A review on the recent advances in mixed matrix membranes for gas separation processes

Abstract Gas separation processes are amongst the most important operations in the refineries and gas-related industries. Recently, many efforts are being dedicated towards modifying the gas separation properties of existing polymers to further expand their use for extensive industrial gas separation applications. Mixed matrix membranes (MMMs), which are organic–inorganic hybrid membranes, have been proposed as the alternative approach to intensify the comprehensive gas separation performance of the polymeric membranes. In this regard, we analyze and review the recent scientific and technological advances in the development of MMM's, including the emerging class of inorganic fillers like two-dimensional (2D)materials, that have been the focus of much recent work for gas separation. The review also discusses the current issues associated with the filler materials and further provides an outline to overcome the emerging challenges for the future development of high performance MMMs.

[1]  R. Bagheri,et al.  Mixed matrix membranes of polyurethane with nickel oxide nanoparticles for CO2 gas separation , 2018 .

[2]  B. Bruggen The Separation Power of Nanotubes in Membranes: A Review , 2012 .

[3]  T. Mohammadi,et al.  Preparation and characterization of SAPO-34 – Matrimid® 5218 mixed matrix membranes for CO2/CH4 separation , 2013 .

[4]  C. P. Ribeiro,et al.  Gas permeability, diffusivity, and free volume of thermally rearranged polymers based on 3,3′-dihydroxy-4,4′-diamino-biphenyl (HAB) and 2,2′-bis-(3,4-dicarboxyphenyl) hexafluoropropane dianhydride (6FDA) , 2012 .

[5]  M. Asghari,et al.  Effect of nano Zinc Oxide on gas permeation through mixed matrix poly (Amide-6-b-Ethylene Oxide)-based membranes , 2017 .

[6]  V. Pirouzfar,et al.  Mixed matrix membranes comprising PMP polymer with dispersed alumina nanoparticle fillers to separate CO2/N2 , 2016, Macromolecular Research.

[7]  William J. Koros,et al.  Mixed matrix membranes using carbon molecular sieves: I. Preparation and experimental results , 2003 .

[8]  X. Zhang,et al.  MoS2 Nanosheets Functionalized Composite Mixed Matrix Membrane for Enhanced CO2 Capture via Surface Drop-Coating Method. , 2016, ACS applied materials & interfaces.

[9]  S. Dai,et al.  Porous graphene as the ultimate membrane for gas separation. , 2009, Nano letters.

[10]  J. Ferraris,et al.  MIL-53 frameworks in mixed-matrix membranes , 2014 .

[11]  Ashwin R. Kamble,et al.  Modification of PVDF membrane by two-dimensional inorganic additive for improving gas permeation , 2018, Separation Science and Technology.

[12]  D. Sholl,et al.  Rapid transport of gases in carbon nanotubes. , 2002, Physical review letters.

[13]  M. Haranczyk,et al.  Comparing gas separation performance between all known zeolites and their zeolitic imidazolate framework counterparts. , 2016, Dalton transactions.

[14]  May‐Britt Hägg,et al.  Gas separation properties of ZIF-8/6FDA-durene diamine mixed matrix membrane , 2014 .

[15]  P. Webley,et al.  Two-dimensional nanosheet-based gas separation membranes , 2018 .

[16]  K. Shahidi,et al.  Hydrogen separation and purification using crosslinkable PDMS/zeolite A nanoparticles mixed matrix membranes , 2012 .

[17]  H. Hasbullah,et al.  Preliminary study on gas separation performance of flat sheet mixed matrix (PVDF/Zeolite) , 2018 .

[18]  Peng Li,et al.  Fabrication of polyimide and functionalized multi-walled carbon nanotubes mixed matrix membranes by in-situ polymerization for CO2 separation , 2017 .

[19]  Naiying Du,et al.  Gas transport behavior of mixed-matrix membranes composed of silica nanoparticles in a polymer of intrinsic microporosity ( PIM-1 ) , 2012 .

[20]  Z. Smith,et al.  Mixed-Matrix Membranes Formed from Multi-Dimensional Metal-Organic Frameworks for Enhanced Gas Transport and Plasticization Resistance. , 2019, ChemSusChem.

[21]  Overview on porous inorganic membranes for gas separation , 2017 .

[22]  R. Castro‐Muñoz,et al.  Enhanced CO2 permeability in Matrimid® 5218 mixed matrix membranes for separating binary CO2/CH4 mixtures , 2019, Separation and Purification Technology.

[23]  J. Pang,et al.  Functionalised Multi-walled Carbon Nanotubes/Cellulose Acetate Butyrate Mixed Matrix Membrane for CO2/N2 Separation , 2019, Journal of Physical Science.

