Effect of Extreme Pressure Additives on the Deformation Behavior of Oxide Scale during the Hot Rolling of Ferritic Stainless Steel Strips

High-speed steel (HSS) materials are universally used as work rolls for the hot rolling of stainless steels. Their use has increased the output of the rolling mill and decreased roll material consumption and grinding. Sticking defects often occur, however, during the hot rolling process. In this article, extreme pressure (EP) additives were dropped on the HSS samples at high temperature. Zinc dialkyl dithiophosphate (ZDDP) was chosen as the most effective EP additive by scratch tests on the HSS samples. In order to determine the optimum proportion of ZDDP in the lubricant, two reduction rates were tested on a Hille 100 experimental rolling mill by hot rolling ferritic stainless steel 445J1M at five different concentrations of ZDDP. The mechanism of EP additive action during the hot rolling process was also investigated. By analyzing the deformation behavior of the oxide scale of samples after hot rolling using different proportions of ZDDP, it was found that 20% ZDDP in the lubricant is the preferred concentration for industrial application.

[1]  Mohammed Azmi Al-Betar,et al.  comprehensive review : Krill Herd algorithm ( KH ) and its pplications saju , 2016 .

[2]  Ibrahim Dauda Muhammad,et al.  Characterisation of blaTEM genes and types of β-lactamase plasmids in Neisseria gonorrhoeae – the prevalent and conserved blaTEM-135 has not recently evolved and existed in the Toronto plasmid from the origin , 2014, BMC Infectious Diseases.

[3]  M. Grahn,et al.  Effect of ZDDP on friction in fretting contacts , 2011 .

[4]  W. M. Rainforth,et al.  High Temperature Oxidation of a Work Roll Grade High Speed Steel , 2011 .

[5]  Itzhak Green,et al.  On the Modeling of Elastic Contact between Rough Surfaces , 2011 .

[6]  J. Han,et al.  Test research on sticking mechanism during hot rolling of SUS 430 ferritic stainless steel , 2010 .

[7]  Keishi Matsumoto,et al.  Tribological Properties of Water Glass Lubricant for Hot Metalworking , 2009 .

[8]  Sunghak Lee,et al.  Analysis and prevention of sticking occurring during hot rolling of ferritic stainless steel , 2009 .

[9]  D. J. Ha,et al.  Effects of Alloying Elements on Sticking Behavior Occurring during Hot Rolling of Modified Ferritic STS430J1L Stainless Steels , 2009 .

[10]  J. Tse,et al.  Effects of Temperature and Pressure on ZDDP , 2007 .

[11]  J. M. Martín,et al.  Formation Mechanism of a Low Friction ZDDP Tribofilm on Iron Oxide , 2007 .

[12]  Zhengyi Jiang,et al.  Characterisation of thin oxide scale and its surface roughness in hot metal rolling , 2006 .

[13]  M. Müser,et al.  Interpretation of experiments on ZDDP anti-wear films through pressure-induced cross-linking , 2006 .

[14]  Zhengyi Jiang,et al.  Modelling of oxide scale surface roughness in hot metal forming , 2006 .

[15]  K. Holmberg,et al.  Tribological contact analysis of a rigid ball sliding on a hard coated surface. Part I: Modelling stresses and strains , 2006 .

[16]  Hugh Spikes,et al.  Study of Zinc Dialkydithiophosphate Antiwear Film Formation and Removal Processes, Part I: Experimental , 2005 .

[17]  R. Chen,et al.  Examination of Oxide Scales of Hot Rolled Steel Products , 2005 .

[18]  J. Lim,et al.  Oxidation Behavior of High-speed Steels in Dry and Wet Atmospheres , 2003 .

[19]  G. Bancroft,et al.  X-ray Absorption Spectroscopy and Atomic Force Microscopy of Films Generated from Organosulfur Extreme-Pressure (EP) Oil Additives , 2003 .

[20]  Keith D. Bartle,et al.  A review of zinc dialkyldithiophosphates (ZDDPS): characterisation and role in the lubricating oil , 2001 .

[21]  J. Choi,et al.  Nucleation and Growth Process of Sticking Particles in Ferritic Stainless Steel , 2000 .

[22]  J. Choi,et al.  Effect of Roll and Rolling Temperatures on Sticking Behavior of Ferritic Stainless Steels , 1998 .

[23]  W. Jin,et al.  Sticking mechanism during hot rolling of two stainless steels , 1998 .

[24]  Donald W. Brenner,et al.  Effect of atomic-scale surface roughness on friction: a molecular dynamics study of diamond surfaces , 1993 .

[25]  P. Harrison,et al.  External reflection FTIR, 31P MAS NMR and SEM study of the thermal decomposition of zinc(II) bis(O,O'-dialkyldithiophosphates) on 316 stainless steel , 1991 .

[26]  I. S. Morton DEVELOPMENT TESTING OF METALWORKING LUBRICANTS , 1972 .

[27]  E. S. Forbes The load-carrying action of organo-sulphur compounds—A review☆ , 1970 .

[28]  N. Perez High-Temperature Oxidation , 2016 .

[29]  Zhengyi Jiang,et al.  Effect of extreme pressure agents on the anti-scratch behaviour of high-speed steel material , 2015 .

[30]  S. Q. Rizvi A Comprehensive Review of Lubricant Chemistry, Technology, Selection, and Design , 2009 .

[31]  Neil Canter,et al.  The tribological challenges of high-speed machining , 2007 .

[32]  John G. Lenard,et al.  The effect of lubrication on mill loads during hot rolling of low carbon steel strips , 2000 .

[33]  R. R. Dils,et al.  High‐Temperature Oxidation II . Molybdenum Silicides , 1964 .