Graphitic Carbon Nitride/Graphene Hybrids as New Active Materials for Energy Conversion and Storage

Energy conversion and storage devices play an important role in industry and society with the rapid growth of energy consumption. Developing a highly efficient, environmentally friendly device mainly depends on improvements in high-performance electrode materials or catalysts. Recently, graphitic carbon nitride/graphene (g-C3N4/graphene) hybrids have drawn considerable attention and shown great potential as active materials in the field of energy conversion and storage due to their unique and tunable nanostructure, high nitrogen content, and conductivity. This review focuses on the recent significant advances in the fabrication and application of g-C3N4/graphene hybrids as electro- or photocatalysts and electrode materials. Synthetic strategies and applications for photo- or electro-related devices are presented, accompanied with a discussion of the challenges and research directions for the future development of g-C3N4/graphene hybrids.

[1]  Huakun Liu,et al.  A Metal-Free, Free-Standing, Macroporous Graphene@g-C₃N₄ Composite Air Electrode for High-Energy Lithium Oxygen Batteries. , 2015, Small.

[2]  Yao Zheng,et al.  Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions. , 2015, Chemical Society reviews.

[3]  Mietek Jaroniec,et al.  Phosphorus-doped graphitic carbon nitrides grown in situ on carbon-fiber paper: flexible and reversible oxygen electrodes. , 2015, Angewandte Chemie.

[4]  Yong Wang,et al.  Carbon nitride in energy conversion and storage: recent advances and future prospects. , 2015, ChemSusChem.

[5]  Yong Wang,et al.  Graphitic carbon nitride polymers: promising catalysts or catalyst supports for heterogeneous oxidation and hydrogenation , 2015 .

[6]  L. Qu,et al.  Monoatomic-thick graphitic carbon nitride dots on graphene sheets as an efficient catalyst in the oxygen reduction reaction. , 2015, Nanoscale.

[7]  Tongwen Xu,et al.  Graphene oxide modified graphitic carbon nitride as a modifier for thin film composite forward osmosis membrane , 2015 .

[8]  L. Qu,et al.  Sulfur-doped graphitic carbon nitride decorated with graphene quantum dots for an efficient metal-free electrocatalyst , 2015 .

[9]  L. Qu,et al.  Graphitic C3N4-Pt nanohybrids supported on a graphene network for highly efficient methanol oxidation , 2015, Science China Materials.

[10]  S. Chai,et al.  Graphene oxide as a structure-directing agent for the two-dimensional interface engineering of sandwich-like graphene-g-C3N4 hybrid nanostructures with enhanced visible-light photoreduction of CO2 to methane. , 2015, Chemical communications.

[11]  Vishal M. Dhavale,et al.  Low surface energy plane exposed Co3O4 nanocubes supported on nitrogen-doped graphene as an electrocatalyst for efficient water oxidation. , 2015, ACS applied materials & interfaces.

[12]  M. Jaroniec,et al.  Porous C3N4 nanolayers@N-graphene films as catalyst electrodes for highly efficient hydrogen evolution. , 2015, ACS nano.

[13]  Yao Zheng,et al.  Advancing the electrochemistry of the hydrogen-evolution reaction through combining experiment and theory. , 2015, Angewandte Chemie.

[14]  R. Ruoff,et al.  Graphene, related two-dimensional crystals, and hybrid systems for energy conversion and storage , 2015, Science.

[15]  Juan Li,et al.  Hollow mesoporous carbon nitride nanosphere/three-dimensional graphene composite as high efficient electrocatalyst for oxygen reduction reaction , 2014 .

[16]  W. Ho,et al.  Enhancing the photocatalytic activity of bulk g-C₃N₄ by introducing mesoporous structure and hybridizing with graphene. , 2014, Journal of colloid and interface science.

[17]  L. Qu,et al.  Graphitic carbon nitride nanoribbons: graphene-assisted formation and synergic function for highly efficient hydrogen evolution. , 2014, Angewandte Chemie.

