Experimental study of the mechanical properties and durability of self-compacting mortars with nano materials (SiO2 and TiO2)

Abstract Cement, as well as the remaining constituents of self-compacting mortars, must be carefully selected, in order to obtain an adequate composition with a granular mix as compact as possible and a good performance in the fresh state (self-compacting effect) and the hardened state (mechanical and durability-related behavior). Therefore in this work the possibility of incorporating nano particles in self-compacting mortars was studied. Nano materials are very reactive due mostly to their high specific surface and show a great potential to improve the properties of these mortars, both in mechanical and durability terms. In this work two nano materials were used, nano silica (nano SiO 2 ) in colloidal state and nano titanium (nano TiO 2 ) in amorphous state, in two types of self-compacting mortars (ratio binder:sand of 1:1 and 1:2). The self-compacting mortar mixes have the same water/cement ratio and 30% of replacement of cement with fly ashes. The influence of nano materials nano-SiO 2 and nano-TiO 2 on the fresh and hardened state properties of these self-compacting mortars was studied. The results show that the use of nano materials in repair and rehabilitation mortars has significant potential but still needs to be optimized.

[1]  Dachamir Hotza,et al.  Effect of nano-silica on rheology and fresh properties of cement pastes and mortars , 2009 .

[2]  Surendra P. Shah,et al.  Modification of cement-based materials with nanoparticles , 2013 .

[3]  J. Jawahar,et al.  OPTIMIZATION OF SUPERPLASTICISER AND VISCOSITY MODIFYING AGENT IN SELF COMPACTING MORTAR , 2013 .

[4]  A. Nazari,et al.  THE EFFECTS OF SIO2 NANOPARTICLES ON PHYSICAL AND MECHANICAL PROPERTIES OF HIGH STRENGTH COMPACTING CONCRETE , 2010 .

[5]  K. Day,et al.  Aggregates for concrete , 2013 .

[6]  A. Fujishima,et al.  TiO2 photocatalysis and related surface phenomena , 2008 .

[7]  Hajime Okamura,et al.  Self-Compacting Concrete , 2000 .

[8]  M. Oltulu,et al.  Effect of nano-SiO2, nano-Al2O3 and nano-Fe2O3 powders on compressive strengths and capillary water absorption of cement mortar containing fly ash: A comparative study , 2013 .

[9]  A. Nazari,et al.  RETRACTED: The effects of TiO2 nanoparticles on properties of binary blended concrete , 2011 .

[10]  Hamlin M. Jennings,et al.  Influence of Nucleation Seeding on the Hydration Mechanisms of Tricalcium Silicate and Cement , 2009 .

[11]  J. Dolado,et al.  Effect of Nanosilica Additions on Belite Cement Pastes Held in Sulfate Solutions , 2007 .

[12]  A. Neville Properties of Concrete , 1968 .

[13]  Gengying Li,et al.  Properties of high-volume fly ash concrete incorporating nano-SiO2 , 2004 .

[14]  M. Criado,et al.  Effect of sodium sulfate on the alkali activation of fly ash , 2010 .

[15]  Jahidul Islam,et al.  Use of nano-silica to reduce setting time and increase early strength of concretes with high volumes of fly ash or slag , 2012 .

[16]  Florence Sanchez,et al.  Nanotechnology in concrete – A review , 2010 .

[17]  Peter Domone,et al.  Relationships between the fresh properties of scc and its mortar component , 2002 .

[18]  J. Ou,et al.  Microstructure of cement mortar with nano-particles , 2004 .

[19]  A. Nazari,et al.  The effect of TiO2 nanoparticles on water permeability and thermal and mechanical properties of high strength self-compacting concrete , 2010 .

[20]  M. Liu,et al.  Wider application of additions in self-compacting concrete , 2009 .

[21]  P. Hewlett,et al.  Lea's chemistry of cement and concrete , 2001 .

[22]  Ta-Peng Chang,et al.  Effect of nanosilica on characterization of Portland cement composite , 2006 .

[23]  J. de Brito,et al.  Experimental study of the porosity and microstructure of self-compacting concrete (SCC) with binary and ternary mixes of fly ash and limestone filler , 2015 .

[24]  Tao Meng,et al.  Effect of nano-TiO2 on the mechanical properties of cement mortar , 2012 .

[25]  J. Ou,et al.  Flexural fatigue performance of concrete containing nano-particles for pavement , 2007 .

[26]  Ioanna Papayianni,et al.  Influence of nano-SiO2 on the Portland cement pastes , 2012 .

[27]  J. Brito,et al.  Electrical resistivity and capillarity of self-compacting concrete with incorporation of fly ash and limestone filler , 2013 .

[28]  Sergio M.R. Lopes,et al.  Methodology for mix design of the mortar phase of self-compacting concrete using different mineral additions in binary blends of powders , 2012 .

[29]  Tao Ji,et al.  Preliminary study on the water permeability and microstructure of concrete incorporating nano-SiO2 , 2005 .

[30]  J. Labrincha,et al.  Effect of nano-SiO2 and nano-TiO2 addition on the rheological behavior and the hardened properties of cement mortars , 2012 .

[31]  Luca Bertolini,et al.  Corrosion of Steel in Concrete , 2013 .