Nitrogen-doped carbons by sustainable N- and C-containing natural resources as nonprecious catalysts and catalyst supports for low temperature fuel cells

Nitrogen-doped carbon materials represent a significant part in the field of energy conversion and storage technologies such as proton exchange membrane fuel cells and supercapacitors. The achievement of these materials by sustainable N- and C-containing natural resources using various methods, such as pyrolysis, hydrothermal and ionothermal carbonization is presented. The application of these novel materials as nonprecious catalysts and catalyst supports for low temperature fuel cells is discussed.

[1]  J. Figueiredo,et al.  Synthesis and characterization of nitrogen-doped carbon xerogels , 2009 .

[2]  Yong Wang,et al.  Improved electrocatalytic activity for ethanol oxidation by Pd@N-doped carbon from biomass. , 2014, Chemical communications.

[3]  C. Ciavatta,et al.  Influence of blood meal organic fertilizer on soil organic matter: a laboratory study , 1997 .

[4]  D. Bhattacharjya,et al.  Seaweed-derived heteroatom-doped highly porous carbon as an electrocatalyst for the oxygen reduction reaction. , 2014, ChemSusChem.

[5]  Christophe Coutanceau,et al.  Recent advances in the development of direct alcohol fuel cells (DAFC) , 2002 .

[6]  Qiuping Zhao,et al.  Direct synthesis of nitrogen-doped carbon nanosheets with high surface area and excellent oxygen reduction performance. , 2014, Langmuir : the ACS journal of surfaces and colloids.

[7]  E. Barbarino,et al.  Amino acid composition, protein content and calculation of nitrogen‐to‐protein conversion factors for 19 tropical seaweeds , 2002 .

[8]  Yoshio Takasu,et al.  High oxygen-reduction activity of silk-derived activated carbon , 2009 .

[9]  Yitai Qian,et al.  Synthesis of nitrogen-doped carbon and application in highly selective and sensitive dopamine sensing , 2014 .

[10]  Robin J. White,et al.  Ordered Carbohydrate-Derived Porous Carbons , 2011 .

[11]  M. Rahman,et al.  Effect of Nitrogen on Seed Yield, Protein Content and Nutrient Uptake of Soybean (Glycine max L.) , 2008 .

[12]  R. López-Fandiño,et al.  Comparative study of egg white proteins from different species by chromatographic and electrophoretic methods , 2005 .

[13]  Li Zhao,et al.  Sustainable nitrogen-doped carbonaceous materials from biomass derivatives , 2010 .

[14]  Huyen N. Dinh,et al.  Enhancement of Pt and Pt-alloy fuel cell catalyst activity and durability via nitrogen-modified carbon supports , 2010 .

[15]  Hong Wang,et al.  Nitrogen-doped carbon based on peptides of hair as electrode materials for surpercapacitors , 2013 .

[16]  G. Yushin,et al.  Hydrothermal synthesis of microalgae-derived microporous carbons for electrochemical capacitors , 2014 .

[17]  Freek Kapteijn,et al.  Evolution of nitrogen functionalities in carbonaceous materials during pyrolysis , 1995 .

[18]  M. Antonietti,et al.  One-step hydrothermal synthesis of nitrogen-doped nanocarbons: albumine directing the carbonization of glucose. , 2010, ChemSusChem.

[19]  S. Dong,et al.  Nitrogen, cobalt-codoped carbon electrocatalyst for oxygen reduction reaction using soy milk and cobalt salts as precursors , 2013 .

[20]  P. Stein,et al.  Structure and properties of ovalbumin. , 2001, Journal of chromatography. B, Biomedical sciences and applications.

[21]  Robin J. White,et al.  Black perspectives for a green future: hydrothermal carbons for environment protection and energy storage , 2012 .

[22]  Hairong Xue,et al.  Enhanced electrocatalytic activity of platinum supported on nitrogen modified ordered mesoporous car , 2011 .

[23]  S. Ogale,et al.  Yogurt: a novel precursor for heavily nitrogen doped supercapacitor carbon , 2015 .

