Preparation and characterisation of demineralised tyre derived activated carbon

Abstract The effect of demineralisation and activation conditions on the physical and chemical properties of activated carbon adsorbents produced from waste tyre char has been investigated. Experimental data showed that hydrochloric acid treatment prior to the activation is able to remove certain mineral contents such as zinc, calcium, sodium and others from the tyre char. The removal of some of the components which have catalytic effect on the activation increase the yield of the activated carbon and at the same time lower the ash content of the tyre activated carbon. The tyre demineralised activated carbons are generally mesoporous with a surface area up to 960 m2/g and therefore are comparable to commercial products. The adsorption of phenol onto the tyre activated carbon was also tested and the Redlich–Peterson equilibrium isotherm model gave the best-fit to experimental data for the phenol using the non-linear error functions.

[1]  G. Sakellaropoulos,et al.  Enhanced mercury adsorption in activated carbons from biomass materials and waste tires , 2007 .

[2]  G. Mckay,et al.  Mesoporous activated carbon from waste tyre rubber for dye removal from effluents , 2010 .

[3]  R. Sips,et al.  On the Structure of a Catalyst Surface , 1948 .

[4]  M. Lázaro,et al.  Cherry stones as precursor of activated carbons for supercapacitors , 2009 .

[5]  H. Tamon,et al.  Adsorption-desorption characteristics of phenol and reactive dyes from aqueous solution on mesoporous activated carbon prepared from waste tires. , 2005, Water research.

[6]  Juan Daniel Martínez,et al.  Production of activated carbon by waste tire thermochemical degradation with CO2. , 2009, Journal of hazardous materials.

[7]  Xiaoqin Liu,et al.  Peanut Shell Activated Carbon: Characterization, Surface Modification and Adsorption of Pb2+ from Aqueous Solution , 2008 .

[8]  G. S. Miguel,et al.  Porosity and surface characteristics of activated carbons produced from waste tyre rubber , 2002 .

[9]  A. Neimark,et al.  Experimental Confirmation of Different Mechanisms of Evaporation from Ink-Bottle Type Pores: Equilibrium, Pore Blocking, and Cavitation , 2002 .

[10]  Akbar A. Merchant,et al.  PREPARATION AND CHARACTERIZATION OF ACTIVATED CARBONS FROM SCRAP TIRES, ALMOND SHELLS, AND ILLINOIS COAL , 1992 .

[11]  T. Anirudhan,et al.  Removal of mercury(II) from aqueous solutions and chlor-alkali industry effluent by steam activated and sulphurised activated carbons prepared from bagasse pith: kinetics and equilibrium studies. , 2002, Journal of hazardous materials.

[12]  Todd A. Brady,et al.  Adsorbed Natural Gas Storage with Activated Carbons Made from Illinois Coals and Scrap Tires , 1997 .

[13]  G. S. Miguel,et al.  A study of the characteristics of activated carbons produced by steam and carbon dioxide activation of waste tyre rubber , 2003 .

[14]  Q. Yao,et al.  Properties of Pyrolytic Chars and Activated Carbons Derived from Pilot-Scale Pyrolysis of Used Tires , 2005, Journal of the Air & Waste Management Association.

[15]  Paul T. Williams,et al.  Influence of Process Conditions on the Rate of Activation of Chars Derived from Pyrolysis of Used Tires , 1999 .

[16]  S. Mukherjee,et al.  Effect of leaching high sulphur subbituminous coal by potassium hydroxide and acid on removal of mineral matter and sulphur , 2003 .

[17]  Mohammed M. Farid,et al.  Adsorption kinetics for the removal of chromium(VI) from aqueous solution by adsorbents derived from used tyres and sawdust , 2001 .

[18]  Jale Yanik,et al.  Evaluation of two different scrap tires as hydrocarbon source by pyrolysis , 2005 .

[19]  A. Harris,et al.  Influence of carbon dioxide partial pressure and fluidization velocity on activated carbons prepared from scrap car tyre in a fluidized bed , 2006 .

