Energy efficiency, solar energy conversion and storage in photogalvanic cell

Abstract Solar generating photogalvanic cell collect the energy from the sun for conversion to electricity. In the present work photogalvanic effect was studied in photogalvanic cell consisting Tween 60 – Biebrich scarlet – Ascorbic acid system. The photopotential, photocurrent and power generated in cell were 919.0 mV, 210.0 μA and 93.15 μW respectively. The conversion efficiency and storage capacity reported in this article as 0.8967% and 75.0 min. respectively. The effects of other parameters on the cell electrical output were investigated and a cell photoreaction mechanism for the generation of the photocurrent has also been proposed. The results also shown the efficiency along with storage performance of a photogalvanic cell based on Tween 60 – Bibrich scarlet – Ascorbic acid system.

[1]  R. Meena Study in Glycerol-Azure A-NaLS System: Solar energy conversion and storage by the use of photogalvanic cell , 2012 .

[2]  K. R. Genwa,et al.  The Role of Ascorbic Acid in a Photogalvanic Solar Cell Containing a Crystal Violet-diocyle Sulphosuccinate System and to Study the Energy Efficiency of the Cell , 2012 .

[3]  M. S. Akhtar,et al.  Water splitting on Rhodamine-B dye sensitized Co-doped TiO2 catalyst under visible light , 2012 .

[4]  K. R. Genwa,et al.  Role of acridine orange – sodium lauryl sulphate system in photogalvanic cell for solar energy conversion , 2012 .

[5]  Photogalvanic behaviour of [Cr2O2S2(1-Pipdtc)2(H2O)2] in aqueous DMF , 2009 .

[6]  A. Usami Analysis of energy conversion efficiency with an empirical model in dye-sensitized nanocrystalline solar cells , 2003 .

[7]  Ying-xu Chen,et al.  Photodegradation of dye pollutants on silica gel supported TiO2 particles under visible light irradiation , 2004 .

[8]  M. Grätzel Photovoltaic and photoelectrochemical conversion of solar energy , 2007, Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences.

[9]  K. R. Genwa,et al.  Study of Electrical Parameters and Energy Efficiency in Photogalvanic Cell Containing Erythrosine as a Photosensitizer in Benzethonium Chloride – EDTA System , 2011 .

[10]  S. Yadav,et al.  Efficient Solar Energy Conversion and Storage Through Photogalvanic Cell Based on EDTA: Brilliant Green and Fast Green System , 2011 .

[11]  M. S. Akhtar,et al.  Synthesis and Characterization of ZnO Nanorods and Balls Nanomaterials for Dye Sensitized Solar Cells , 2011 .

[12]  H. Gerischer Heterogeneous electrochemical systems for solar energy conversion , 1980 .

[13]  S. Ameta,et al.  Photogalvanic effect in azur B-NTA system , 1997 .

[14]  D. Ginley,et al.  Principles of photoelectrochemical, solar energy conversion , 1980 .

[15]  Vincenzo Balzani,et al.  The future of energy supply: Challenges and opportunities. , 2007, Angewandte Chemie.

[16]  K. R. Genwa,et al.  Comparative Study of Photosensitizing Dyes in Photogalvanic Cells for Solar Energy Conversion and Storage: Brij-35−Diethylenetriamine Pentaacetic Acid (DTPA) System , 2009 .

[17]  Crpp Papers presented at the18th IAEA Fusion Energy Conference, Sorrento, Italy, October 4 - 10, 2000 , 2000 .

[18]  K. M. Gangotri,et al.  Studies of the Anionic Micelles Effect on Photogalvanic Cells for Solar Energy Conversion and Storage in Sodium Lauryl Sulphate-Safranine-D-Xylose System , 2011 .

[19]  M. S. Akhtar,et al.  Nanocomposites of poly(1-naphthylamine)/SiO2 and poly(1-naphthylamine)/TiO2: Comparative photocatalytic activity evaluation towards methylene blue dye , 2011 .

[20]  N. R. Nenival STUDY ON EFFECT OF SURFACTANT IN PHOTOSENSITIZER FOR SOLAR ENERGY CONVERSION AND STORAGE: BISMARK BROWN - MANNITOL - NALS SYSTEM , 2012 .

[21]  W. J. Albery,et al.  Optimum efficiency of photogalvanic cells for solar energy conversion , 1977, Nature.

[22]  K. M. Gangotri,et al.  Study the performance of photogalvanic cells for solar energy conversion and storage: Toluidine blue–D‐Xylose–NaLS system , 2011 .

[23]  N. Lewis,et al.  Powering the planet: Chemical challenges in solar energy utilization , 2006, Proceedings of the National Academy of Sciences.

[24]  Krishna Kanwar Bhati,et al.  Photogalvanic conversion of solar energy into electrical energy by using NaLS–xylose–methylene blue system , 2011 .

[25]  K. M. Gangotri,et al.  Solar energy conversion and storage: Rhodamine B - Fructose photogalvanic cell , 2012 .

[26]  Kangjin Kim,et al.  Beneficial role of surfactants in electrochemistry and in the modification of electrodes. , 2006, Advances in colloid and interface science.

[27]  Shweta Sharma,et al.  Studies in photochemical conversion of solar energy: Simultaneous use of two dyes with mannitol in photogalvanic cell , 1994 .