Asphaltene Deposition during CO2 Injection and Pressure Depletion: A Visual Study

Carbon dioxide miscible flooding has become a popular method for Enhanced Oil Recovery (EOR) because it not only efficiently enhances oil recovery but also considerably reduces green house gas emissions. However, it can significantly cause asphaltene deposition, which leads to serious production problems such as wettability alteration, plugging of the reservoir formation, blocking the transportation pipelines, etc. It is crucial to investigate the effects of different factors on asphaltene deposition. A novel experimental setup was prepared to employ a high-pressure visual cell for investigation of asphaltene deposition on a model rock under typical reservoir conditions. The evolution of asphaltene deposition was monitored via a high-resolution microscope. Image processing software was utilized to check the amount of deposited asphaltene and its size distribution under different conditions. Crudes from two Iranian oil fields were used in the experiments. The amount of asphaltene deposition was measured du...

[1]  G. Hirasaki,et al.  Prediction of Asphaltene Instability under Gas Injection with the PC-SAFT Equation of State† , 2005 .

[2]  S. Andersen,et al.  Study of Pressure and Temperature Effects on Asphaltene Stability in Presence of CO2 , 2006 .

[3]  B. Martínez-Haya,et al.  On the determination of molecular weight distributions of asphaltenes and their aggregates in laser desorption ionization experiments. , 2006, Journal of mass spectrometry : JMS.

[4]  S. Ayatollahi,et al.  Fractal characteristics of an asphaltene deposited heterogeneous surface , 2009 .

[5]  M. Gray,et al.  Molecular Structures of Asphaltenes Based on the Dissociation Reactions of Their Ions in Mass Spectrometry , 2010 .

[6]  O. Mullins,et al.  Molecular Size and Structure of Asphaltenes from Various Sources , 2000 .

[7]  A. S. Bemani,et al.  Laboratory investigation of thermally-assisted gas–oil gravity drainage for secondary and tertiary oil recovery in fractured models , 2007 .

[8]  G. Ali Mansoori,et al.  Aggregation and Deposition of Heavy Organics in Petroleum Crudes , 1988 .

[9]  Ning Liu,et al.  Measurement and corresponding states modeling of asphaltene precipitation in Jilin reservoir oils , 2004 .

[10]  H. Sarma,et al.  Characteristics and Impact of Asphaltene Precipitation During CO2 Injection in Sandstone and Carbonate Cores: An Investigative Analysis Through Laboratory Tests and Compositional Simulation , 2003 .

[11]  R. Idem,et al.  Kinetics of CO2-induced asphaltene precipitation from various Saskatchewan crude oils during CO2 miscible flooding , 2002 .

[12]  Yongan Gu,et al.  Mutual interactions between crude oil and CO2 under different pressures , 2008 .

[13]  A. Alamdari,et al.  Kinetics of Asphaltene Precipitation in a Heptane−Toluene Mixture , 2010 .

[14]  G. C. Klein,et al.  Mass Spectral Analysis of Asphaltenes. I. Compositional Differences between Pressure-Drop and Solvent-Drop Asphaltenes Determined by Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry , 2006 .

[15]  Jimmy Yu,et al.  Solvent deasphalting effects on whole cold lake bitumen , 1995 .

[16]  J. G. Meijer,et al.  Influence of Temperature and Pressure on Asphaltene Flocculation , 1984 .

[17]  P. M. Spiecker,et al.  Aggregation and solubility behavior of asphaltenes and their subfractions. , 2003, Journal of colloid and interface science.

[18]  Kosta J. Leontaritis,et al.  Asphaltene deposition: a survey of field experiences and research approaches , 1988 .

[19]  G. Mansoori,et al.  The Role of Asphaltene in Wettability Reversal . , 1990 .

[20]  S. Ayatollahi,et al.  Prediction of Asphaltene Precipitation: Learning from Data at Different Conditions , 2010 .

[21]  G. Ali Mansoori,et al.  Modeling of asphaltene and other heavy organic depositions , 1997 .

[22]  W. Svrcek,et al.  Effects of temperature and pressure on asphaltene particle size distributions in crude oils diluted with n-pentane , 1994 .

[23]  S. Ayatollahi,et al.  Investigating wettability alteration due to asphaltene precipitation: Imprints in surface multifractal characteristics , 2010 .

[24]  James G. Speight,et al.  Fuel Science and Technology Handbook , 1990 .

[25]  Sam Huang,et al.  Asphaltene Deposition During CO2 Flooding , 1999 .

[26]  G. Mansoori Modeling and prevention of asphaltene and other heavy organic deposition in oil wells , 1994 .

[27]  Riyaz Kharrat,et al.  Study of the VAPEX Process in Fractured Physical Systems Using Different Solvent Mixtures , 2008 .

[28]  J. Buckley Effective wettability of minerals exposed to crude oil , 2001 .

[29]  J. Buckley,et al.  Crude oil and asphaltene characterization for prediction of wetting alteration , 2002 .

[30]  L. H. Stiles,et al.  Review of the means San Andres unit CO2 tertiary project , 1990 .

[31]  David A. Wood,et al.  Challenges, risks can be managed in deepwater oil and gas projects , 2006 .

[32]  G. A. Mansoori,et al.  Identification and measurement of petroleum precipitates , 2000 .

[33]  Yongan Gu,et al.  Four Important Onset Pressures for Mutual Interactions between Each of Three Crude Oils and CO2 , 2010 .