Recycling of ethylene propylene diene monomer (EPDM) waste. III. Processability of EPDM rubber compound containing ground EPDM vulcanizates

The rheological behavior of ethylene propylene diene monomer (EPDM) compounds containing ground EPDM waste (W-EPDM) of known composition was studied by using a Monsanto processability tester in a temperature range of 90–110°C and a shear rate range of 306.7–1533.24 s−1. It is found that the shear viscosity decreases slightly with increasing W-EPDM loading because of wall slip that results from the migration of lubricants from the W-EPDM. The addition of W-EPDM to raw EPDM results in a decreased die swell at all temperatures and shear rates. SEM photomicrographs of the EPDM extrudate surface show improved surface smoothness and reduced extrudate distortion when EPDM is blended with W-EPDM. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 87: 2204–2215, 2003

[1]  A. Bhowmick,et al.  Recycling of EPDM waste. I. Effect of ground EPDM vulcanizate on properties of EPDM rubber , 2001 .

[2]  A. Bhowmick,et al.  Recycling of EPDM waste. II. Replacement of Virgin rubber by ground EPDM vulcanizate in EPDM/PP thermoplastic elastomeric composition , 2001 .

[3]  S. De Re-use of Ground Rubber Waste - A Review , 2001 .

[4]  J. Matisons,et al.  Rheological behavior of highly filled ethylene propylene diene rubber compounds , 2000 .

[5]  J. Padovan,et al.  Topology of Wear Particles , 1999 .

[6]  Jin Kuk Kim,et al.  Study on Powder Utilization of Waste Tires as a Filler in Rubber Compounding , 1998 .

[7]  M. Wan,et al.  Injection Molding of Rubber Compound with Rheology Affected by Vulcanization: Part I. Material Characterization , 1996 .

[8]  G. Hamed,et al.  Cure and Mechanical Behavior of Rubber Compounds Containing Ground Vulcanizates. Part II—Mooney Viscosity , 1996 .

[9]  H. Eggers,et al.  Steady-State Shear Flow Properties of Carbon-Black Filled Rubber Compounds , 1994 .

[10]  B. R. Gupta,et al.  Rheological Behaviour of Short Carbon Fiber Filled Thermoplastic Elastomeric Blends of Natural Rubber and High Density Polyethylene , 1993 .

[11]  A. Bhowmick,et al.  EFFECT OF CRYOGROUND RUBBER ON PROPERTIES OF NR , 1986 .

[12]  S. De,et al.  Cryoground Rubber-Natural Rubber Blends , 1984 .

[13]  J. Leblanc Factors Affecting the Extrudate Swell and Melt Fracture Phenomena of Rubber Compounds , 1981 .

[14]  J. Hopper Effect of Oil and Black on SBR Rheological Properties , 1967 .

[15]  F. Rodriguez,et al.  Flow properties of a linear–gel polymer system , 1965 .

[16]  F. Rodriguez,et al.  Elastic effects in a linear–gel polymer system , 1965 .

[17]  D. K. Tripathy,et al.  Rheological properties of ethylene propylene diene rubber (EPDM) compound — effect of blowing agent, curing agent and carbon black filler , 1998 .