Performance and Life Degradation Characteristics Analysis of NCM LIB for BESS

The battery energy storage system (BESS) market is growing rapidly around the world. Lithium Nickel Cobalt Manganese Oxide (LiNiCoMnO2) is attracting attention due to its excellent energy density, high output power, and fast response characteristics. It is being extensively researched and is finding use in many applications, such as in electric vehicles (EV) and energy storage systems (ESS). The performance and lifetime characteristics of a battery change for varying Ni contents. The consideration of these characteristics of a battery allow for a more reliable battery management system (BMS) design. In this study, various experiments and analyses were carried out using a lithium-ion battery (NCM LIB) with differing Ni contents. In particular, the following two combinations were studied: LiNi0.5Co0.2Mn0.3O2(NCM523) and LiNi0.6Co0.2Mn0.2O2 (NCM622). Various analyses were performed, such as C-rate (C-rate is the charge-discharge rate of a battery relative to nominal capacity) performance tests, hybrid pulse power characterization (HPPC), accelerated deterioration experiments, electrochemical impedance spectroscopy (EIS), parameter estimations of battery equivalent circuits through alternating current (AC) and direct current (DC) impedance, and comparative analyses of battery modeling.

[1]  Kyung Soo Kook,et al.  SOC-based Control Strategy of Battery Energy Storage System for Power System Frequency Regulation , 2014 .

[2]  Jiuchun Jiang,et al.  Investigation of path dependence in commercial lithium-ion cells for pure electric bus applications: Aging mechanism identification , 2015 .

[3]  Patrick Willmann,et al.  Effect of cobalt substitution on cationic distribution in LiNi1 − y CoyO2 electrode materials , 1996 .

[4]  Feixiang Wu,et al.  Li-ion battery materials: present and future , 2015 .

[5]  B. Riccò,et al.  Electrical impedance spectroscopy (EIS) for biological analysis and food characterization: a review , 2017 .

[6]  Joeri Van Mierlo,et al.  A combined thermo-electric resistance degradation model for nickel manganese cobalt oxide based lithium-ion cells , 2018 .

[7]  S. J Kwon,et al.  Performance Analysis and Degradation Characteristics of NCM LIB for ESS , 2018 .

[8]  Massimo Ceraolo,et al.  Battery Model Parameter Estimation Using a Layered Technique: An Example Using a Lithium Iron Phosphate Cell , 2013 .

[9]  S. Rangan,et al.  Studies of LiNi0.6Co0.4O2 Cathode Material Prepared by the Citric Acid-Assisted Sol-Gel Method for Lithium Batteries , 1999 .

[10]  J. C. Currie,et al.  Morphology Effects on the Electrochemical Performance of LiNi1 − x Co x O 2 , 1997 .

[11]  Geng Yang,et al.  A Parameter Identification Method for Dynamics of Lithium Iron Phosphate Batteries Based on Step-Change Current Curves and Constant Current Curves , 2016 .

[12]  Hyung-Joo Noh Comparison of the Electrochemical Properties of Layered Structure Li[NixCoyMn1-x-Y]O2 (x = 1/3, 0.5, 0.6, 0.7, 0.8, and 0.85) Cathode Material for Lithium-Ion Batteries , 2013 .

[13]  Søren Knudsen Kær,et al.  Generalized Characterization Methodology for Performance Modelling of Lithium-Ion Batteries , 2016 .

[14]  Hubert A. Gasteiger,et al.  Oxygen Release and Its Effect on the Cycling Stability of LiNixMnyCozO2 (NMC) Cathode Materials for Li-Ion Batteries , 2017 .

[15]  Jinhua Sun,et al.  Electrochemical performance and thermal stability analysis of LiNixCoyMnzO2 cathode based on a composite safety electrolyte. , 2018, Journal of hazardous materials.

[16]  Michael M. Thackeray,et al.  Spinel versus layered structures for lithium cobalt oxide synthesised at 400°C , 1993 .

[17]  H. Takenouti,et al.  Electrochemical Impedance Spectroscopy response study of a commercial graphite-based negative electrode for Li-ion batteries as function of the cell state of charge and ageing , 2017 .

[18]  C. Delmas,et al.  Electrochemical and physical properties of the LixNi1$minus;yCoyO2 phases , 1992 .

[19]  Helmuth Biechl,et al.  Modelling of Li-ion batteries using equivalent circuit diagrams , 2012 .

[20]  Yingchang Yang,et al.  Influences of transition metal on structural and electrochemical properties of Li[NixCoyMnz]O2 (0.6≤x≤0.8) cathode materials for lithium-ion batteries , 2016 .

[21]  Joongpyo Shim,et al.  Characterization of high-power lithium-ion cells during constant current cycling: Part I. Cycle performance and electrochemical diagnostics , 2003 .

[22]  Gregory L. Plett Battery Management Systems , 2015 .

[23]  Michael M. Thackeray,et al.  Structure and electrochemistry of lithium cobalt oxide synthesised at 400°C , 1992 .

[24]  Chong Seung Yoon,et al.  Comparison of the structural and electrochemical properties of layered Li[NixCoyMnz]O2 (x = 1/3, 0.5, 0.6, 0.7, 0.8 and 0.85) cathode material for lithium-ion batteries , 2013 .

[25]  Chong Seung Yoon,et al.  Nanostructured high-energy cathode materials for advanced lithium batteries. , 2012, Nature materials.

[26]  Karim Zaghib,et al.  Comparative Issues of Cathode Materials for Li-Ion Batteries , 2014 .

[27]  S. Lux,et al.  Impedance change and capacity fade of lithium nickel manganese cobalt oxide-based batteries during calendar aging , 2017 .