[18]  Hui-Ming Cheng,et al.  Increasing the Visible Light Absorption of Graphitic Carbon Nitride (Melon) Photocatalysts by Homogeneous Self‐Modification with Nitrogen Vacancies , 2014, Advanced materials.

[19]  Xinchen Wang,et al.  Helical graphitic carbon nitrides with photocatalytic and optical activities. , 2014, Angewandte Chemie.

[20]  Yusuke Yamauchi,et al.  Nanoarchitectured graphene-based supercapacitors for next-generation energy-storage applications. , 2014, Chemistry.

[21]  Xiaodong Wu,et al.  Covalently coupled hybrid of graphitic carbon nitride with reduced graphene oxide as a superior performance lithium-ion battery anode. , 2014, Nanoscale.

[22]  C. Yuan,et al.  N-doped graphene/porous g-C3N4 nanosheets supported layered-MoS2 hybrid as robust anode materials for lithium-ion batteries , 2014 .

[23]  S. Qiao,et al.  Fe–N Decorated Hybrids of CNTs Grown on Hierarchically Porous Carbon for High‐Performance Oxygen Reduction , 2014, Advanced materials.

[24]  Qian Liu,et al.  Ultrathin graphitic C3 N4 nanosheets/graphene composites: efficient organic electrocatalyst for oxygen evolution reaction. , 2014, ChemSusChem.

[25]  P. Ajayan,et al.  Pt‐Decorated 3D Architectures Built from Graphene and Graphitic Carbon Nitride Nanosheets as Efficient Methanol Oxidation Catalysts , 2014, Advanced materials.

[26]  Yong Wang,et al.  Combination of carbon nitride and carbon nanotubes: synergistic catalysts for energy conversion. , 2014, ChemSusChem.

[27]  V. Khare,et al.  Hybrid photocatalysts using graphitic carbon nitride/cadmium sulfide/reduced graphene oxide (g-C3N4/CdS/RGO) for superior photodegradation of organic pollutants under UV and visible light. , 2014, Dalton transactions.

[28]  Mietek Jaroniec,et al.  Graphitic carbon nitride nanosheet-carbon nanotube three-dimensional porous composites as high-performance oxygen evolution electrocatalysts. , 2014, Angewandte Chemie.

[29]  S. Pati,et al.  Transition Metal Embedded Two-Dimensional C3N4–Graphene Nanocomposite: A Multifunctional Material , 2014 .

[30]  Youhong Tang,et al.  Proton-functionalized two-dimensional graphitic carbon nitride nanosheet: an excellent metal-/label-free biosensing platform. , 2014, Small.

[31]  Dan Wu,et al.  Cathodic electrochemiluminescence immunosensor based on nanocomposites of semiconductor carboxylated g-C3N4 and graphene for the ultrasensitive detection of squamous cell carcinoma antigen. , 2014, Biosensors & bioelectronics.

[32]  Yao Zheng,et al.  Hydrogen evolution by a metal-free electrocatalyst , 2014, Nature Communications.

[33]  Q. Yu,et al.  Template free fabrication of porous g-C3N4/graphene hybrid with enhanced photocatalytic capability under visible light , 2014 .

[34]  Luhua Lu,et al.  Sonication assisted preparation of graphene oxide/graphitic-C₃N₄ nanosheet hybrid with reinforced photocurrent for photocatalyst applications. , 2014, Dalton transactions.

[35]  M. Antonietti,et al.  Controlled carbon nitride growth on surfaces for hydrogen evolution electrodes. , 2014, Angewandte Chemie.

[36]  Xinchen Wang,et al.  Photochemical Reduction of CO2 by Graphitic Carbon Nitride Polymers , 2014 .

[37]  Qunjie Xu,et al.  Enhanced reactive oxygen species on a phosphate modified C3N4/graphene photocatalyst for pollutant degradation , 2014 .