[24]  M. Radosz,et al.  Carbon nanotube composite membranes of brominated poly(2,6-diphenyl-1,4-phenylene oxide) for gas separation , 2007 .

[25]  Yuguang Ma,et al.  CO2 Capture and Separations Using MOFs: Computational and Experimental Studies. , 2017, Chemical reviews.

[26]  Katrin Schmitt,et al.  Towards Enhanced Gas Sensor Performance with Fluoropolymer Membranes , 2016, Sensors.

[27]  Lujie Cao,et al.  A highly permeable mixed matrix membrane containing CAU-1-NH2 for H2 and CO2 separation. , 2013, Chemical communications.

[28]  J. Bellare,et al.  Carboxylated Carbon Nanotubes/Polyethersulfone Hollow Fiber Mixed Matrix Membranes: Development and Characterization for Enhanced Gas Separation Performance , 2018 .

[29]  F. Daeyaert,et al.  Machine-learning approach to the design of OSDAs for zeolite beta , 2019, Proceedings of the National Academy of Sciences.

[30]  Peter Schwerdtfeger,et al.  Nanoporous Graphene Membranes for Efficient 3He/4He Separation , 2012 .

[31]  V. Pirouzfar,et al.  The influence of nanoparticles on gas transport properties of mixed matrix membranes: An experimental investigation and modeling , 2017, Korean Journal of Chemical Engineering.

[32]  Tianyu Liu,et al.  Enhanced interfacial interaction and CO2 separation performance of mixed matrix membrane by incorporating polyethylenimine-decorated metal-organic frameworks. , 2015, ACS applied materials & interfaces.

[33]  F. Zhang,et al.  MOF Nanosheet-Based Mixed Matrix Membranes with Metal-Organic Coordination Interfacial Interaction for Gas Separation. , 2020, ACS applied materials & interfaces.

[34]  J. Ferraris,et al.  Origins and Evolution of Inorganic-Based and MOF-Based Mixed-Matrix Membranes for Gas Separations , 2016 .

[35]  M. Shariaty-Niassar,et al.  Purified and Functionalized MWCNTs: Application In CO2/CH4 Separation Using Mixed Matrix Membranes , 2018 .

[36]  P. Budd,et al.  Boosting gas separation performance and suppressing the physical aging of polymers of intrinsic microporosity (PIM-1) by nanomaterial blending. , 2020, Nanoscale.

[37]  S. Shahid Polymer-Metal Organic Frameworks (MOFs) Mixed Matrix Membranes For Gas Separation Applications , 2015 .

[38]  Freek Kapteijn,et al.  Metal-organic framework nanosheets in polymer composite materials for gas separation , 2014, Nature materials.

[39]  N. K. Acharya Temperature-dependent gas transport and its correlation with kinetic diameter in polymer nanocomposite membrane , 2017, Bulletin of Materials Science.

[40]  Denis Rodrigue,et al.  Amine-Functionalized MIL-53 Metal–Organic Framework in Polyimide Mixed Matrix Membranes for CO2/CH4 Separation , 2012 .

[41]  J. Campbell,et al.  Mg-MOF-74/Polyvinyl acetate (PVAc) mixed matrix membranes for CO2 separation , 2020, Separation and Purification Technology.

[42]  K. K. Lau,et al.  Fabrication of 6FDA-durene membrane incorporated with zeolite T and aminosilane grafted zeolite T for CO2/CH4 separation , 2017 .

[43]  Ting Yang,et al.  Poly-/metal-benzimidazole nano-composite membranes for hydrogen purification , 2011 .

[44]  S. A. Hamid Membrane-based Gas Separation: Principle, Applications and Future Potential , 2014 .

[45]  M. Jazebizadeh,et al.  Investigation of Methane and Carbon Dioxide Gases Permeability Through PEBAX/PEG/ZnO Nanoparticle Mixed Matrix Membrane , 2017, Silicon.

[46]  Dan Zhao,et al.  Mixed matrix membranes composed of two-dimensional metal–organic framework nanosheets for pre-combustion CO2 capture: a relationship study of filler morphology versus membrane performance , 2015 .

[47]  M. Sahimi,et al.  Structural characterization of polyetherimide-based carbon molecular sieve membranes , 2000 .

[48]  Sebastien Balme,et al.  Boron Nitride Nanoporous Membranes with High Surface Charge by Atomic Layer Deposition. , 2017, ACS applied materials & interfaces.

[49]  P. Goh,et al.  Gas separation properties of functionalized carbon nanotubes mixed matrix membranes , 2011 .

[50]  C. Téllez,et al.  Pervaporation-Assisted Esterification Reactions by Means of Mixed Matrix Membranes , 2018, Industrial & Engineering Chemistry Research.