[24]  E. Wang,et al.  Energetic carbon-based hybrids: green and facile synthesis from soy milk and extraordinary electrocatalytic activity towards ORR. , 2014, Nanoscale.

[25]  F. Renzo,et al.  Aerogel materials from marine polysaccharides , 2008 .

[26]  S. Ji,et al.  Egg White Derived Tremella-Like Mesoporous Carbon as Efficient Non-Precious Electrocatalyst for Oxygen Reduction , 2014 .

[27]  Changpeng Liu,et al.  Biomass-derived N-doped carbon and its application in electrocatalysis , 2014 .

[28]  Robin J. White,et al.  Naturally inspired nitrogen doped porous carbon , 2009 .

[29]  A. Mohamad,et al.  Recent progress in nitrogen-doped carbon and its composites as electrocatalysts for fuel cell applications , 2013 .

[30]  S. Ji,et al.  The enhanced electrocatalytic activity of okara-derived N-doped mesoporous carbon for oxygen reduction reaction , 2015 .

[31]  J. Murillo,et al.  Long-Term Biomonitoring of Soil Contamination Using Poplar Trees: Accumulation of Trace Elements in Leaves and Fruits , 2013, International journal of phytoremediation.

[32]  S. Ji,et al.  Beef-derived mesoporous carbon as highly efficient support for PtRuIr electrocatalysts and their high activity for CO and methanol oxidation , 2014 .

[33]  Maria Angeles Lillo-Rodenas,et al.  Spherical carbons: Synthesis, characterization and activation processes , 2014 .

[34]  Ermete Antolini,et al.  The stability of Pt–M (M = first row transition metal) alloy catalysts and its effect on the activity in low temperature fuel cells: A literature review and tests on a Pt–Co catalyst , 2006 .

[35]  Robin J. White,et al.  Template Synthesis of Carbonaceous Tubular Nanostructures with Tunable Surface Properties , 2010 .

[36]  M. Antonietti,et al.  Aminated hydrophilic ordered mesoporous carbons , 2007 .

[37]  Shuyan Gao,et al.  Nitrogen-enriched carbon from bamboo fungus with superior oxygen reduction reaction activity , 2014 .

[38]  K. Phani,et al.  Nitrogen-doped carbon black as methanol tolerant electrocatalyst for oxygen reduction reaction in direct methanol fuel cells , 2012 .

[39]  Drew C. Higgins,et al.  Nitrogen doped carbon nanotubes and their impact on the oxygen reduction reaction in fuel cells , 2010 .

[40]  Shuqin Song,et al.  Low and non-platinum electrocatalysts for PEMFCs: Current status, challenges and prospects , 2012 .

[41]  Markus Antonietti,et al.  Structural Characterization of Hydrothermal Carbon Spheres by Advanced Solid-State MAS C-13 NMR Investigations , 2009 .

[42]  D. Zhao,et al.  A facile aqueous route to synthesize highly ordered mesoporous polymers and carbon frameworks with Ia3d bicontinuous cubic structure. , 2005, Journal of the American Chemical Society.

[43]  Wenming Qiao,et al.  Chemical state of nitrogen in carbon aerogels issued from phenol–melamine–formaldehyde gels , 2008 .

[44]  Dang Sheng Su,et al.  Heterogeneous nanocarbon materials for oxygen reduction reaction , 2014 .

[45]  Zhongwei Chen,et al.  A review on non-precious metal electrocatalysts for PEM fuel cells , 2011 .

[46]  Joan-Hwa Yang,et al.  Physicochemical characterization of chitin and chitosan from crab shells. , 2009 .

[47]  S. Dai,et al.  Updating biomass into functional carbon material in ionothermal manner. , 2014, ACS applied materials & interfaces.

[48]  M. Mitrić,et al.  Electrocatalysis of oxygen reduction reaction on polyaniline-derived nitrogen-doped carbon nanoparticle surfaces in alkaline media , 2012 .

[49]  Jong-Won Lee,et al.  A review of the development of nitrogen-modified carbon-based catalysts for oxygen reduction at USC , 2011 .

