PBM-CFD Investigation of the Gas Holdup and Mass Transfer in a Lab-Scale Internal Loop Airlift Reactor

This paper investigated the problem of overall gas holdup and the oxygen mass transfer in the internal loop airlift reactor by numerical modeling and experimental validation. The population balance model (PBM) was introduced as the general model to characterize the bubble behaviors, i.e., bubble breakage and coalescence. Bubble coalescence, as a result of fluid turbulent eddy, bubble rise difference, and bubble wake entrainment, was considered in the PBM kernels. Meanwhile, bubble breakage, owing to eddy collision and large bubble instability, was included in the PBM kernels. A class method was applied to numerically solve the population balance equations. Based on the lab-scale internal loop airlift reactor, experiments and CFD simulations have been carried on simultaneously. The comparison between them demonstrated that CFD simulation results had good agreement between the experimental data and validated the effectiveness of the PBM model indirectly. Therefore, the PBM-CFD modeling provides an effective method for the problem of scale up. Finally, the flow regime transition of gas holdup difference and small bubble volume fraction are investigated in an internal loop airlift reactor.

[1]  E. S. Gaddis Mass transfer in gas–liquid contactors , 1999 .

[2]  J. Zahradnı́k,et al.  The effect of bubbling regime on gas and liquid phase mixing in bubble column reactors , 1996 .

[3]  Tiefeng Wang,et al.  Numerical simulations of gas–liquid mass transfer in bubble columns with a CFD–PBM coupled model , 2007 .

[4]  Mamoru Ishii,et al.  Two-group interfacial area transport equations at bubbly-to-slug flow transition , 2000 .

[5]  Hamid Reza Karimi,et al.  New results on H∞ dynamic output feedback control for Markovian jump systems with time‐varying delay and defective mode information , 2014 .

[6]  Donald S. Scott,et al.  An eddy cell model of mass transfer into the surface of a turbulent liquid , 1970 .

[7]  Jose C. Merchuk,et al.  Air-lift reactors in chemical and biological technology , 2007 .

[8]  Ville Alopaeus,et al.  Validation of bubble breakage, coalescence and mass transfer models for gas–liquid dispersion in agitated vessel , 2006 .

[9]  Junwei Sun,et al.  Hydrodynamics and mass transfer characteristics in an internal loop airlift reactor with sieve plates , 2013 .

[10]  Geoffrey Brooks,et al.  Numerical simulation of two-phase flow with bubble break-up and coalescence coupled with population balance modeling , 2013 .

[11]  Alain Liné,et al.  Modeling hydrodynamics of gas–liquid airlift reactor , 2007 .

[12]  R. Higbie,et al.  The Rate of Absorption of a Pure Gas into a Still Liquid during Short Periods of Exposure , 1935 .

[13]  Wen-Jang Lu,et al.  Gas-liquid mass transfer in an internal loop airlift reactor with low density particles , 1997 .

[14]  Amol A. Kulkarni,et al.  Mass Transfer in Bubble Column Reactors: Effect of Bubble Size Distribution , 2007 .

[15]  Liang-Shih Fan,et al.  Bubble wake dynamics in liquids and liquid-solid suspensions , 1990 .

[16]  Yong Jin,et al.  Theoretical prediction of flow regime transition in bubble columns by the population balance model , 2005 .

[17]  Spiros V. Paras,et al.  Experimental study of bubble formation at metal porous spargers: Effect of liquid properties and sparger characteristics on the initial bubble size distribution , 2008 .

[18]  Rajamani Krishna,et al.  Hydrodynamics of internal air-lift reactors: experiments versus CFD simulations , 2003 .

[19]  Sabine Le Borne,et al.  Algorithms for the Haar wavelet based fast evaluation of aggregation integrals in population balance equations , 2016 .

[20]  M. Sommerfeld,et al.  Multiphase Flows with Droplets and Particles , 2011 .

[21]  J. Markoš,et al.  Comparison of gassing-out and pressure-step dynamic methods for kLa measurement in an airlift reactor with internal loop , 2004 .

[22]  R. F. Mudde,et al.  2D and 3D simulations of an internal airlift loop reactor on the basis of a two-fluid model , 2001 .

[23]  Lijia Luo,et al.  Hydrodynamics and mass transfer characteristics in an internal loop airlift reactor with different spargers , 2011 .

[24]  Hamid Reza Karimi,et al.  Model approximation for two-dimensional Markovian jump systems with state-delays and imperfect mode information , 2015, Multidimens. Syst. Signal Process..

[25]  Rajamani Krishna,et al.  Volumetric mass transfer coefficients in slurry bubble columns operating in the heterogeneous flow regime , 2004 .

[26]  Hamid Reza Karimi,et al.  Filtering design for two-dimensional Markovian jump systems with state-delays and deficient mode information , 2014, Inf. Sci..

[27]  M.E.E. Abashar,et al.  Hydrodynamic Flow Regimes, Gas Holdup, and Liquid Circulation in Airlift Reactors , 1998 .

[28]  Daniele Marchisio,et al.  Simulation of coalescence, break-up and mass transfer in a gas-liquid stirred tank with CQMOM , 2013 .

[29]  B. C. Khoo,et al.  Mass transfer across the turbulent gas–water interface , 2006 .

[30]  Jianbin Qiu,et al.  New approach to delay-dependent H ∞ filtering for discrete-time Markovian jump systems with time-varying delay and incomplete transition descriptions , 2013 .

[31]  Lijia Luo,et al.  CFD simulations to portray the bubble distribution and the hydrodynamics in an annulus sparged air‐lift bioreactor , 2011 .

[32]  Hanns Hofmann,et al.  Bubble behaviour and flow structure of bubble columns , 1991 .

[33]  Jos Derksen,et al.  Population Balance Modeling of Aerated Stirred Vessels Based on CFD , 2002 .

[34]  Donald A. Drew,et al.  The virtual mass and lift force on a sphere in rotating and straining inviscid flow , 1987 .

[35]  A. Lübbert,et al.  Detailed investigations of the multiphase flow in airlift tower loop reactors , 1990 .

[36]  Jay Sanyal,et al.  A generalized approach to model oxygen transfer in bioreactors using population balances and computational fluid dynamics , 2005 .

[37]  Paulo L.C. Lage,et al.  EXPERIMENTAL STUDY ON BUBBLE SIZE DISTRIBUTIONS IN A DIRECT-CONTACT EVAPORATOR , 2004 .

[38]  Alejandro Clausse,et al.  A Mathematical Description of the Critical Heat Flux as a Non-Linear Dynamic Instability , 1993 .

[39]  M.C.M. van Loosdrecht,et al.  Bubble recirculation regimes in an internal-loop airlift reactor , 1999 .

[40]  Rajamani Krishna,et al.  Gas holdup and mass transfer in bubble column reactors operated at elevated pressure. , 1999 .

[41]  Maurice A. Bergougnou,et al.  Application of surface-renewal-stretch model for interface mass transfer , 2006 .