[51]  Tomoyuki Suzuki,et al.  Gas transport properties of polybenzoxazole–silica hybrid membranes prepared with different alkoxysilanes , 2018, Polymer Journal.

[52]  Rong Wang,et al.  High-performance nanocomposite membranes realized by efficient molecular sieving with CuBDC nanosheets. , 2017, Chemical communications.

[53]  Sangil Kim,et al.  Fabrication and characterization of polyimide–zeolite L mixed matrix membranes for gas separations , 2006 .

[54]  Sangil Kim,et al.  Poly(imide siloxane) and carbon nanotube mixed matrix membranes for gas separation , 2006 .

[55]  T. Mohammadi,et al.  Synthesis of a PEBAX-1074/ZnO nanocomposite membrane with improved CO 2 separation performance , 2017 .

[56]  D. Sholl,et al.  Ultem®/ZIF-8 mixed matrix hollow fiber membranes for CO2/N2 separations , 2012 .

[57]  Ashwin R. Kamble,et al.  Polyethersulfone based MMMs with 2D materials and ionic liquid for CO2, N2 and CH4 separation. , 2020, Journal of environmental management.

[58]  T. Merkel,et al.  50th Anniversary Perspective: Polymers and Mixed Matrix Membranes for Gas and Vapor Separation: A Review and Prospective Opportunities , 2017 .

[59]  R. Castro‐Muñoz,et al.  Effect of the ZIF‐8 Distribution in Mixed‐Matrix Membranes Based on Matrimid® 5218‐PEG on CO 2 Separation , 2019, Chemical Engineering & Technology.

[60]  G. Bengtson,et al.  Functionalized carbon nanotubes mixed matrix membranes of polymers of intrinsic microporosity for gas separation , 2012, Nanoscale Research Letters.

[61]  Tai‐Shung Chung,et al.  Effects of novel silane modification of zeolite surface on polymer chain rigidification and partial pore blockage in polyethersulfone (PES)-zeolite A mixed matrix membranes , 2006 .

[62]  C. Lamberti,et al.  frameworks: structure, properties, methods of synthesis and characterization , 2022 .

[63]  Liangjun Hu,et al.  Ultrathin membranes of single-layered MoS₂ nanosheets for high-permeance hydrogen separation. , 2015, Nanoscale.

[64]  M. Tsapatsis,et al.  Preparation and characterization of a glassy fluorinated polyimide zeolite-mixed matrix membrane , 2002 .

[65]  Ashwin R. Kamble,et al.  Effects of inorganic additive of two-dimensional hexagonal boron nitride on the gas separation/permeation for PVDF-derived membranes , 2019, Separation Science and Technology.

[66]  Joshua Schrier,et al.  Helium Separation Using Porous Graphene Membranes , 2010 .

[67]  Hsueh-Chia Chang,et al.  Carbon nanotube-based mixed-matrix membranes with supramolecularly engineered interface for enhanced gas separation performance , 2020 .

[68]  C. Téllez,et al.  NH2-MIL-53(Al) and NH2-MIL-101(Al) in sulfur-containing copolyimide mixed matrix membranes for gas separation , 2013 .

[69]  Yujie Ban,et al.  Metal-organic framework-based mixed matrix membranes: Synergetic effect of adsorption and diffusion for CO2/CH4 separation , 2018, Journal of Membrane Science.

[70]  Huanting Wang,et al.  2D Nanosheets and Their Composite Membranes for Water, Gas, and Ion Separation , 2019, Angewandte Chemie.

[71]  M. Pakizeh,et al.  Preparation, characterization and gas permeation study of PSf/MgO nanocomposite membrane , 2013 .

[72]  J. Ferraris,et al.  Mixed-matrix membranes containing MOF-5 for gas separations , 2009 .

[73]  Y. S. Lin,et al.  Gas Separation Properties of Metal Organic Framework (MOF-5) Membranes , 2013 .

[74]  P. Prádanos,et al.  Gas separation of 6FDA–6FpDA membranes: Effect of the solvent on polymer surfaces and permselectivity , 2007 .

[75]  Seyed Foad Mousavi,et al.  Synthesis and gas transport performance of MIL-101/Matrimid mixed matrix membranes , 2015 .

[76]  P. Webley,et al.  Enhancing plasticization-resistance of mixed-matrix membranes with exceptionally high CO2/CH4 selectivity through incorporating ZSM-25 zeolite , 2019, Journal of Membrane Science.

[77]  Kenji Sumida,et al.  Carbon dioxide capture in metal-organic frameworks. , 2012, Chemical reviews.