[38]  Abdullah M. Asiri,et al.  Three-dimensional porous supramolecular architecture from ultrathin g-C(3)N(4) nanosheets and reduced graphene oxide: solution self-assembly construction and application as a highly efficient metal-free electrocatalyst for oxygen reduction reaction. , 2014, ACS applied materials & interfaces.

[39]  S. Kim,et al.  Graphene oxide-assisted production of carbon nitrides using a solution process and their photocatalytic activity , 2014 .

[40]  Dong-bo Wang,et al.  Enhancing Electrocatalytic Oxygen Reduction on Nitrogen-Doped Graphene by Active Sites Implantation , 2013, Scientific Reports.

[41]  B. Pan,et al.  Controllable disorder engineering in oxygen-incorporated MoS2 ultrathin nanosheets for efficient hydrogen evolution. , 2013, Journal of the American Chemical Society.

[42]  Junhong Chen,et al.  Constructing 2D Porous Graphitic C3N4 Nanosheets/Nitrogen‐Doped Graphene/Layered MoS2 Ternary Nanojunction with Enhanced Photoelectrochemical Activity , 2013, Advanced materials.

[43]  Porun Liu,et al.  Cross-linked g-C3 N4 /rGO nanocomposites with tunable band structure and enhanced visible light photocatalytic activity. , 2013, Small.

[44]  G. Stucky,et al.  Three-dimensional macroscopic assemblies of low-dimensional carbon nitrides for enhanced hydrogen evolution. , 2013, Angewandte Chemie.

[45]  Jens K Nørskov,et al.  Theoretical investigation of the activity of cobalt oxides for the electrochemical oxidation of water. , 2013, Journal of the American Chemical Society.

[46]  Yong Zhao,et al.  Nitrogen-doped carbon nanomaterials as non-metal electrocatalysts for water oxidation , 2013, Nature Communications.

[47]  Qiao Liu,et al.  A highly active and stable electrocatalyst for the oxygen reduction reaction based on a graphene-supported g-C3N4@cobalt oxide core–shell hybrid in alkaline solution , 2013 .

[48]  G. Stucky,et al.  From Melamine‐Cyanuric Acid Supramolecular Aggregates to Carbon Nitride Hollow Spheres , 2013 .

[49]  Yajun Wang,et al.  Nanoporous graphitic carbon nitride with enhanced photocatalytic performance. , 2013, Langmuir : the ACS journal of surfaces and colloids.

[50]  M. Antonietti,et al.  Improving carbon nitride photocatalysis by supramolecular preorganization of monomers. , 2013, Journal of the American Chemical Society.

[51]  T. Peng,et al.  Effect of graphitic carbon nitride microstructures on the activity and selectivity of photocatalytic CO2 reduction under visible light , 2013 .

[52]  L. Qu,et al.  Highly nitrogen-doped carbon capsules: scalable preparation and high-performance applications in fuel cells and lithium ion batteries. , 2013, Nanoscale.

[53]  Qiao Liu,et al.  Graphene supported Co-g-C3N4 as a novel metal-macrocyclic electrocatalyst for the oxygen reduction reaction in fuel cells. , 2013, Langmuir : the ACS journal of surfaces and colloids.

[54]  H. Vrubel,et al.  Molybdenum boride and carbide catalyze hydrogen evolution in both acidic and basic solutions. , 2012, Angewandte Chemie.

[55]  Yao Zheng,et al.  Nanostructured metal-free electrochemical catalysts for highly efficient oxygen reduction. , 2012, Small.

[56]  Liangti Qu,et al.  A versatile, ultralight, nitrogen-doped graphene framework. , 2012, Angewandte Chemie.

[57]  Jakob Kibsgaard,et al.  Engineering the surface structure of MoS2 to preferentially expose active edge sites for electrocatalysis. , 2012, Nature materials.

[58]  A. Yamada,et al.  The nature of lithium battery materials under oxygen evolution reaction conditions. , 2012, Journal of the American Chemical Society.