[50]  S. Tanaka,et al.  Synthesis of ordered mesoporous carbons with channel structure from an organic-organic nanocomposite. , 2005, Chemical communications.

[51]  Dingsheng Yuan,et al.  N-doped mesoporous carbon as a bifunctional material for oxygen reduction reaction and supercapacitors , 2014 .

[52]  F. Rodríguez-Reinoso,et al.  Role of chemical activation in the development of carbon porosity , 2004 .

[53]  S. Ji,et al.  Biomass-derived activated carbon as high-performance non-precious electrocatalyst for oxygen reduction , 2013 .

[54]  Tamer M. Alslaibi,et al.  A review: production of activated carbon from agricultural byproducts via conventional and microwave heating , 2013 .

[55]  E. Gonzalez,et al.  An overview of platinum-based catalysts as methanol-resistant oxygen reduction materials for direct methanol fuel cells , 2008 .

[56]  Markus Antonietti,et al.  Mesoporous nitrogen-doped carbon for the electrocatalytic synthesis of hydrogen peroxide. , 2012, Journal of the American Chemical Society.

[57]  S. Benjakul,et al.  Effect of Different Cations on Pidan Composition and Flavor in Comparison to the Fresh Duck Egg , 2013 .

[58]  Qiuping Zhao,et al.  Nitrogen-doped porous carbon nanosheets made from biomass as highly active electrocatalyst for oxygen reduction reaction , 2014 .

[59]  A. Manthiram,et al.  Mesoporous Carbons with Controlled Porosity as an Electrocatalytic Support for Methanol Oxidation , 2005 .

[60]  W. Sugimoto,et al.  Oxygen-reduction activity of silk-derived carbons , 2010 .

[61]  A. Chuvilin,et al.  XPS and TEM study of new carbon material: N-containing catalytic filamentous carbon , 2000 .

[62]  Maria-Magdalena Titirici,et al.  Morphological and structural differences between glucose, cellulose and lignocellulosic biomass derived hydrothermal carbons , 2011 .

[63]  Yaqin Huang,et al.  Pig Bone Derived Hierarchical Porous Carbon‐Supported Platinum Nanoparticles with Superior Electrocatalytic Activity Towards Oxygen Reduction Reaction , 2014 .

[64]  Huan Wang,et al.  Nitrogen doped large mesoporous carbon for oxygen reduction electrocatalyst using DNA as carbon and nitrogen precursor , 2012 .

[65]  M. Antonietti,et al.  Nitrogen‐Containing Hydrothermal Carbons with Superior Performance in Supercapacitors , 2010, Advanced materials.

[66]  Y. Chisti,et al.  Protein measurements of microalgal and cyanobacterial biomass. , 2010, Bioresource technology.

[67]  D. Kubmarawa,et al.  Determination Of Plant Proteins Via The Kjeldahl Method And Amino Acid Analysis: A Comparative Study. , 2014 .

[68]  E. Barbarino,et al.  DISTRIBUTION OF INTRACELLULAR NITROGEN IN MARINE MICROALGAE: BASIS FOR THE CALCULATION OF SPECIFIC NITROGEN‐TO‐PROTEIN CONVERSION FACTORS , 1998 .

[69]  Ana Primo,et al.  From biomass wastes to large-area, high-quality, N-doped graphene: catalyst-free carbonization of chitosan coatings on arbitrary substrates. , 2012, Chemical communications.

[70]  Jong‐Sung Yu,et al.  Transforming hair into heteroatom-doped carbon with high surface area. , 2014, Small.

[71]  Jianji Wang,et al.  Transforming organic-rich amaranthus waste into nitrogen-doped carbon with superior performance of the oxygen reduction reaction , 2015 .

[72]  Martin M. F. Choi,et al.  Facile synthesis of nitrogen-doped carbon dots for Fe(3+) sensing and cellular imaging. , 2015, Analytica chimica acta.

[73]  W. Schuhmann,et al.  PtRu nanoparticles supported on nitrogen-doped multiwalled carbon nanotubes as catalyst for methanol electrooxidation , 2009 .

[74]  H. Gasteiger,et al.  Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs , 2005 .