[78]  R. Castro‐Muñoz,et al.  Economic Framework of Membrane Technologies for Natural Gas Applications , 2018, Separation & Purification Reviews.

[79]  R. Castro‐Muñoz,et al.  New insights of nanomaterials usage toward superhydrophobic membranes for water desalination via membrane distillation: A review , 2021, Critical Reviews in Environmental Science and Technology.

[80]  B. C. Ng,et al.  Effect of Dispersed Multi-Walled Carbon Nanotubes on Mixed Matrix Membrane for O2/N2 Separation , 2011 .

[81]  M. Omidkhah,et al.  Enhanced CO2 transport properties of membranes by embedding nano-porous zeolite particles into Matrimid®5218 matrix , 2015 .

[82]  R. Castro‐Muñoz,et al.  Chemical Crosslinking of 6FDA-ODA and 6FDA-ODA:DABA for Improved CO2/CH4 Separation , 2018, Membranes.

[83]  D. Bastani,et al.  Polymeric mixed matrix membranes containing zeolites as a filler for gas separation applications: A review , 2013 .

[84]  Rong Wang,et al.  Nanosizing zeolite 5A fillers in mixed-matrix carbon molecular sieve membranes to improve gas separation performance , 2020 .

[85]  Yatao Zhang,et al.  Covalent organic frameworks (COFs) functionalized mixed matrix membrane for effective CO2/N2 separation , 2019, Journal of Membrane Science.

[86]  Chongli Zhong,et al.  Development of computational methodologies for metal-organic frameworks and their application in gas separations. , 2013, Chemical reviews.

[87]  J. Tascón,et al.  Production of aqueous dispersions of inorganic graphene analogues by exfoliation and stabilization with non-ionic surfactants , 2014 .

[88]  J. Coronas,et al.  Ultrathin permselective membranes: the latent way for efficient gas separation , 2020, RSC advances.

[89]  Easir A Khan,et al.  Synthesis of continuous MOF-5 membranes on porous α-alumina substrates , 2009 .

[90]  A. Javaid Membranes for solubility-based gas separation applications , 2005 .

[91]  A. Ismail,et al.  Fabrication of Mixed Matrix Membrane Polysulfone - Zeolite Carbon Composites (ZCC) For Gas Separation , 2019, IOP Conference Series: Materials Science and Engineering.

[92]  B. Freeman,et al.  Energy-efficient polymeric gas separation membranes for a sustainable future: A review , 2013 .

[93]  S. M. Ghoreishi,et al.  Polyimide based mixed matrix membranes incorporating Cu-BDC nanosheets for impressive helium separation , 2020, Separation and Purification Technology.

[94]  Wha-Seung Ahn,et al.  Synthesis of metal-organic frameworks: A mini review , 2013, Korean Journal of Chemical Engineering.

[95]  H. Kalipcilar,et al.  Preparation and performance assessment of binary and ternary PES-SAPO 34-HMA based gas separation membranes , 2010 .

[96]  I. Vankelecom,et al.  SPEEK and functionalized mesoporous MCM-41 mixed matrix membranes for CO2 separations , 2012 .

[97]  M. P. Chenar,et al.  Aminosilane grafted Matrimid 5218/nano-silica mixed matrix membrane for CO2/light gases separation , 2018, Korean Journal of Chemical Engineering.

[98]  Qinzhuo Wang,et al.  Chitosan/graphene oxide mixed matrix membrane with enhanced water permeability for high-salinity water desalination by pervaporation , 2018, Desalination.

[99]  S. Basu,et al.  MOF-containing mixed-matrix membranes for CO2/CH4 and CO2/N2 binary gas mixture separations , 2011 .

[100]  Xingzhong Cao,et al.  MXene versus graphene oxide: Investigation on the effects of 2D nanosheets in mixed matrix membranes for CO2 separation , 2020 .

[101]  Chalida Klaysom,et al.  Zeolite-based mixed matrix membranes for hazardous gas removal , 2018, Advanced Nanomaterials for Membrane Synthesis and its Applications.

[102]  S. Basu,et al.  Asymmetric Matrimid®/[Cu3(BTC)2] mixed-matrix membranes for gas separations , 2010 .

[103]  Gongpin Liu,et al.  Pebax-based membrane filled with two-dimensional MXene nanosheets for efficient CO2 Capture. , 2019, Chemistry, an Asian journal.

[104]  Omid Ghaffari Nik,et al.  Functionalized metal organic framework-polyimide mixed matrix membranes for CO2/CH4 separation , 2012 .

[105]  Dewei Rao,et al.  Hexagonal Boron Nitride with Designed Nanopores as a High-Efficiency Membrane for Separating Gaseous Hydrogen from Methane , 2015 .