[59]  Youngjin Kim,et al.  Direct synthesis of self-assembled ferrite/carbon hybrid nanosheets for high performance lithium-ion battery anodes. , 2012, Journal of the American Chemical Society.

[60]  M. Antonietti,et al.  Polymeric Graphitic Carbon Nitride for Heterogeneous Photocatalysis , 2012 .

[61]  Robert W. Black,et al.  Non‐Aqueous and Hybrid Li‐O2 Batteries , 2012 .

[62]  Maria Chan,et al.  Trends in activity for the water electrolyser reactions on 3d M(Ni,Co,Fe,Mn) hydr(oxy)oxide catalysts. , 2012, Nature materials.

[63]  Klaus Müllen,et al.  3D nitrogen-doped graphene aerogel-supported Fe3O4 nanoparticles as efficient electrocatalysts for the oxygen reduction reaction. , 2012, Journal of the American Chemical Society.

[64]  Jun He,et al.  Enhancement of photocatalytic activity of Bi2WO6 hybridized with graphite-like C3N4 , 2012 .

[65]  Yao Zheng,et al.  Graphitic carbon nitride materials: controllable synthesis and applications in fuel cells and photocatalysis , 2012 .

[66]  D. Dhawale,et al.  Facile synthesis and basic catalytic application of 3D mesoporous carbon nitride with a controllable bimodal distribution , 2012 .

[67]  M. Jaroniec,et al.  Facile oxygen reduction on a three-dimensionally ordered macroporous graphitic C3N4/carbon composite electrocatalyst. , 2012, Angewandte Chemie.

[68]  Lan Jiang,et al.  Facile Fabrication of Light, Flexible and Multifunctional Graphene Fibers , 2012, Advanced materials.

[69]  Hongjian Yan Soft-templating synthesis of mesoporous graphitic carbon nitride with enhanced photocatalytic H2 evolution under visible light. , 2012, Chemical communications.

[70]  N. Peres,et al.  Electron tunneling through ultrathin boron nitride crystalline barriers. , 2012, Nano letters.

[71]  Rose Amal,et al.  Hybrid graphene and graphitic carbon nitride nanocomposite: gap opening, electron-hole puddle, interfacial charge transfer, and enhanced visible light response. , 2012, Journal of the American Chemical Society.

[72]  N. Peres,et al.  Electron tunneling through ultrathin boron nitride crystalline barriers. , 2012, Nano letters.

[73]  Huimin Zhao,et al.  Graphene oxide modified g-C3N4 hybrid with enhanced photocatalytic capability under visible light irradiation , 2012 .

[74]  S. Joo,et al.  Ordered mesoporous carbon nitrides with graphitic frameworks as metal-free, highly durable, methanol-tolerant oxygen reduction catalysts in an acidic medium. , 2012, Langmuir : the ACS journal of surfaces and colloids.

[75]  Xinchen Wang,et al.  Polymeres graphitisches Kohlenstoffnitrid als heterogener Organokatalysator: von der Photochemie über die Vielzweckkatalyse hin zur nachhaltigen Chemie , 2012 .

[76]  Yong Wang,et al.  Polymeric graphitic carbon nitride as a heterogeneous organocatalyst: from photochemistry to multipurpose catalysis to sustainable chemistry. , 2012, Angewandte Chemie.

[77]  Sean C. Smith,et al.  Nanoporous graphitic-C3N4@carbon metal-free electrocatalysts for highly efficient oxygen reduction. , 2011, Journal of the American Chemical Society.

[78]  Xiaoqiang An,et al.  Graphene-based photocatalytic composites , 2011 .

[79]  L. Niu,et al.  Non-covalent doping of graphitic carbon nitride polymer with graphene: controlled electronic structure and enhanced optoelectronic conversion , 2011 .

[80]  Arne Thomas,et al.  Mesoporous carbon nitride–silica composites by a combined sol–gel/thermal condensation approach and their application as photocatalysts , 2011 .

