An experimental investigation of class A surface finish of composites made by the resin transfer molding process

Achievement of high class surface finish is important to the high volume automotive industry when using the resin transfer molding (RTM) process for exterior body panels. Chemical cure shrinkage of the polyester resins has a direct impact on the surface finish of RTM molded components. Therefore, resins with low profile additives (LPA) are used to reduce cure shrinkage and improve surface quality of the composite parts. However, little is known about the behaviour of low profile resins during RTM manufacturing and their ultimate effects on the surface quality of molded plaques. In this work, the effects of controlled material and processing parameters on the pressure variations, process cycle times and ultimately on the surface quality of RTM molded components were investigated. Taguchi experimental design techniques were employed to design test matrices and an optimization analysis was performed. Test panels were manufactured using a flat plate steel mold mounted on a press. Pressure sensors were inserted in the mold cavity to monitor pressure variations during different stages of cure and at various locations in the mold cavity. It was found that a critical amount of LPA (10%) was required to push the material against the mold cavity and to compensate for the resin cure shrinkage. A significant increase in pressure was observed during the later stages of resin cure due to the LPA expansion. The pressure increase had a significant effect on the surface roughness of the test samples with higher pressures resulting in better surface finish. A cure gradient was observed for low pressure injections which significantly reduced the maximum pressure levels.

[1]  M. S. Kiasat,et al.  The effect of the addition of a low profile additive on the curing shrinkage of an unsaturated polyester resin , 1999 .

[2]  M. E. Ryan,et al.  Kinetics of epoxy cure: a rapid technique for kinetic parameter estimation , 1979 .

[3]  H.G.S.J. Thuis,et al.  Design, fabrication and testing of a composite bracket for aerospace applications , 1997 .

[4]  L. J. Lee,et al.  Effect of co‐promoter and secondary monomer on shrinkage control of unsaturated polyester (UP)/styrene (St)/low‐profile additive (LPA) systems cured at low temperatures , 2001 .

[5]  C. L. Tucker,et al.  Thermal dispersion in resin transfer molding , 1995 .

[6]  L. J. Lee,et al.  Shrinkage behaviour of low-profile unsaturated polyester resins , 1994 .

[7]  M. Chan-Park,et al.  Tough low profile additives in sheet molding compound , 1996 .

[8]  Larry Lessard,et al.  Cure shrinkage characterization and modeling of a polyester resin containing low profile additives , 2007 .

[9]  L. J. Lee,et al.  Effects of thermoplastic additives on the cure of unsaturated polyester resins , 1991 .

[10]  C. Bucknall,et al.  Mechanism of shrinkage control in polyester resins containing low-profile additives , 1991 .

[11]  L. J. Lee,et al.  Low temperature cure of unsaturated polyester resins with thermoplastic additives: I. Dilatometry and morphology study , 2000 .

[12]  Yan-Jyi Huang,et al.  Volume shrinkage characteristics in the cure of low-shrink unsaturated polyester resins , 1996 .

[13]  L. J. Lee,et al.  Shrinkage control of low-profile unsaturated polyester resins cured at low temperature , 1998 .

[14]  L. J. Lee,et al.  Low temperature cure of unsaturated polyester resins with thermoplastic additives. II. Structure formation and shrinkage control mechanism , 2000 .

[15]  Lars Berglund,et al.  Manufacturing and performance of RTM U-beams , 1997 .

[16]  José Luis Vilas,et al.  Unsaturated polyester resins cure: Kinetic, rheologic, and mechanical‐dynamical analysis. I. Cure kinetics by DSC and TSR , 2001 .

[17]  Gale Morrison The art of aerospace composites , 1999 .

[18]  G. Lebrun,et al.  Experimental investigation of resin temperature and pressure during filling and curring in a flat steel RTM mould , 1996 .

[19]  E. O’Rear,et al.  Effect of Injection Rate and Post-Fill Cure Pressure on Properties of Resin Transfer Molded Disks , 2002 .

[20]  Y. Xia,et al.  The Effect of Low Profile Additives on Unsaturated Polyester Resins During Curing at Low/Medium Temperature: Shrinkage Behavior Study , 2003 .

[21]  Michael Chun-Yung Niu,et al.  Composite airframe structures : practical design information and data , 1993 .

[22]  Kevin D Potter,et al.  The early history of the resin transfer moulding process for aerospace applications , 1999 .

[23]  L. J. Lee,et al.  Effect of nanoclay on shrinkage control of low profile unsaturated polyester (UP) resin cured at room temperature , 2004 .

[24]  M. Altan,et al.  Effect of Preform Thickness and Volume Fraction on Injection Pressure and Mechanical Properties of Resin Transfer Molded Composites , 2004 .

[25]  M. Vayer,et al.  Modeling PVTX diagrams: Application to various blends based on unsaturated polyester-influence of thermoplastic additive, fillers, and reinforcements , 2004 .

[26]  L. J. Lee,et al.  Control of shrinkage and residual styrene of unsaturated polyester resins cured at low temperatures: I. Effect of curing agents , 2003 .

[27]  Simulations and Applications of Injection-Compression Molding , 1999 .

[28]  Kevin D Potter Resin Transfer Moulding , 1997 .

[29]  R. R. Hill,et al.  Analysis of volumetric changes of unsaturated polyester resins during curing , 1995 .

[30]  Suresh G. Advani,et al.  Flow and rheology in polymer composites manufacturing , 1994 .