Poly[[bis[μ-1,2-bis(4-pyridyl)ethene]bis(trichloroacetato)cadmium(II)] monohydrate]

In the crystal structure of the title compound, {[Cd(C2Cl3O2)2(C12H10N2)2]·H2O}n, the CdII ion lies on a twofold rotation axis and 1,2-bis(4-pyridyl)ethene ligands bridge symmetry-related CdII ions, forming a two-dimensional structure. Two trichloroacetate ligands complete the coordination around the CdII ion, forming a distorted octahedral environment. In the crystal, solvent water molecules, which also lie on twofold rotation axes, form intermolecular O—H⋯O hydrogen bonds, which connect the two-dimensional structure into a three-dimensional network. The crystal studied was an inversion twin, the refined ratio of twin components being 0.75 (4):0.25 (4).

[1]  Kumar Biradha,et al.  Molecular paneling via coordination , 2001 .

[2]  Youngmee Kim,et al.  Structure and heterogeneous catalytic activity of a coordination polymer containing Cu(NO3)2 and Cu(H2O)2+2 units bridged alternatively by btp ligands (btp = 2,6-bis(N'-1,2,4-triazolyl)pyridine) , 2005 .

[3]  H. Flack,et al.  On enantiomorph‐polarity estimation , 1983 .

[4]  G. Sheldrick A short history of SHELX. , 2008, Acta crystallographica. Section A, Foundations of crystallography.

[5]  Kimoon Kim Mechanically interlocked molecules incorporating cucurbituril and their supramolecular assemblies. , 2002, Chemical Society reviews.

[6]  H Li,et al.  Modular chemistry: secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks. , 2001, Accounts of chemical research.

[7]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[8]  S. Teat,et al.  Di- and trinuclear CoII complexes of a bis-β-diketone ligand with variable conformation: structure and magnetic studies , 2006 .

[9]  S. Takizawa,et al.  Metal-bridged polymers as insoluble multicomponent asymmetric catalysts with high enantiocontrol: an approach for the immobilization of catalysts without using any support. , 2003, Angewandte Chemie.

[10]  Susumu Kitagawa,et al.  Functional porous coordination polymers. , 2004, Angewandte Chemie.

[11]  Youngmee Kim,et al.  Synthesis, structure and heterogeneous catalytic activities of Cu-containing polymeric compounds: anion effect and comparison of homogeneous vs. heterogeneous catalytic activity. , 2004, Dalton transactions.

[12]  H. Hou,et al.  Fe(Cu)‐Containing Coordination Polymers: Syntheses, Crystal Structures, and Applications as Benzyl Alcohol Oxidation Catalysts , 2006 .

[13]  Sung-Jin Kim,et al.  Synthesis, structure and heterogeneous catalytic activity of a coordination polymer containing tetranuclear Cu(II)-btp units connected by nitrates , 2003 .

[14]  Stuart R Batten,et al.  Interpenetrating Nets: Ordered, Periodic Entanglement. , 1998, Angewandte Chemie.

[15]  Wenbin Lin,et al.  Crystal engineering of NLO materials based on metal--organic coordination networks. , 2002, Accounts of chemical research.

[16]  M. Zaworotko,et al.  From molecules to crystal engineering: supramolecular isomerism and polymorphism in network solids. , 2001, Chemical reviews.