[81]  H. Dai,et al.  Co₃O₄ nanocrystals on graphene as a synergistic catalyst for oxygen reduction reaction. , 2011, Nature materials.

[82]  Rui Shi,et al.  Enhancement of photocurrent and photocatalytic activity of ZnO hybridized with graphite-like C3N4 , 2011 .

[83]  Feng Li,et al.  Doped graphene sheets as anode materials with superhigh rate and large capacity for lithium ion batteries. , 2011, ACS nano.

[84]  Ying Wan,et al.  Ordered mesoporous non-oxide materials. , 2011, Chemical Society reviews.

[85]  Klaus Müllen,et al.  Graphene-based carbon nitride nanosheets as efficient metal-free electrocatalysts for oxygen reduction reactions. , 2011, Angewandte Chemie.

[86]  M. Antonietti,et al.  Metal-free activation of dioxygen by graphene/g-C3N4 nanocomposites: functional dyads for selective oxidation of saturated hydrocarbons. , 2011, Journal of the American Chemical Society.

[87]  M. Jaroniec,et al.  Preparation and Enhanced Visible-Light Photocatalytic H2-Production Activity of Graphene/C3N4 Composites , 2011 .

[88]  G. Shi,et al.  Graphene based new energy materials , 2011 .

[89]  Ping Liu,et al.  Sulfur-mediated synthesis of carbon nitride: Band-gap engineering and improved functions for photocatalysis , 2011 .

[90]  Hua Zhou,et al.  Facile one-pot synthesis of bimodal mesoporous carbon nitride and its function as a lipase immobilization support , 2011 .

[91]  M. Antonietti,et al.  Synthesis of boron doped polymeric carbon nitride solids and their use as metal-free catalysts for aliphatic C–H bond oxidation , 2011 .

[92]  M. Antonietti,et al.  Synthesis of ordered porous graphitic-C3N4 and regularly arranged Ta3N5 nanoparticles by using self-assembled silica nanospheres as a primary template. , 2011, Chemistry, an Asian journal.

[93]  M. Antonietti,et al.  Synthesis of transition metal-modified carbon nitride polymers for selective hydrocarbon oxidation. , 2010, ChemSusChem.

[94]  Arne Thomas,et al.  Cubic mesoporous graphitic carbon(IV) nitride: an all-in-one chemosensor for selective optical sensing of metal ions. , 2010, Angewandte Chemie.

[95]  Xiaobo Chen,et al.  Semiconductor-based photocatalytic hydrogen generation. , 2010, Chemical reviews.

[96]  Thomas Bligaard,et al.  Modeling the Electrochemical Hydrogen Oxidation and Evolution Reactions on the Basis of Density Functional Theory Calculations , 2010 .

[97]  D. Zhao,et al.  Facile synthesis of porous carbon nitride spheres with hierarchical three-dimensional mesostructures for CO2 capture , 2010 .

[98]  Katsuhiko Ariga,et al.  Gold nanoparticles embedded in a mesoporous carbon nitride stabilizer for highly efficient three-component coupling reaction. , 2010, Angewandte Chemie.

[99]  Hui-Ming Cheng,et al.  Unique electronic structure induced high photoreactivity of sulfur-doped graphitic C3N4. , 2010, Journal of the American Chemical Society.

[100]  B. Wei,et al.  Tandem structure of porous silicon film on single-walled carbon nanotube macrofilms for lithium-ion battery applications. , 2010, ACS nano.

[101]  S. Bernhard,et al.  Fast water oxidation using iron. , 2010, Journal of the American Chemical Society.

[102]  Enoch A. Nagelli,et al.  Metal-Free Carbon Nanomaterials Become More Active than Metal Catalysts and Last Longer , 2010 .

[103]  Chun Xing Li,et al.  Chemically converted graphene as substrate for immobilizing and enhancing the activity of a polymeric catalyst. , 2010, Chemical communications.

[104]  Kun Yang,et al.  Adsorption of organic compounds by carbon nanomaterials in aqueous phase: Polanyi theory and its application. , 2010, Chemical reviews.

