Kinetic modeling of hydrogen adsorption/absorption in thin films on hydrogen‐sensitive field‐effect devices: Observation of large hydrogen‐induced dipoles at the Pd‐SiO2 interface

A kinetic modeling of the hydrogen interaction with a Pd‐SiO2‐Si (Pd‐MOS) device is reported. The model is fitted to a number of experimental results, mainly from mass spectrometric desorption meas ...

[1]  M. Armgarth,et al.  Physics with catalytic metal gate chemical sensors , 1989 .

[2]  M. Eriksson,et al.  Spillover of hydrogen, oxygen and carbon monoxide in oxidation reactions on SiO2 supported Pd , 1994 .

[3]  K. Laidler.  The mechanisms of some elementary surface reactions. , 1949, The Journal of physical and colloid chemistry.

[4]  C. Nylander,et al.  Hydrogen induced drift in palladium gate metal‐oxide‐semiconductor structures , 1984 .

[5]  Ingemar Lundström,et al.  Hydrogen sensitive mos-structures: Part 1: Principles and applications , 1981 .

[6]  Gerhard Ertl,et al.  Adsorption of hydrogen on palladium single crystal surfaces , 1974 .

[7]  Ingemar Lundström,et al.  A hydrogen sensitive Pd-MOS structure working over a wide pressure range , 1984 .

[8]  Gabor A. Somorjai,et al.  Principles of Surface Chemistry , 1973 .

[9]  Ingemar Lundström,et al.  Hydrogen adsorption states at the external and internal palladium surfaces of a palladium‐silicon dioxide‐silicon structure , 1985 .

[10]  I. Lundström,et al.  Reactions between hydrocarbons and an oxygen covered palladium surface , 1988 .

[11]  Klaus Christmann,et al.  Interaction of hydrogen with solid surfaces , 1988 .

[12]  F. Nakao.  Determination of the ionization gauge sensitivity using the relative ionization cross-section , 1975 .

[13]  A. Spetz,et al.  Optimization of ammonia-sensitive metal-oxide-semiconductor structures with platinum gates , 1987 .

[14]  I. Lundström,et al.  Ammonia Dissociation on Oxygen Covered Palladium Studied with a Hydrogen Sensitive Pd-MOS Device , 1987 .

[15]  W. Lanford.  Analysis for hydrogen by nuclear reaction and energy recoil detection , 1992 .

[16]  R. Gasser,et al.  An Introduction to Chemisorption and Catalysis by Metals , 1987 .

[17]  Goodman,et al.  Kinetics of hydrogen absorption by Pd(110). , 1986, Physical review. B, Condensed matter.

[18]  L. Petersson,et al.  NO dissociation on polycrystalline palladium studied with a Pd‐metal‐oxide‐semiconductor structure , 1989 .