[106]  Miao Yu,et al.  Ultrathin, Molecular-Sieving Graphene Oxide Membranes for Selective Hydrogen Separation , 2013, Science.

[107]  Zhonghua Zhu,et al.  Mixed matrix membranes incorporated with size-reduced Cu-BTC for improved gas separation , 2013 .

[108]  M. Sadeghi,et al.  Polyurethane-Silica Nanocomposite Membranes for Separation of Propane/Methane and Ethane/Methane , 2014 .

[109]  Lin Hao,et al.  Photo-oxidative PIM-1 based mixed matrix membranes with superior gas separation performance , 2015 .

[110]  A. König,et al.  Mixed‐Matrix Membrane for Gas Separation: Polydimethylsiloxane Filled with Zeolite , 2012 .

[111]  I. Pinnau,et al.  Ultraselective glassy polymer membranes with unprecedented performance for energy-efficient sour gas separation , 2019, Science Advances.

[112]  R. Castro‐Muñoz,et al.  Matrimid® 5218 in preparation of membranes for gas separation: Current state-of-the-art , 2018 .

[113]  Yi-Feng Lin,et al.  Effects of structural crystallinity and defects in microporous Al-MOF filled chitosan mixed matrix membranes for pervaporation of water/ethanol mixtures , 2017 .

[114]  J. Koresh,et al.  Molecular Sieve Carbon Permselective Membrane. Part I. Presentation of a New Device for Gas Mixture Separation , 1983 .

[115]  M. Buonomenna,et al.  Some approaches for high performance polymer based membranes for gas separation: block copolymers, carbon molecular sieves and mixed matrix membranes , 2012 .

[116]  J. Long,et al.  On the direct synthesis of Cu(BDC) MOF nanosheets and their performance in mixed matrix membranes , 2018 .

[117]  R. Castro‐Muñoz,et al.  Enhancing the CO 2 Separation Performance of Matrimid 5218 Membranes for CO 2 /CH 4 Binary Mixtures , 2019, Chemical Engineering & Technology.

[118]  Yingfei Hou,et al.  Molecular simulation for separation of ethylene and ethane by functionalised graphene membrane , 2019, Molecular Simulation.

[119]  A. Rehman,et al.  Optimization analysis of polyurethane based mixed matrix gas separation membranes by incorporation of gamma-cyclodextrin metal organic frame work , 2020, Chemical Papers.

[120]  A. Nizami,et al.  Synergistic solution of CO2 capture by novel lanthanide-based MOF-76 yttrium nanocrystals in mixed-matrix membranes , 2020, Energy & Environment.

[121]  Gas transport properties of LiA type zeolite-filled poly(trimethylsilylpropyne) membranes , 2015, Petroleum Chemistry.

[122]  Hao Li,et al.  Recent advances in gas storage and separation using metal–organic frameworks , 2018 .

[123]  C. Scholes,et al.  Review of Membranes for Helium Separation and Purification , 2017, Membranes.

[124]  E. Kamio,et al.  Fundamental investigation of the gas permeation mechanism of facilitated transport membranes with Co(salen)-containing ionic liquid as O2 carriers , 2020 .

[125]  C. Téllez,et al.  Mixed matrix membranes comprising glassy polymers and dispersed mesoporous silica spheres for gas separation , 2011 .

[126]  E. Drioli,et al.  Filler-polymer combination: a route to modify gas transport properties of a polymeric membrane , 2004 .

[127]  R. Castro‐Muñoz,et al.  Mixed Matrix Membranes Based on PIMs for Gas Permeation: Principles, Synthesis, and Current Status , 2017 .

[128]  H. Kita,et al.  Nano-porous Zeolite and MOF Filled Mixed Matrix Membranes for Gas Separation , 2021, MATEC Web of Conferences.

[129]  Freek Kapteijn,et al.  Visualizing MOF Mixed Matrix Membranes at the Nanoscale: Towards Structure‐Performance Relationships in CO2/CH4 Separation Over NH2‐MIL‐53(Al)@PI , 2014 .

[130]  R. Banerjee,et al.  Chemically Stable Covalent Organic Framework (COF)-Polybenzimidazole Hybrid Membranes: Enhanced Gas Separation through Pore Modulation. , 2016, Chemistry.

[131]  Ruili Guo,et al.  Introducing two-dimensional metal-organic frameworks with axial coordination anion into Pebax for CO2/CH4 separation , 2020 .

[132]  Ineke G.M. Punt,et al.  Suppression of gas separation membrane plasticization by homogeneous polymer blending , 2001 .

[133]  V. Chen,et al.  Challenges and opportunities for mixed-matrix membranes for gas separation , 2013 .