[105]  M. Antonietti,et al.  Facile one-pot synthesis of nanoporous carbon nitride solids by using soft templates. , 2010, ChemSusChem.

[106]  M. Antonietti,et al.  Phosphorus-doped carbon nitride solid: enhanced electrical conductivity and photocurrent generation. , 2010, Journal of the American Chemical Society.

[107]  Qiushi Yin,et al.  A Fast Soluble Carbon-Free Molecular Water Oxidation Catalyst Based on Abundant Metals , 2010, Science.

[108]  Christopher J. Chang,et al.  A molecular molybdenum-oxo catalyst for generating hydrogen from water , 2010, Nature.

[109]  Y. Liu,et al.  Nitrogen-doped graphene as efficient metal-free electrocatalyst for oxygen reduction in fuel cells. , 2010, ACS nano.

[110]  R. Kaner,et al.  Honeycomb carbon: a review of graphene. , 2010, Chemical reviews.

[111]  M. Antonietti,et al.  Mesoporous, 2D Hexagonal Carbon Nitride and Titanium Nitride/Carbon Composites , 2009 .

[112]  S. Moriya,et al.  Carbon Nitride as a Nonprecious Catalyst for Electrochemical Oxygen Reduction , 2009 .

[113]  A. Vinu,et al.  Highly ordered mesoporous carbon nitride nanoparticles with high nitrogen content: a metal-free basic catalyst. , 2009, Angewandte Chemie.

[114]  Bei Wang,et al.  In situ chemical synthesis of SnO2–graphene nanocomposite as anode materials for lithium-ion batteries , 2009 .

[115]  A S Bondarenko,et al.  Alloys of platinum and early transition metals as oxygen reduction electrocatalysts. , 2009, Nature chemistry.

[116]  C. Liang,et al.  Hierarchically Structured Sulfur/Carbon Nanocomposite Material for High-Energy Lithium Battery , 2009 .

[117]  X. Xia,et al.  A green approach to the synthesis of graphene nanosheets. , 2009, ACS nano.

[118]  M. Antonietti,et al.  Fe-g-C3N4-catalyzed oxidation of benzene to phenol using hydrogen peroxide and visible light. , 2009, Journal of the American Chemical Society.

[119]  Z. Zou,et al.  Photodegradation performance of g-C3N4 fabricated by directly heating melamine. , 2009, Langmuir : the ACS journal of surfaces and colloids.

[120]  A. Reina,et al.  Large area, few-layer graphene films on arbitrary substrates by chemical vapor deposition. , 2009, Nano letters.

[121]  S. Banerjee,et al.  Large-Area Synthesis of High-Quality and Uniform Graphene Films on Copper Foils , 2009, Science.

[122]  M. Antonietti,et al.  Metal‐Containing Carbon Nitride Compounds: A New Functional Organic–Metal Hybrid Material , 2009 .

[123]  R. Ruoff,et al.  Chemical methods for the production of graphenes. , 2009, Nature nanotechnology.

[124]  Jiaguo Yu,et al.  Enhancement of Photocatalytic Activity of Mesporous TiO2 Powders by Hydrothermal Surface Fluorination Treatment , 2009 .

[125]  S. T. Lee,et al.  High-quality Graphenes via a facile quenching method for field-effect transistors. , 2009, Nano letters.

[126]  Inhwa Jung,et al.  Colloidal suspensions of highly reduced graphene oxide in a wide variety of organic solvents. , 2009, Nano letters.

[127]  F. Du,et al.  Nitrogen-Doped Carbon Nanotube Arrays with High Electrocatalytic Activity for Oxygen Reduction , 2009, Science.

[128]  Kwang S. Kim,et al.  Large-scale pattern growth of graphene films for stretchable transparent electrodes , 2009, Nature.

[129]  G. Zou,et al.  Preparation and characterization of graphitic carbon nitride through pyrolysis of melamine , 2009 .

