Exploration of waveguide fabrication from thermally evaporated Ge–Sb–S glass films

Abstract Waveguides from thermally evaporated Ge 23 Sb 7 S 70 films have been fabricated using both plasma etching and lift-off techniques. The two methods have been compared in their ability to provide high quality, low-loss waveguides for microphotonics applications. We have demonstrated in this paper that low-loss 3 μm and 4 μm wide channel waveguides can be fabricated using CHF 3 and SF 6 plasma etching, and lift-off, respectively. Additionally, lift-off does not change the structure of the waveguide during the fabrication whereas the structure of the plasma etched waveguide differs slightly from that of the films. Finally, channel waveguides fabricated using lift-off leads to a low RMS roughness of 10 ± 2 nm, compared to those fabricated by a plasma etching process which lead to a higher RMS roughness of 17–20 nm. As-fabricated waveguides have been found to exhibit optical propagation losses of 3–5 dB/cm at 1550 nm. These high losses are attributed to scattering by sidewall roughness and defects arising from the fabrication process.

[1]  John B. Shoven,et al.  I , Edinburgh Medical and Surgical Journal.

[2]  Christos Riziotis,et al.  Development of channel waveguide lasers in Nd3+-doped chalcogenide (Ga:La:S) glass through photoinduced material modification , 2002 .

[3]  Andrew G. Glen,et al.  APPL , 2001 .

[4]  Barry Luther-Davies,et al.  Dry-etch of As2S3 thin films for optical waveguide fabrication , 2005 .

[5]  Oleg M. Efimov,et al.  Waveguide writing in chalcogenide glasses by train of femtosecond laser pulses , 2001 .

[6]  J. McMullin,et al.  Small core rib waveguides with embedded gratings in As2Se3 glass. , 2004, Optics express.

[7]  Boolchand,et al.  Structure of GeSsub2 glass: Spectroscopic evidence for broken chemical order. , 1986, Physical review. B, Condensed matter.

[8]  Tigran Galstian,et al.  Fabrication and characterization of integrated optical waveguides in sulfide chalcogenide glasses , 1999 .

[9]  S. Campbell The Science and Engineering of Microelectronic Fabrication , 2001 .

[10]  Kathleen Richardson,et al.  Fabrication and testing of planar chalcogenide waveguide integrated microfluidic sensor. , 2007, Optics express.

[11]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[12]  Kathleen Richardson,et al.  Si-CMOS-compatible lift-off fabrication of low-loss planar chalcogenide waveguides. , 2007, Optics express.

[13]  J. Sanghera,et al.  Waveguide amplifiers in sputtered films of Er3+-doped gallium lanthanum sulfide glass. , 2006, Optics express.

[14]  K. Matsuishi,et al.  Low frequency Raman scattering spectra of (GeS2)1−χ(Sb2S3)χ amorphous semiconductors , 1997 .

[15]  P. Paniez,et al.  Polymer behavior under plasma etching: Influence of physical properties on kinetics and durability , 1991 .

[16]  Leslie Brandon Shaw,et al.  Development and Infrared Applications of Chalcogenide Glass Optical Fibers , 2000 .

[17]  C. Julien,et al.  Raman and infrared spectroscopic studies of GeGaAg sulphide glasses , 1994 .

[18]  Steve W. Martin,et al.  Preparation and characterization of glasses in the Ag2S + B2S3 + GeS2 system , 2003 .

[19]  Michel Couzi,et al.  Correlation between physical, optical and structural properties of sulfide glasses in the system Ge–Sb–S , 2006 .

[20]  H. Ticha,et al.  Far Infrared Spectra and Bonding Arrangement in Some Ge–Sb–S Glasses , 2000 .

[21]  J. Oswald,et al.  Synthesis and optical properties of the Ge–Sb–S:PrCl3 glass system , 1999 .

[22]  Barry Luther-Davies,et al.  Fabrication and characterization of low loss rib chalcogenide waveguides made by dry etching. , 2004, Optics express.

[23]  Renbo Song,et al.  Fabrication of chalcogenide glass waveguide for IR evanescent wave sensors , 2004, SPIE Optics East.

[24]  M. Iso,et al.  Fabrication of an As2S8 stripe waveguide with an optical stopping effect by exposure to ultraviolet irradiation , 2006 .

[25]  Ishwar D. Aggarwal,et al.  Chalcogenide fibers deliver high IR power , 1996 .

[26]  S. K. Chaudhuri,et al.  Full-vectorial mode calculations by finite difference method , 1994 .