Previous molecular dynamics (MD) simulations of V-T curves for several polymers are extended to lower temperatures, including through the glass transition. It is demonstrated that these V-T curves can be used to locate volumetric T g reliably. Four polymers, namely, cis-poly(1,3-butadiene), polyisobutylene, atactic polypropylene, and polystyrene were studied, and previously determined MD data for polyethylene (PE) are available. The T g values span a range of 200 K, from 170 to 370 K. The values from the MD V-T curves tend to be displaced, as expected, to somewhat higher temperature than the longer time experimental values. However, the displacements are minor compared to the range of T g values considered. Determination of Tg from MD simulations appears to be a practical procedure. The relation of the MD-determined T g of wholly amorphous PE to experimental values in the semicrystalline environment is discussed