination and increase free charge carriers , 2017 .

[132]  J. Pereira,et al.  Revalorization of spent coffee residues by a direct agronomic approach , 2015 .

[133]  Sanghun Lee,et al.  The effectiveness of spent coffee grounds and its biochar on the amelioration of heavy metals-contaminated water and soil using chemical and biological assessments. , 2014, Journal of environmental management.

[134]  S. Mussatto,et al.  Optimization of autohydrolysis conditions to extract antioxidant phenolic compounds from spent coffee grounds , 2017 .

[135]  S. Shen,et al.  Strength assessment of spent coffee grounds-geopolymer cement utilizing slag and fly ash precursors , 2016 .

[136]  J. Simão,et al.  Reusing coffee waste in manufacture of ceramics for construction , 2014 .

[137]  Jaai Kim,et al.  Anaerobic co-digestion of spent coffee grounds with different waste feedstocks for biogas production. , 2017, Waste management.

[138]  D. Wiesenborn,et al.  In-situ transesterification process for biodiesel production using spent coffee grounds from the instant coffee industry , 2017 .

[139]  Stanislav Obruca,et al.  Production of polyhydroxyalkanoates using hydrolysate of spent coffee grounds , 2014 .

[140]  Y. Ok,et al.  Minireview of potential applications of hydrochar derived from hydrothermal carbonization of biomass , 2018 .

[141]  K. Corscadden,et al.  Hydrothermal liquefaction of spent coffee grounds in water medium for bio-oil production , 2016 .

[142]  J. Pereira,et al.  Improvement of vegetables elemental quality by espresso coffee residues. , 2014, Food chemistry.

[143]  J. Görgens,et al.  Enzymatic Hydrolysis of Spent Coffee Ground , 2013, Applied Biochemistry and Biotechnology.

[144]  Xiaodong Ma,et al.  Adsorption properties of biomass-based activated carbon prepared with spent coffee grounds and pomelo skin by phosphoric acid activation , 2013 .

[145]  F. Acevedo,et al.  Spent Coffee Grounds as a Renewable Source of Bioactive Compounds , 2013 .

[146]  Y. Song,et al.  Green nanocomposites filled with spent coffee grounds , 2015 .

[147]  K. Liu,et al.  Evaluation of three composting systems for the management of spent coffee grounds. , 2011, Bioresource technology.

[148]  R. Gambari,et al.  Preparation and characterization of bio-safe activated charcoal derived from coffee waste residue and its application for removal of lead and copper ions , 2014 .

[149]  S. Mussatto,et al.  Sugars metabolism and ethanol production by different yeast strains from coffee industry wastes hydrolysates , 2012 .

[150]  L. Were,et al.  Antioxidant effect of spent, ground, and lyophilized brew from roasted coffee in frozen cooked pork patties , 2016 .

[151]  Sunil Kumar Ramasahayam,et al.  Spent coffee grounds derived P, N co-doped C as electrocatalyst for supercapacitor applications , 2015 .

[152]  Vesna Najdanovic-Visak,et al.  Kinetics of extraction and in situ transesterification of oils from spent coffee grounds , 2017 .

[153]  Chin-San Wu Renewable resource-based green composites of surface-treated spent coffee grounds and polylactide: Characterisation and biodegradability , 2015 .

[154]  C. Jeon Adsorption and recovery of immobilized coffee ground beads for silver ions from industrial wastewater , 2017 .

[155]  S. Hanini,et al.  Biosorption of strontium from aqueous solutions onto spent coffee grounds , 2013, Journal of Radioanalytical and Nuclear Chemistry.

[156]  Solange I. Mussatto,et al.  Production, Composition, and Application of Coffee and Its Industrial Residues , 2011 .

[157]  Wan Aizan Wan Abdul Rahman,et al.  The influence of extraction parameters on spent coffee grounds as a renewable tannin resource , 2015 .

[158]  Hang Seok Choi,et al.  Fast pyrolysis of coffee grounds: Characteristics of product yields and biocrude oil quality , 2011 .

[159]  I. Safarik,et al.  Magnetically modified spent coffee grounds for dyes removal , 2012, European Food Research and Technology.

[160]  A. Fiore,et al.  Ultrasound-assisted extraction to improve the recovery of phenols and antioxidants from spent espresso coffee ground: a study by response surface methodology and desirability approach , 2017, European Food Research and Technology.

[161]  Yuanhang Wei,et al.  Experimental investigation on the oxy-fuel co-combustion behavior of anthracite coal and spent coffee grounds , 2016, Journal of Thermal Analysis and Calorimetry.

[162]  A. Dector,et al.  A semi-conducting polypyrrole/coffee grounds waste composite for rhodamine B dye adsorption , 2018, Iranian Polymer Journal.

[163]  Helena Ribeiro,et al.  From coffee industry waste materials to skin-friendly products with improved skin fat levels , 2013 .

[164]  T. Bandosz,et al.  Spent coffee-based activated carbon: specific surface features and their importance for H2S separation process. , 2012, Journal of hazardous materials.

[165]  Kyu-Hong Ahn,et al.  Fabrication of granular activated carbons derived from spent coffee grounds by entrapment in calcium alginate beads for adsorption of acid orange 7 and methylene blue. , 2016, Bioresource technology.