[134]  Effect of Carbon Molecular Sieve (CMS) Concentration on Mixed Matrix Membranes (MMMs) Performance for Carbon Dioxide Removal , 2015 .

[135]  T. Jiang,et al.  Design of thin and tubular MOFs-polymer mixed matrix membranes for highly selective separation of H2 and CO2 , 2019, Separation and Purification Technology.

[136]  A. Ismail,et al.  P84/ZCC Hollow Fiber Mixed Matrix Membrane with PDMS Coating to Enhance Air Separation Performance , 2020, Membranes.

[137]  M. Bilad,et al.  Tuning the gas separation performance of fluorinated and sulfonated PEEK membranes by incorporation of zeolite 4A , 2018 .

[138]  H. Zhang,et al.  Mixed-Matrix Membranes Containing Carbon Nanotubes Composite with Hydrogel for Efficient CO2 Separation. , 2016, ACS applied materials & interfaces.

[139]  Y. Alqaheem,et al.  Recent developments in polyetherimide membrane for gas separation , 2019, Journal of the Chinese Chemical Society.

[140]  Design and Evaluation of Gas Transport through a Zeolite Membrane on an Alumina Support , 2018, Zeolites and Their Applications.

[141]  R. Castro‐Muñoz,et al.  Progress on Incorporating Zeolites in Matrimid®5218 Mixed Matrix Membranes towards Gas Separation , 2018, Membranes.

[142]  Ebelegi Newton Augustus,et al.  Metal-organic Frameworks as Novel Adsorbents: A Preview , 2017 .

[143]  M. Darvish Ganji,et al.  Hydrogen purification performance of a nanoporous hexagonal boron nitride membrane: molecular dynamics and first-principle simulations. , 2017, Physical chemistry chemical physics : PCCP.

[144]  A. Hussain,et al.  Carbon capture from natural gas using multi-walled CNTs based mixed matrix membranes , 2019, Environmental technology.

[145]  M. Fazli,et al.  Reactive molecular dynamic simulations on the gas separation performance of porous graphene membrane , 2017, Scientific Reports.

[146]  S. Dai,et al.  Permeance of H2 through porous graphene from molecular dynamics , 2013 .

[147]  M. Omidkhah,et al.  Preparation and characterization of Matrimid® 5218 based binary and ternary mixed matrix membranes for CO2 separation , 2015 .

[148]  Tao Li,et al.  Carbon dioxide selective mixed matrix composite membrane containing ZIF-7 nano-fillers , 2013 .

[149]  Christopher W. Jones,et al.  A high-performance gas-separation membrane containing submicrometer-sized metal-organic framework crystals. , 2010, Angewandte Chemie.

[150]  Stephen J. Miller,et al.  Crosslinked mixed matrix membranes for the purification of natural gas: Effects of sieve surface modification , 2008 .

[151]  R. Baker Future directions of membrane gas separation technology , 2002 .

[152]  P. Prádanos,et al.  Effect of fractional free volume and Tg on gas separation through membranes made with different glassy polymers , 2008 .

[153]  M. Sadrzadeh,et al.  Improvement in gas separation properties of a polymeric membrane through the incorporation of inorganic nano‐particles , 2012 .

[154]  M. Sadeghi,et al.  Gas separation properties of polyvinylchloride (PVC)-silica nanocomposite membrane , 2014, Korean Journal of Chemical Engineering.

[155]  Youguo Yan,et al.  Molecular Dynamics Simulations of CO2/N2 Separation through Two-Dimensional Graphene Oxide Membranes , 2016 .

[156]  D. D. De Vos,et al.  Bipyridine-based UiO-67 as novel filler in mixed-matrix membranes for CO2-selective gas separation , 2019, Journal of Membrane Science.

[157]  T. Mohammadi,et al.  Effective hydrogen purification from methane via polyimide Matrimid® 5218- Deca-dodecasil 3R type zeolite mixed matrix membrane , 2017 .

[158]  A. Dashti,et al.  Polyurethane-SAPO-34 mixed matrix membrane for CO2/CH4 and CO2/N2 separation , 2019, Chinese Journal of Chemical Engineering.

[159]  Roy D. Raharjo,et al.  Gas Permeability, Solubility, and Diffusion Coefficients in 1,2-Polybutadiene Containing Magnesium Oxide , 2008 .

[160]  R. Castro‐Muñoz,et al.  Novel MMM using CO2 selective SSZ-16 and high-performance 6FDA-polyimide for CO2/CH4 separation , 2021 .

[161]  M. Bilad,et al.  Mixed matrix membranes comprising of polysulfone and microporous Bio-MOF-1: Preparation and gas separation properties , 2019, Separation and Purification Technology.

