Atmospheric aerosol monitoring as a strategy for the preventive conservation of urban monumental heritage: The Florence Baptistery

The over time a knowledge of atmospheric aerosol composition near monuments has become an increasingly important issue in preservation strategies. Concerning the protection of outdoor monumental heritage against urban air pollution, scientific works have mainly focused on the composition of background urban aerosol. In the literature the importance of atmospheric pollutant monitoring close to monuments is not yet sufficiently emphasized. In order to fill this gap, the atmosphere in proximity of the Florence Baptistery was monitored throughout 2003. Aerosol samples were collected close to two of the three doors, characterized by different exposures to pollutant sources. The non-carbonate carbon and soluble ions in the total suspended matter were measured. The paper presents and discusses the comparison between the analytical data obtained from the different sampling sites on the same monument. The results obtained may provide a contribution to the formulation of guidelines for a suitable safeguard of cultural heritage.

[1]  S Nava,et al.  An integrated approach to assess air pollution threats to cultural heritage in a semi-confined environment: the case study of Michelozzo's Courtyard in Florence (Italy). , 2010, The Science of the total environment.

[2]  Eduardo Sebastian,et al.  Role of particulate matter from vehicle exhaust on porous building stones (limestone) sulfation , 1996 .

[3]  H. Cachier,et al.  Beijing aerosol: Atmospheric interactions and new trends , 2007 .

[4]  A. A. Mikhailov,et al.  Improvement of the ISO classification system based on dose-response functions describing the corrosivity of outdoor atmospheres , 2002 .

[5]  J. G. Irwin,et al.  Preliminary results from the analysis of stone tablets from the National Materials Exposure Programme (NMEP) , 1992 .

[6]  Martin Beniston,et al.  The 2003 heat wave as an example of summers in a greenhouse climate? Observations and climate model simulations for Basel, Switzerland , 2004 .

[7]  Katerina Kreislova,et al.  UN ECE ICP Materials: Dose-Response Functions on Dry and Wet Acid Deposition Effects After 8 Years of Exposure , 2001 .

[8]  R. Grima,et al.  Shelters over the Megalithic Temples of Malta: debate, design and implementation , 2011 .

[9]  OXIDATION OF SO2 IN DROPLETS WHICH CONTAIN SOOT PARTICLES , 1982 .

[10]  P. Artaxo,et al.  Aerosol emissions by tropical forest and savanna biomass burning: Characteristic trace elements and fluxes , 1995 .

[11]  C. Saiz-Jimenez,et al.  Aerosols characterization and sources in different European urban atmospheres: Paris, Seville, Florence and Milan , 2004 .

[12]  M. Rebetez.  Summer 2003 maximum and minimum daily temperatures over a 3300 m altitudinal range in the Alps , 2004 .

[13]  Cristina Sabbioni,et al.  Organic anions in damage layers on monuments and buildings , 2003 .

[14]  J. Tidblad,et al.  The Classification System of ISO 9223 Standard and the Dose–Response Functions Assessing the Corrosivity of Outdoor Atmospheres , 2004 .

[15]  P. A. Baedecker,et al.  Effects of acidic deposition on the erosion of carbonate stone — experimental results from the U.S. National Acid Precipitation Assessment Program (NAPAP) , 1992 .

[16]  Armando C. Duarte,et al.  Atmospheric aerosol and soiling of external surfaces in an urban environment , 1998 .

[17]  Cristina Sabbioni,et al.  Quantitative data on carbon fractions in interpretation of black crusts and soiling on European built heritage , 2005 .

[18]  C. Sabbioni,et al.  Anion determination in damage layers of stone monuments , 1995 .

[19]  A. Bonazza,et al.  The Importance Of Atmospheric ParticleMonitoring In The Protection OfCultural Heritage , 2009 .

[20]  J. Osán,et al.  Characterisation of Individual Aerosol Particles for Atmospheric and Cultural Heritage Studies , 2000 .

[21]  C. Sabbioni,et al.  Sulphite quantification on damaged stones and mortars , 1998 .

[22]  Peter Wåhlin,et al.  A European aerosol phenomenology—1: physical characteristics of particulate matter at kerbside, urban, rural and background sites in Europe , 2004 .

[23]  R. Vecchi,et al.  Characterisation of PM10 and PM2.5 particulate matter in the ambient air of Milan (Italy) , 2001 .

[24]  Peter Brimblecombe,et al.  Aesthetics of simulated soiling patterns on architecture. , 2004, Environmental science & technology.

[25]  V. Furlan,et al.  Experimental study of limestone and sandstone sulphation in polluted realistic conditions: The Lausanne Atmospheric Simulation Chamber (LASC) , 1996 .

[26]  Min Hu,et al.  When aerosol sulfate goes up, so does oxalate: implication for the formation mechanisms of oxalate. , 2005, Environmental science & technology.

[27]  R. Belmont,et al.  Origin of trace elements and inorganic ions in PM10 aerosols to the South of Mexico City , 2007 .

[28]  C Saiz-Jimenez,et al.  Air Pollution and Cultural Heritage , 2004 .