Shear‐Thickening (“Dilatancy”) in Suspensions of Nonaggregating Solid Particles Dispersed in Newtonian Liquids
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The literature on this subject stands currently at over 100 articles; this review seeks to present an overall picture of the subject, using the results of these articles. Concentrated suspensions of nonaggregating solid particles, if measured in the appropriate shear rate range, will always show (reversible) shear thickening. The actual nature of the shear thickening will depend on the parameters of the suspended phase: phase volume, particle size (distribution), particle shape, as well as those of the suspending phase (viscosity and the details of the deformation, i.e., shear or extensional flow, steady or transient, time and rate of deformation). The explanations offered for the phenomenon that are supported by independent physical measurements postulate that the increase in viscosity is due to the transition from a two‐dimensional layered arrangement of particles to a random three‐dimensional form. The transition rarely takes more than one decade of shear rate, but it can be over a much shorter range, ...