[162]  R. Castro‐Muñoz,et al.  Tuning of Nano-Based Materials for Embedding Into Low-Permeability Polyimides for a Featured Gas Separation , 2020, Frontiers in Chemistry.

[163]  E. Ricci,et al.  Modelling Mixed-Gas Sorption in Glassy Polymers for CO2 Removal: A Sensitivity Analysis of the Dual Mode Sorption Model , 2019, Membranes.

[164]  Navid Azizi,et al.  Applying Pebax-1657/ZnO mixed matrix membranes for CO2/CH4 separation , 2019, Petroleum Science and Technology.

[165]  Yunwu Yu,et al.  A poly(arylene ether sulfone) hybrid membrane using titanium dioxide nanoparticles as the filler , 2017 .

[166]  Xiaoyan Yuan,et al.  Improvement of mechanical properties for epoxy composites with modified titanate whiskers via dopamine self-oxidation , 2021, Journal of Polymer Research.

[167]  C. Téllez,et al.  High-pressure CO2/CH4 separation of Zr-MOFs based mixed matrix membranes , 2020 .

[168]  S. Dai,et al.  Effect of pore density on gas permeation through nanoporous graphene membranes. , 2018, Nanoscale.

[169]  M. Boroglu,et al.  Gas separation performance of 6FDA-DAM-ZIF-11 mixed-matrix membranes for H2/CH4 and CO2/CH4 separation , 2017 .

[170]  H. Park,et al.  Two-dimensional materials: an emerging platform for gas separation membranes , 2018, Current Opinion in Chemical Engineering.

[171]  Jae-Young Choi,et al.  Selective Gas Transport Through Few-Layered Graphene and Graphene Oxide Membranes , 2013, Science.

[172]  Michael D. Guiver,et al.  Polysulfone/silica nanoparticle mixed-matrix membranes for gas separation , 2008 .

[173]  Ying Zhang,et al.  Hydrogen-bonded polyamide 6/Zr-MOF mixed matrix membranes for efficient natural gas dehydration , 2021 .

[174]  Jing Zhang,et al.  Separation of Hydrogen and Nitrogen Gases with Porous Graphene Membrane , 2011 .

[175]  I. Sreedhar,et al.  Process and engineering trends in membrane based carbon capture , 2017 .

[176]  A. Hill,et al.  Post-synthetic Ti Exchanged UiO-66 Metal-Organic Frameworks that Deliver Exceptional Gas Permeability in Mixed Matrix Membranes , 2015, Scientific Reports.

[177]  C. Téllez,et al.  Crystallization in THF: the possibility of one-pot synthesis of mixed matrix membranes containing MOF MIL-68(Al) , 2013 .

[178]  Enrico Drioli,et al.  Membrane Gas Separation: A Review/State of the Art , 2009 .

[179]  D. A. Tanaka,et al.  Recent Advances on Carbon Molecular Sieve Membranes (CMSMs) and Reactors , 2016 .

[180]  G. Silva,et al.  Polydimethylsiloxane Membranes Containing Multi-walled Carbon Nanotubes for Gas Separation , 2017 .

[181]  Baoquan Zhang,et al.  Enhanced CO2/CH4 Separation Performances of Mixed Matrix Membranes Incorporated with Two-Dimensional Ni-Based MOF Nanosheets , 2019, ACS Sustainable Chemistry & Engineering.

[182]  Jason K. Ward,et al.  Metal organic framework mixed matrix membranes for gas separations , 2010 .

[183]  R. Castro‐Muñoz,et al.  High-performance pervaporation chitosan-based membranes: new insights and perspectives , 2020, Reviews in Chemical Engineering.

[184]  M. Kurian,et al.  Synthesis and catalytic applications of metal–organic frameworks: a review on recent literature , 2018, International Nano Letters.

[185]  K. K. Lau,et al.  Dispersion of Titanium(IV) Oxide Nanoparticles in Mixed Matrix Membrane Using Octaisobutyl Polyhedral Oligomeric Silsesquioxane for Enhanced CO2/CH4 Separation Performance , 2019, Chinese Journal of Polymer Science.

[186]  M. Asghari,et al.  Investigation of Carbon Nanotubes in Mixed Matrix Membranes for Gas Separation: A Review , 2016 .

[187]  Gas Separation Properties of the Dense Polymer : Zeolite Powder Composite Membranes , 2016 .

[188]  Michael S Strano,et al.  Mechanisms of gas permeation through single layer graphene membranes. , 2012, Langmuir : the ACS journal of surfaces and colloids.

[189]  M. Othman,et al.  Carbon Dioxide (CO2) Separation from Natural Gas using Single-layer and Dual-layer Mixed-matrix Membranes (MMMs) , 2014 .

