Low‐temperature dielectric properties of candidate substrates for high‐temperature superconductors: LaAlO3 and ZrO2 : 9.5 mol % Y2O3

The effects of temperature (4–400 K), hydrostatic pressure and frequency on the dielectric constant, e’, and dielectric loss of single crystals of LaAlO3 and cubic yttria(9.5 mol %)‐stabilized zirconia (ZrO2) were investigated. Both crystals are relatively low‐loss, low‐dispersion dielectrics in the temperature range (T<150 K) of most interest for high‐temperature superconductors. The pressure results make it possible to evaluate the various contributions to the temperature dependence of e’. It is found that this dependence is dominated by the change of polarizability with volume. The dielectric properties of the two crystals are compared with those of other candidate substrate materials.

[1]  Clive H. Perry,et al.  Phase Characterization of Partially Stabilized Zirconia by Raman Spectroscopy , 1985 .

[2]  Robert Shelby,et al.  The low temperature electrical properties of some anisotropic crystals , 1979 .

[3]  M. Lanagan,et al.  The dielectric properties of yttria-stabilized zirconia , 1989 .

[4]  G. Samara,et al.  Anharmonic Effects in KTaO 3 : Ferroelectric Mode, Thermal Expansion,and Compressibility , 1973 .

[5]  G. S. Lee,et al.  Low-loss substrate for epitaxial growth of high-temperature superconductor , 1988 .

[6]  E. C. Subbarao,et al.  Advances in Ceramics , 1981 .

[7]  S. Terblanche Thermal-expansion coefficients of yttria-stabilized cubic zirconias , 1989 .

[8]  G. Samara Pressure and Temperature Dependences of the Dielectric Properties of the Perovskites BaTi O 3 and SrTi O 3 , 1966 .

[9]  Robert Benjamin Laibowitz,et al.  Critical-current measurements in epitaxial films of YBa/sub 2/Cu/sub 3/O/sub 7-//sub x/ compound , 1987 .

[10]  G. Samara,et al.  Pressure and Temperature Dependence of the Static Dielectric Constants and Raman Spectra of TiO2(Rutile) , 1973 .

[11]  J. Smith,et al.  Single‐Crystal Elastic Constants of Yttria‐Stabilized Zirconia in the Range 20° to 700°C , 1984 .

[12]  S. Geller,et al.  Crystallographic studies of perovskite‐like compounds. II. Rare earth alluminates , 1956 .

[13]  McGuire,et al.  Critical-current measurements in epitaxial films of YBa2Cu , 1987, Physical review letters.

[14]  G. Samara Temperature and pressure dependences of the dielectric properties of PbF 2 and the alkaline-earth fluorides , 1976 .