[130]  M. Antonietti,et al.  Polymer semiconductors for artificial photosynthesis: hydrogen evolution by mesoporous graphitic carbon nitride with visible light. , 2009, Journal of the American Chemical Society.

[131]  M. Antonietti,et al.  A metal-free polymeric photocatalyst for hydrogen production from water under visible light. , 2009, Nature materials.

[132]  Olivier Roubeau,et al.  Solutions of negatively charged graphene sheets and ribbons. , 2008, Journal of the American Chemical Society.

[133]  R. Schlögl,et al.  Graphitic carbon nitride materials: variation of structure and morphology and their use as metal-free catalysts , 2008 .

[134]  H. Dai,et al.  Highly conducting graphene sheets and Langmuir-Blodgett films. , 2008, Nature nanotechnology.

[135]  J. Coleman,et al.  High-yield production of graphene by liquid-phase exfoliation of graphite. , 2008, Nature nanotechnology.

[136]  Bei Wang,et al.  FACILE SYNTHESIS AND CHARACTERIZATION OF GRAPHENE NANOSHEETS , 2008 .

[137]  A. Vinu Two‐Dimensional Hexagonally‐Ordered Mesoporous Carbon Nitrides with Tunable Pore Diameter, Surface Area and Nitrogen Content , 2008 .

[138]  M. Armand,et al.  Building better batteries , 2008, Nature.

[139]  Yong Liu,et al.  Direct Growth of Flexible Carbon Nanotube Electrodes , 2008 .

[140]  G. Wallace,et al.  Processable aqueous dispersions of graphene nanosheets. , 2008, Nature nanotechnology.

[141]  J. Sehnert,et al.  Ab initio calculation of solid-state NMR spectra for different triazine and heptazine based structure proposals of g-C3N4. , 2007, The journal of physical chemistry. B.

[142]  Sarmimala Hore,et al.  Synthesis of Hierarchically Porous Carbon Monoliths with Highly Ordered Microstructure and Their Application in Rechargeable Lithium Batteries with High‐Rate Capability , 2007 .

[143]  M. Antonietti,et al.  Mesoporous graphitic carbon nitride as a versatile, metal-free catalyst for the cyclisation of functional nitriles and alkynes , 2007 .

[144]  S. Stankovich,et al.  Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide , 2007 .

[145]  Jong‐Sung Yu,et al.  Novel ordered nanoporous graphitic C3N4 as a support for Pt–Ru anode catalyst in direct methanol fuel cell , 2007 .

[146]  N. Lewis Toward Cost-Effective Solar Energy Use , 2007, Science.

[147]  S. Stankovich,et al.  Stable aqueous dispersions of graphitic nanoplatelets via the reduction of exfoliated graphite oxide in the presence of poly(sodium 4-styrenesulfonate) , 2006 .

[148]  George Crabtree,et al.  The hydrogen economy , 2006, IEEE Engineering Management Review.

[149]  Raouf O. Loutfy,et al.  Overcharge studies of carbon fiber composite-based lithium-ion cells , 2006 .

[150]  Arne Thomas,et al.  Chemische Synthese von mesoporösen Kohlenstoffnitriden in harten Templaten und ihre Anwendung als metallfreie Katalysatoren in Friedel‐Crafts‐Reaktionen , 2006 .

[151]  M. Antonietti,et al.  Chemical synthesis of mesoporous carbon nitrides using hard templates and their use as a metal-free catalyst for Friedel-Crafts reaction of benzene. , 2006, Angewandte Chemie.

[152]  C. Berger,et al.  Electronic Confinement and Coherence in Patterned Epitaxial Graphene , 2006, Science.

[153]  Ying Shirley Meng,et al.  Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries , 2006, Science.

[154]  Hyunwoong Park,et al.  Visible-light-sensitized production of hydrogen using perfluorosulfonate polymer-coated TiO2 nanoparticles: an alternative approach to sensitizer anchoring. , 2006, Langmuir : the ACS journal of surfaces and colloids.

