Electrochemical Modeling and Equivalent Circuit Representation of a Microphotosynthetic Power Cell

This paper discusses the electrochemical modeling of a microphotosynthetic power cell (μ-PSC) in a similar way as the conventional fuel cell model while taking into consideration the electrochemical dynamics of the chemical contents of the cell. It also presents the development of an electrical equivalent circuit that represents the operation of the fabricated cell. The developed equivalent circuit is different from previous works in which they used the equivalent circuit of an ordinary solar cell. The proposed model predicts the performance of this type of power harvesting cell. The study includes the steady-state and transient responses when the cell is connected to an external load. In particular, the focus of this paper is related to the development of an electrical representation with a computationally efficient parameter model for real-time simulation and control. The performance of this model is simulated and results are evaluated and compared with experimental data.

[1]  Mu Chiao,et al.  A Microfabricated PDMS Microbial Fuel Cell , 2008, Journal of Microelectromechanical Systems.

[2]  Carlos Andrés Ramos-Paja,et al.  A PEM Fuel-Cell Model Featuring Oxygen-Excess-Ratio Estimation and Power-Electronics Interaction , 2010, IEEE Transactions on Industrial Electronics.

[3]  Bruno Allard,et al.  Optimal Energy Harvesting From Serially Connected Microbial Fuel Cells , 2015, IEEE Transactions on Industrial Electronics.

[4]  Bo-Hyung Cho,et al.  Equivalent Circuit Modeling of PEM Fuel Cell Degradation Combined With a LFRC , 2013, IEEE Transactions on Industrial Electronics.

[5]  Mehdi Shahparnia,et al.  Polymer Micro Photosynthetic Power Cell: Design, Fabrication, Parametric Study and Testing , 2011 .

[6]  R. Alberty Thermodynamics of Biochemical Reactions: Alberty/Thermodynamics , 2005 .

[7]  Sheldon S. Williamson,et al.  Advanced Fabrication, Modeling, and Testing of a Microphotosynthetic Electrochemical Cell for Energy Harvesting Applications , 2015, IEEE Transactions on Power Electronics.

[8]  Raghunathan Rengaswamy,et al.  Solid Oxide Fuel Cell Modeling , 2009, IEEE Transactions on Industrial Electronics.

[9]  Shehab Ahmed,et al.  PEM Fuel Cell Stack Model Development for Real-Time Simulation Applications , 2011, IEEE Transactions on Industrial Electronics.

[10]  Muthukumaran Packirisamy,et al.  Micro photosynthetic power cell for power generation from photosynthesis of algae , 2015 .

[11]  Stéphan Astier,et al.  A Large-Signal and Dynamic Circuit Model of a $\hbox{H}_{2}/\hbox{O}_{2}$ PEM Fuel Cell: Description, Parameter Identification, and Exploitation , 2010, IEEE Transactions on Industrial Electronics.

[12]  Tom Markvart,et al.  Solar cell model for electron transport in photosynthesis , 2002, Conference Record of the Twenty-Ninth IEEE Photovoltaic Specialists Conference, 2002..

[13]  Pragasen Pillay,et al.  Implementation of Fuel Cell Emulation on DSP and dSPACE Controllers in the Design of Power Electronic Converters , 2010 .

[14]  Tonio Buonassisi,et al.  Modeling integrated photovoltaic–electrochemical devices using steady-state equivalent circuits , 2013, Proceedings of the National Academy of Sciences.

[15]  Mu Chiao,et al.  Micromachined microbial and photosynthetic fuel cells , 2006 .

[16]  A. Feliachi,et al.  Dynamic and transient analysis of power distribution systems with fuel Cells-part I: fuel-cell dynamic model , 2004, IEEE Transactions on Energy Conversion.

[17]  D. A. Noren,et al.  Clarifying the Butler–Volmer equation and related approximations for calculating activation losses in solid oxide fuel cell models , 2005 .

[18]  K. B. Lam,et al.  A bio-solar cell powered by sub-cellular plant photosystems , 2004, 17th IEEE International Conference on Micro Electro Mechanical Systems. Maastricht MEMS 2004 Technical Digest.

[19]  M. Chiao,et al.  A MEMS Photosynthetic Electrochemical Cell Powered by Subcellular Plant Photosystems , 2006, Journal of Microelectromechanical Systems.

[20]  Colleen Spiegel,et al.  PEM Fuel Cell Modeling and Simulation Using Matlab , 2008 .

[21]  Mu Chiao,et al.  A micro photosynthetic electrochemical cell , 2003, The Sixteenth Annual International Conference on Micro Electro Mechanical Systems, 2003. MEMS-03 Kyoto. IEEE.

[22]  Pragasen Pillay,et al.  Online Diagnostics of HTPEM Fuel Cells Using Small Amplitude Transient Analysis for CO Poisoning , 2015, IEEE Transactions on Industrial Electronics.

[23]  Massimo Guarnieri,et al.  A Dynamic Circuit Model of a Small Direct Methanol Fuel Cell for Portable Electronic Devices , 2010, IEEE Transactions on Industrial Electronics.

[24]  C. H. Bartholomew,et al.  Hydrogen Production and Fuel Cells: Catalyst Technology , 2010 .

[25]  Bruce E. Logan,et al.  Microbial Fuel Cells , 2006 .

[26]  Carlos Bordons,et al.  Real-Time Implementation of a Constrained MPC for Efficient Airflow Control in a PEM Fuel Cell , 2010, IEEE Transactions on Industrial Electronics.

[27]  Seokheun Choi,et al.  A micro-sized bio-solar cell for self-sustaining power generation. , 2015, Lab on a chip.

[28]  Raghunathan Rengaswamy,et al.  Classification of High-Temperature PEM Fuel Cell Degradation Mechanisms Using Equivalent Circuits , 2015, IEEE Transactions on Industrial Electronics.