Magnetic Properties and Crystal Structure of Binuclear Copper(II) Complexes with 1,3-Bis(hydroxymethyl)-2-imidazolidinethione

Reaction of copper(II) carboxylates with 1,3-bis(hydroxymethyl)-2-imidazolidinethione (H2L) gives a new series of binuclear copper(II) complexes, [Cu(RCOO)(HL)]2 (where R = methyl and substituted phenyl). The magnetic data for the complexes conform to the usual dimer equation with values of −2J ranging from 227–1023 cm−1.

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