[155]  P. Bruce,et al.  Rechargeable LI2O2 electrode for lithium batteries. , 2006, Journal of the American Chemical Society.

[156]  M. Antonietti,et al.  Synthesis of g‐C3N4 Nanoparticles in Mesoporous Silica Host Matrices , 2005 .

[157]  K. Ariga,et al.  Preparation and Characterization of Well‐Ordered Hexagonal Mesoporous Carbon Nitride , 2005 .

[158]  Kazuhiko Maeda,et al.  GaN:ZnO solid solution as a photocatalyst for visible-light-driven overall water splitting. , 2005, Journal of the American Chemical Society.

[159]  P. Bruce,et al.  Nanostructured materials for advanced energy conversion and storage devices , 2005, Nature materials.

[160]  R. Kaner,et al.  Intercalation and exfoliation routes to graphite nanoplatelets , 2005 .

[161]  Andre K. Geim,et al.  Electric Field Effect in Atomically Thin Carbon Films , 2004, Science.

[162]  C. Berger,et al.  Ultrathin epitaxial graphite: 2D electron gas properties and a route toward graphene-based nanoelectronics. , 2004, cond-mat/0410240.

[163]  C. Li,et al.  Graphitic carbon nitride thin films deposited by electrodeposition , 2004, Materials Letters.

[164]  K. Domen,et al.  Oxysulfide Sm2Ti2S2O5 as a Stable Photocatalyst for Water Oxidation and Reduction under Visible Light Irradiation (λ ≤ 650 nm) , 2002 .

[165]  B. V. Tilak,et al.  Interfacial processes involving electrocatalytic evolution and oxidation of H2, and the role of chemisorbed H , 2002 .

[166]  P. Kroll,et al.  Tri-s-triazine derivatives. Part I. From trichloro-tri-s-triazine to graphitic C3N4 structuresPart II: Alkalicyamelurates M3[C6N7O3], M = Li, Na, K, Rb, Cs, manuscript in preparation. , 2002 .

[167]  Hironori Arakawa,et al.  Direct splitting of water under visible light irradiation with an oxide semiconductor photocatalyst , 2001, Nature.

[168]  M. Armand,et al.  Issues and challenges facing rechargeable lithium batteries , 2001, Nature.

[169]  J. Margrave,et al.  Synthesis of Spherical Carbon Nitride Nanostructures , 2001 .

[170]  M. Bauer,et al.  High-Pressure Bulk Synthesis of Crystalline C6N9H3·HCl: A Novel C3N4 Graphitic Derivative , 2001 .

[171]  E. G. Gillan Synthesis of Nitrogen-Rich Carbon Nitride Networks from an Energetic Molecular Azide Precursor , 2000 .

[172]  J. E. Lowther RELATIVE STABILITY OF SOME POSSIBLE PHASES OF GRAPHITIC CARBON NITRIDE , 1999 .

[173]  J. Ying,et al.  SYNTHESIS AND APPLICATIONS OF SUPRAMOLECULAR-TEMPLATED MESOPOROUS MATERIALS , 1999 .

[174]  C. Mehnert,et al.  Synthese und Anwendungen von mit supramolekularen Templaten hergestellten mesoporösen Materialien , 1999 .

[175]  G. Demazeau,et al.  The Stabilization of C3N4 : New Development of Such a Material as Macroscopic Sample , 1998 .

[176]  Ortega,et al.  Relative stability of hexagonal and planar structures of hypothetical C3N4 solids. , 1995, Physical Review B (Condensed Matter).

[177]  J. S. Beck,et al.  Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism , 1992, Nature.

[178]  A. Liu,et al.  Prediction of New Low Compressibility Solids , 1989, Science.

[179]  E. C. Franklin THE AMMONO CARBONIC ACIDS , 1922 .

[180]  J. Liebig Uber einige Stickstoff ‐ Verbindungen , 1834 .