[20]  Hsisheng Teng,et al.  Mesoporous carbons from waste tire char and their application in wastewater discoloration , 2002 .

[21]  K. Zhang,et al.  Role of chemical pre-treatment in the development of super-high surface areas and heteroatom fixation in activated carbons prepared from bagasse , 2008 .

[22]  E. Teller,et al.  ADSORPTION OF GASES IN MULTIMOLECULAR LAYERS , 1938 .

[23]  Maria Stanciulescu,et al.  Characterization and potential applications of pyrolytic char from ablative pyrolysis of used tires , 2001 .

[24]  Irving Langmuir THE CONSTITUTION AND FUNDAMENTAL PROPERTIES OF SOLIDS AND LIQUIDS. PART I. SOLIDS. , 1916 .

[25]  J. H. de Boer,et al.  Studies on pore systems in catalysts: V. The t method , 1965 .

[26]  José M. Encinar,et al.  Preparation of activated carbons from used tyres by gasification with steam and carbon dioxide , 2006 .

[27]  H. Freundlich Über die Adsorption in Lösungen , 1907 .

[28]  S Galvagno,et al.  Steam gasification of tyre waste, poplar, and refuse-derived fuel: a comparative analysis. , 2009, Waste management.

[29]  Todd A. Brady,et al.  Applications for activated carbons from waste tires: natural gas storage and air pollution control , 1996 .

[30]  T. Bandosz Chapter 5 Desulfurization on activated carbons , 2006 .

[31]  S. J. Gregg,et al.  Adsorption Surface Area and Porosity , 1967 .

[32]  G. Mckay,et al.  Sulfur fixation on bagasse activated carbon by chemical treatment and its effect on acid dye adsorption , 2009 .

[33]  T. García,et al.  Kinetic Model Comparison for Waste Tire Char Reaction with CO2 , 2004 .

[34]  Peter R. Solomon,et al.  Reprocessing of used tires into activated carbon and other products , 1995 .

[35]  G. Lopez,et al.  Steam activation of pyrolytic tyre char at different temperatures , 2009 .

[36]  K. Sing Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984) , 1985 .

[37]  J. A. Menéndez,et al.  On the difference between the isoelectric point and the point of zero charge of carbons , 1995 .

[38]  Gordon McKay,et al.  Production of active carbons from waste tyres––a review , 2004 .

[39]  M. R. Jan,et al.  Conversion of Waste Tyres into Carbon Black and their Utilization as Adsorbent , 2006 .

[40]  O. Redlich,et al.  A USEFUL ADSORPTION ISOTHERM , 1959 .

[41]  B. Shi,et al.  Production, characterization and properties of chloridized mesoporous activated carbon from waste tyres. , 2009 .

[42]  H. Teng,et al.  Liquid-phase adsorption of phenol by activated carbons prepared from bituminous coals with different oxygen contents , 1999 .

[43]  G. Lu,et al.  Effects of Surface Chemistry on Aromatic Compound Adsorption from Dilute Aqueous Solutions by Activated Carbon , 2002 .

[44]  A. Huitson,et al.  A general treatment and classification of the solute adsorption isotherm. I. Theoretical , 1974 .

[45]  I. Aarna,et al.  Porosity development in carbons derived from scrap automobile tires , 2007 .

[46]  H. Tamon,et al.  Preparation and characterization of mesoporous activated carbon from waste tires , 2003 .

[47]  Gordon McKay,et al.  Adsorption of acid dyes by bamboo derived activated carbon , 2008 .

[48]  C. Yuan,et al.  The Adsorptive Capacity of Vapor-Phase Mercury Chloride onto Powdered Activated Carbon Derived from Waste Tires , 2006, Journal of the Air & Waste Management Association.

[49]  H. Tamon,et al.  Adsorption of phenol and reactive dye from aqueous solution on activated carbons derived from solid wastes. , 2004, Water research.

[50]  N. S. Polyakov,et al.  Porous structure and adsorption properties of active carbon , 1993 .