Growth of carbon nanotubes over Colombian natural limonite ore as catalysts

Multi-walled carbon nanotubes were synthesized using methane as carbon source and Colombian natural limonite ore as catalyst precursor. Catalyst was evaluated in reduced form in the reaction decomposition of methane at 700°C. Multi walled carbon nanotubes were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM) and thermogravimetric analysis (TGA). Finally, TEM micrographs showed that the MWCNTs have inner diameters ranging from 5 to 30 nm and outer diameters up to about 60 nm, and several microns in length.

[1]  F. Mondragón,et al.  Synthesis of MWCNTs and hydrogen from ethanol catalytic decomposition over a Ni/La2O3 catalyst produced by the reduction of LaNiO3 , 2011 .

[2]  F. Mondragón,et al.  Production of hydrogen and MWCNTs by methane decomposition over catalysts originated from LaNiO3 perovskite , 2010 .

[3]  Y. Ohtsuka,et al.  Sulfur tolerance of an inexpensive limonite catalyst for high temperature decomposition of ammonia , 2008 .

[4]  M. C. Guerreiro,et al.  Natural and H2-reduced limonite for organic oxidation by a Fenton-like system: Mechanism study via ESI-MS and theoretical calculations , 2007 .

[5]  A. Tuantranont,et al.  Parametric study of atmospheric-pressure single-walled carbon nanotubes growth by ferrocene–ethanol mist CVD , 2007 .

[6]  Y. Tsunawaki,et al.  Production of single-wall carbon nanotubes by a XeCl excimer laser ablation , 2006 .

[7]  A. Kiennemann,et al.  Characterization and activity in dry reforming of methane on NiMg/Al and Ni/MgO catalysts , 2006 .

[8]  D. S. Misra,et al.  FTIR studies of nitrogen doped carbon nanotubes , 2006 .

[9]  I. Saito,et al.  Hydrocracking Marlim vacuum residue with natural limonite. Part 2: experimental cracking in a slurry-type continuous reactor , 2005 .

[10]  S. Sugita,et al.  Highly active limonite catalysts for direct coal liquefaction , 2002 .

[11]  K. Lozano,et al.  Nanofiber‐reinforced thermoplastic composites. I. Thermoanalytical and mechanical analyses , 2001 .

[12]  Zhengwei Pan,et al.  Mechanical and physical properties on carbon nanotube , 2000 .

[13]  Anthony K. Cheetham,et al.  Preparation of aligned carbon nanotubes catalysed by laser-etched cobalt thin films , 1998 .

[14]  N. Mel’nik,et al.  Carbon nanotubes of polyethylene , 1997 .

[15]  S. Xie,et al.  Large-Scale Synthesis of Aligned Carbon Nanotubes , 1996, Science.

[16]  T. Ichihashi,et al.  Opening carbon nanotubes with oxygen and implications for filling , 1993, Nature.

[17]  S. Iijima Helical microtubules of graphitic carbon , 1991, Nature.