Direct Numerical Simulation of Seawater Desalination Based on Ion Concentration Polarization

The problem of water shortage needs to be solved urgently. The membrane-embedded microchannel structure based on the ion concentration polarization (ICP) desalination effect is a potential portable desalination device with low energy consumption and high efficiency. The electroosmotic flow in the microchannel of the cation exchange membrane and the desalination effect of the system are numerically analyzed. The results show that when the horizontal electric field intensity is 2 kV/m and the transmembrane voltage is 400 mV, the desalting efficiency reaches 97.3%. When the electric field strength increases to 20 kV/m, the desalination efficiency is reduced by 2%. In terms of fluid motion, under the action of the transmembrane voltage, two reverse eddy currents are formed on the surface of the membrane due to the opposite electric field and pressure difference on both sides of the membrane, forming a pumping effect. The electromotive force in the channel exhibits significant pressure-flow characteristics with a slip boundary at a speed approximately six times that of a non-membrane microchannel.

[1]  W. Liu,et al.  Accurate Multi-Physics Numerical Analysis of Particle Preconcentration Based on Ion Concentration Polarization , 2017, 1709.01859.

[2]  F. F. Reuss Sur un Nouvel Effet de l'electricite Galvanique , 1809 .

[3]  S. Litster,et al.  Pumping with electroosmosis of the second kind in mesoporous skeletons , 2011 .

[4]  Leonid Shtilman,et al.  Voltage against current curves of cation exchange membranes , 1979 .

[5]  Jian-Sheng Wang,et al.  Continuum transport model of Ogston sieving in patterned nanofilter arrays for separation of rod‐like biomolecules , 2008, Electrophoresis.

[6]  N. Mishchuk,et al.  Concentration polarization of interface and non-linear electrokinetic phenomena. , 2010, Advances in colloid and interface science.

[7]  E. Demekhin,et al.  Direct numerical simulation of electrokinetic instability and transition to chaotic motion , 2013, 1306.4259.

[8]  I. Rubinstein,et al.  Electroconvection at an electrically inhomogeneous permselective membrane surface , 1991 .

[9]  Aditya S. Khair,et al.  Francois Frenkiel Award Talk: Fundamental Aspects of Concentration Polarization Arising from Nonuniform Electrokinetic Transport , 2008 .

[10]  Janko Auerswald,et al.  Micropump based on electroosmosis of the second kind , 2009, Electrophoresis.

[11]  Hsueh-Chia Chang,et al.  Selection of nonequilibrium overlimiting currents: universal depletion layer formation dynamics and vortex instability. , 2008, Physical review letters.

[12]  I. Rubinstein,et al.  Electric fields in and around ion-exchange membranes1 , 1997 .

[13]  Ali Mani,et al.  Overlimiting current and shock electrodialysis in porous media. , 2013, Langmuir : the ACS journal of surfaces and colloids.

[14]  S. Ghosal,et al.  Electroosmosis in a Finite Cylindrical Pore: Simple Models of End Effects , 2014, Langmuir : the ACS journal of surfaces and colloids.

[15]  H. Helmholtz Ueber einige Gesetze der Vertheilung elektrischer Ströme in körperlichen Leitern mit Anwendung auf die thierisch‐elektrischen Versuche , 1853 .

[16]  P. Gascoyne,et al.  Particle separation by dielectrophoresis , 2002, Electrophoresis.

[17]  Jacob K. White,et al.  Direct numerical simulation of electroconvective instability and hysteretic current-voltage response of a permselective membrane. , 2012, Physical review. E, Statistical, nonlinear, and soft matter physics.

[18]  Matthias Wessling,et al.  Concentration polarization with monopolar ion exchange membranes: current-voltage curves and water dissociation , 1999 .

[19]  Sung Jae Kim,et al.  Amplified electrokinetic response by concentration polarization near nanofluidic channel. , 2009, Langmuir : the ACS journal of surfaces and colloids.

[20]  G. Iglesias,et al.  Effect of Solution Composition on the Energy Production by Capacitive Mixing in Membrane-Electrode Assembly , 2014, The journal of physical chemistry. C, Nanomaterials and interfaces.

[21]  S M Rubinstein,et al.  Direct observation of a nonequilibrium electro-osmotic instability. , 2008, Physical review letters.

[22]  A. A. Moya Electrochemical Impedance of Ion-Exchange Membranes in Ternary Solutions with Two Counterions , 2014 .

[23]  G. Whitesides,et al.  Patterning electro-osmotic flow with patterned surface charge. , 2000, Physical review letters.

[24]  Ali Mani,et al.  Direct numerical simulation of electroconvective instability and hydrodynamic chaos near an ion-selective surface , 2013 .

[25]  John Newman,et al.  Double layer structure at the limiting current , 1967 .

[26]  Sung Jae Kim,et al.  Concentration polarization and nonlinear electrokinetic flow near a nanofluidic channel. , 2007, Physical review letters.

[27]  Ali Mani,et al.  Simulation of chaotic electrokinetic transport: performance of commercial software versus custom-built direct numerical simulation codes. , 2015, Journal of colloid and interface science.

[28]  Jongyoon Han,et al.  Shear flow of an electrically charged fluid by ion concentration polarization: scaling laws for electroconvective vortices. , 2013, Physical review letters.

[29]  Anthony Szymczyk,et al.  Pressure-driven ionic transport through nanochannels with inhomogenous charge distributions. , 2010, Langmuir : the ACS journal of surfaces and colloids.

[30]  Hsueh-Chia Chang,et al.  Nanoscale Electrokinetics and Microvortices: How Microhydrodynamics Affects Nanofluidic Ion Flux , 2012 .

[31]  Andreas Bund,et al.  Ion current rectification at nanopores in glass membranes. , 2008, Langmuir : the ACS journal of surfaces and colloids.

[32]  S. Dukhin,et al.  Electrokinetic phenomena of the second kind and their applications , 1991 .

[33]  Sung Jae Kim,et al.  Direct seawater desalination by ion concentration polarization. , 2010, Nature nanotechnology.