Making fine chemicals, nanomaterials and pharmaceutical ingredients over SiliaCat catalysts

Abstract Referring to selected independent research achievements using sol-gel organosilica catalysts of the SiliaCat series to make fine chemicals, nanomaterials and active pharmaceutical ingredients, we suggest avenues to incorporate these and related sol-gel catalytic materials in green chemistry courses aimed to foster innovation and practical uptake of heterogeneous catalysis as a key green chemistry technology.

[1]  D. Avnir,et al.  Better Catalysis with Organically Modified Sol–Gel Materials , 2015 .

[2]  S. Kuhn,et al.  Strategies for solids handling in microreactors , 2014 .

[3]  M. Pagliaro.  An industry in transition: The chemical industry and the megatrends driving its forthcoming transformation. , 2019, Angewandte Chemie.

[4]  C. Perry.  Telaprevir , 2012, Drugs.

[5]  W. Heggie,et al.  Genotoxic Impurities in Pharmaceutical Manufacturing: Sources, Regulations, and Mitigation. , 2015, Chemical reviews.

[6]  O. Piermatti,et al.  Strategies to Immobilized Catalysts , 2020 .

[7]  M. Reetz,et al.  Second Generation Sol‐Gel Encapsulated Lipases: Robust Heterogeneous Biocatalysts , 2003 .

[8]  G. Marosi,et al.  Immobilization engineering – How to design advanced sol–gel systems for biocatalysis? , 2017 .

[9]  M. Pagliaro.  Chemistry Education Fostering Creativity in the Digital Era , 2018, Israel Journal of Chemistry.

[10]  C. Risko,et al.  An unsymmetrical non-fullerene acceptor: synthesis via direct heteroarylation, self-assembly, and utility as a low energy absorber in organic photovoltaic cells. , 2017, Chemical communications.

[11]  Christopher G. Frost,et al.  Heterogeneous catalytic synthesis using microreactor technology , 2010 .

[12]  V. Pandarus,et al.  SiliaCat® S-Pd and SiliaCat DPP-Pd: Highly Reactive and Reusable Heterogeneous Silica-Based Palladium Catalysts , 2010 .

[13]  Yanming Sun,et al.  A tetrameric perylene diimide non-fullerene acceptor via unprecedented direct (hetero)arylation cross-coupling reactions. , 2018, Chemical communications.

[14]  L. Ilharco,et al.  Role of the Alkyl−Alkoxide Precursor on the Structure and Catalytic Properties of Hybrid Sol−Gel Catalysts , 2005 .

[15]  M. Reetz,et al.  Efficient Heterogeneous Biocatalysts by Entrapment of Lipases in Hydrophobic Sol–Gel Materials , 1995 .

[16]  B. Karimi,et al.  Recent Progress in Design and Application of Functional Ordered/Periodic Mesoporous Silicas (OMSs) and Organosilicas (PMOs) as Catalyst Support in Carbon-Carbon Coupling Reactions , 2016 .

[17]  Herman van Bekkum,et al.  Highly selective nitroxyl radical-mediated oxidation of primary alcohol groups in water-soluble glucans , 1995 .

[18]  David Avnir,et al.  Organic Chemistry within Ceramic Matrixes: Doped Sol-Gel Materials , 1995 .

[19]  N. Kang,et al.  One-Pot Method of Synthesizing TEMPO-Oxidized Bacterial Cellulose Nanofibers Using Immobilized TEMPO for Skincare Applications , 2019, Polymers.

[20]  G. Welch,et al.  Optimized synthesis of π-extended squaraine dyes relevant to organic electronics by direct (hetero)arylation and Sonogashira coupling reactions. , 2017, Organic & biomolecular chemistry.

[21]  D. Zhao,et al.  Mesoporous Organosilica Hollow Nanoparticles: Synthesis and Applications , 2018, Advanced materials.

[22]  N. Zhang,et al.  Waltzing with the Versatile Platform of Graphene to Synthesize Composite Photocatalysts. , 2015, Chemical reviews.

[23]  D. Avnir,et al.  Entrapment of enzymes in silica aerogels , 2020 .

[24]  R. Sheldon,et al.  Towards greener solvents for the bleach oxidation of alcohols catalysed by stable N-oxy radicals , 2011 .

[25]  C. Bolm,et al.  Sol‐Gel Ormosils Doped with TEMPO as Recyclable Catalysts for the Selective Oxidation of Alcohols , 2002 .

[26]  Gregory C. Welch,et al.  Development of Organic Dye-Based Molecular Materials for Use in Fullerene-Free Organic Solar Cells. , 2018, Chemical record.