[190]  M. Sadeghi,et al.  The Gas Separation Performance of Polyurethane–Zeolite Mixed Matrix Membranes , 2018 .

[191]  G. Sakellaropoulos,et al.  Gas Separation Properties of Polyimide-Zeolite Mixed Matrix Membranes , 2012 .

[192]  R. Castro‐Muñoz,et al.  New Trends in Biopolymer-Based Membranes for Pervaporation , 2019, Molecules.

[193]  A. Ehsani,et al.  Synthesis, characterization and gas permeation study of ZIF-11/Pebax® 2533 mixed matrix membranes , 2016 .

[194]  T. Tan,et al.  Engineering of filler/polymer interface in metal-organic framework-based mixed-matrix membranes to enhance gas separation. , 2019, Chemistry, an Asian journal.

[195]  Haitao Yu,et al.  Graphene Oxide/Single-Walled Carbon Nanotube Membranes for CO2 and N2 Separation from Blast Furnace Gas , 2020 .

[196]  M. W. Anjum,et al.  Modulated UiO-66-Based Mixed-Matrix Membranes for CO2 Separation. , 2015, ACS applied materials & interfaces.

[197]  S. Japip,et al.  Particle-Size Effects on Gas Transport Properties of 6FDA-Durene/ZIF-71 Mixed Matrix Membranes , 2016 .

[198]  N. Ibrahim,et al.  Polysulfone/zinc oxide nanoparticle mixed matrix membranes for CO2/CH4 separation , 2014 .

[199]  Hae‐Kwon Jeong,et al.  Recent advances on mixed-matrix membranes for gas separation: Opportunities and engineering challenges , 2018, Korean Journal of Chemical Engineering.

[200]  S. Kulprathipanja,et al.  Novel Ag+‐zeolite/polymer mixed matrix membranes with a high CO2/CH4 selectivity , 2007 .

[201]  Freek Kapteijn,et al.  Functionalized flexible MOFs as fillers in mixed matrix membranes for highly selective separation of CO2 from CH4 at elevated pressures. , 2011, Chemical communications.

[202]  Zhongying Wang,et al.  Environmental Applications of 2D Molybdenum Disulfide (MoS2) Nanosheets. , 2017, Environmental science & technology.

[203]  J. Ferraris,et al.  Molecular sieving realized with ZIF-8/Matrimid® mixed-matrix membranes , 2010 .

[204]  Development of mixed matrix membranes based on zeolite Nu-6(2) for gas separation , 2008 .

[205]  M. Sadeghi,et al.  Enhancement of the gas separation properties of polybenzimidazole (PBI) membrane by incorporation of silica nano particles , 2009 .

[206]  Yury Gogotsi,et al.  MXene molecular sieving membranes for highly efficient gas separation , 2018, Nature Communications.

[207]  R. Othaman,et al.  Permeability of carbon dioxide and nitrogen gases through SiO2 and MgO incorporated ENR/PVC membranes , 2016 .

[208]  P. Budd,et al.  Highly permeable polymers for gas separation membranes , 2010 .

[209]  W. Ho,et al.  Facilitated transport membranes for CO2 separation and capture , 2017 .

[210]  S. Kaliaguine,et al.  Mixed matrix membranes based on silica nanoparticles and microcellular polymers for CO2/CH4 separation , 2016 .

[211]  G. Shi,et al.  Graphene-Based Membranes for Molecular Separation. , 2015, The journal of physical chemistry letters.

[212]  Chongli Zhong,et al.  Synthesis of MIL-88B(Fe)/Matrimid mixed-matrix membranes with high hydrogen permselectivity , 2015 .

[213]  P. Bernardo,et al.  30 Years of Membrane Technology for Gas Separation , 2013 .

[214]  Tai‐Shung Chung,et al.  Enhanced gas separation performance of nanocomposite membranes using MgO nanoparticles , 2007 .

[215]  Yong-ming Wei,et al.  Mixed-Matrix Membrane Hollow Fibers of Cu3(BTC)2 MOF and Polyimide for Gas Separation and Adsorption , 2010 .

[216]  Ashwin R. Kamble,et al.  Different 2D materials based polyetherimide mixed matrix membranes for CO2/N2 separation , 2020 .

[217]  W. Jin,et al.  Mechanical Synthesis of COF Nanosheet Cluster and Its Mixed Matrix Membrane for Efficient CO2 Removal. , 2017, ACS applied materials & interfaces.

[218]  Dan Zhao,et al.  Mixed Matrix Membranes (MMMs) Comprising Exfoliated 2D Covalent Organic Frameworks (COFs) for Efficient CO2 Separation , 2016 .