Composition, strength and workability of alkali-activated metakaolin based mortars

This study has investigated the joint effect of several factors on the workability and mechanical strength of alkali-activated metakaolin based mortars. The factors analysed through a laboratory experiment of 432 specimens, pertaining to 48 different mortar mixes were, sodium hydroxide concentration (10 M, 12 M, 14 M, 16 M), the superplasticizer content (1%, 2%, 3%) and the percentage substitution of metakaolin by calcium hydroxide in the mixture (5%, 10%). The results show that the workability decreases with the concentration of sodium hydroxide and increases with the amount of calcium hydroxide and superplasticizer. The results also show that the use of 3% of superplasticizer, combined with a calcium hydroxide content of 10%, allows improving the mortar flow from less than 50% to over 90%, while maintaining a high compressive and flexural strength.

[1]  F. Puertas,et al.  Effect of Superplasticizer and Shrinkage-Reducing Admixtures on Alkali-Activated Slag Pastes and Mortars , 2005 .

[2]  E. Gartner Industrially interesting approaches to “low-CO2” cements ☆ , 2004 .

[3]  Fernando Pacheco-Torgal,et al.  Alkali-activated binders: A review. Part 2. About materials and binders manufacture , 2008 .

[4]  B. V. Rangan,et al.  Engineering properties of geopolymer concrete , 2009 .

[5]  Prinya Chindaprasirt,et al.  Influence of NaOH solution on the synthesis of fly ash geopolymer , 2009 .

[6]  J. Deventer,et al.  The effects of inorganic salt contamination on the strength and durability of geopolymers , 2002 .

[7]  Anja Buchwald,et al.  Life-cycle analysis of geopolymers , 2009 .

[8]  J. Palutikof,et al.  Climate change 2007 : impacts, adaptation and vulnerability , 2001 .

[9]  Fernando Pacheco-Torgal,et al.  Investigations on mix design of tungsten mine waste geopolymeric binder , 2008 .

[10]  J. Deventer,et al.  The Role of Inorganic Polymer Technology in the Development of ‘Green Concrete’ , 2007 .

[11]  Cynthia Rosenzweig,et al.  Assessment of observed changes and responses in natural and managed systems , 2007 .

[12]  Fernando Pacheco-Torgal,et al.  Adhesion characterization of tungsten mine waste geopolymeric binder. Influence of OPC concrete substrate surface treatment , 2008 .

[13]  Prinya Chindaprasirt,et al.  Workability and strength of lignite bottom ash geopolymer mortar. , 2009, Journal of hazardous materials.

[14]  Fernando Pacheco-Torgal,et al.  Alkali-activated binders: A review: Part 1. Historical background, terminology, reaction mechanisms and hydration products , 2008 .

[15]  Duncan Herfort,et al.  Sustainable Development and Climate Change Initiatives , 2008 .

[16]  J. Deventer,et al.  Commercialization of geopolymers for construction – opportunities and obstacles , 2009 .

[17]  P. Chindaprasirt,et al.  Comparative study on the characteristics of fly ash and bottom ash geopolymers. , 2009, Waste management.

[18]  V. Sirivivatnanon,et al.  Workability and strength of coarse high calcium fly ash geopolymer , 2007 .

[19]  F. Pacheco-Torgal,et al.  Tungsten mine waste geopolymeric binder: Preliminary hydration products investigations , 2009 .

[20]  Fernando Pacheco-Torgal,et al.  Investigations about the effect of aggregates on strength and microstructure of geopolymeric mine waste mud binders , 2007 .