[75]  A. Olejniczak,et al.  The influence of microporosity creation in highly mesoporous N-containing carbons obtained from chitosan on their catalytic and electrochemical properties , 2014 .

[76]  Jiang Deng,et al.  Controlled synthesis of sustainable N-doped hollow core-mesoporous shell carbonaceous nanospheres from biomass , 2014, Nano Research.

[77]  R. Lovitt,et al.  Placing microalgae on the biofuels priority list: a review of the technological challenges , 2010, Journal of The Royal Society Interface.

[78]  E. Antolini Carbon supports for low-temperature fuel cell catalysts , 2009 .

[79]  Shiguo Zhang,et al.  Direct Synthesis of Nitrogen-Doped Carbon Materials from Protic Ionic Liquids and Protic Salts: Structural and Physicochemical Correlations between Precursor and Carbon , 2014 .

[80]  Robin J. White,et al.  Renewable nitrogen-doped hydrothermal carbons derived from microalgae. , 2012, ChemSusChem.

[81]  Markus Antonietti,et al.  Chemistry and materials options of sustainable carbon materials made by hydrothermal carbonization. , 2010, Chemical Society reviews.

[82]  Ermete Antolini,et al.  Formation of carbon-supported PtM alloys for low temperature fuel cells: a review , 2003 .

[83]  Martin M. F. Choi,et al.  Green synthesis of fluorescent nitrogen/sulfur-doped carbon dots and investigation of their properties by HPLC coupled with mass spectrometry , 2014 .

[84]  Y. Sakka,et al.  Doped-carbon electrocatalysts with trimodal porosity from a homogeneous polypeptide gel , 2013 .

[85]  H. García,et al.  High-yield production of N-doped graphitic platelets by aqueous exfoliation of pyrolyzed chitosan , 2014 .

[86]  Sudipta Roy,et al.  Spectroelectrochemical Study of the Role Played by Carbon Functionality in Fuel Cell Electrodes , 1997 .

[87]  Wenjing Yuan,et al.  Nitrogen-doped nanoporous carbon nanosheets derived from plant biomass: an efficient catalyst for oxygen reduction reaction , 2014 .

[88]  Anastasia Zabaniotou,et al.  Agricultural residues as precursors for activated carbon production—A review , 2007 .

[89]  Changsui Zhao,et al.  Evolution of fuel-N in gas phase during biomass pyrolysis , 2015 .

[90]  S. Saxena,et al.  Synthesis and characterization of functionalized CNTs using soya and milk protein , 2014, Applied Nanoscience.

[91]  Robin J. White,et al.  Hierarchical porous carbonaceous materials via ionothermal carbonization of carbohydrates , 2011 .

[92]  Chang Yu,et al.  Hydrothermal synthesis and activation of graphene-incorporated nitrogen-rich carbon composite for high-performance supercapacitors , 2014 .

[93]  J. Lukaszewicz,et al.  Novel nitrogen-containing mesoporous carbons prepared from chitosan , 2013 .

[94]  H. Matsuda,et al.  Preparation of activated carbon from phenolic resin by KOH chemical activation under microwave heating , 2009 .

[95]  Hao Gong,et al.  Exploration of the active center structure of nitrogen-doped graphene-based catalysts for oxygen reduction reaction , 2012 .

[96]  S. Zignani,et al.  Stability of Pt–Ni/C (1:1) and Pt/C electrocatalysts as cathode materials for polymer electrolyte fuel cells: Effect of ageing tests , 2009 .

[97]  S. Liao,et al.  High-performance doped carbon electrocatalyst derived from soybean biomass and promoted by zinc chloride , 2014 .

[98]  F. Rodríguez-Reinoso,et al.  Effect of steam and carbon dioxide activation in the micropore size distribution of activated carbon , 1996 .

[99]  S. Srinivasan,et al.  Quantum jumps in the PEMFC science and technology from the 1960s to the year 2000 Part I. Fundamental scientific aspects , 2001 .

[100]  Zheng Hu,et al.  The production of carbon microtubes by the carbonization of catkins and their use in the oxygen reduction reaction , 2011 .

[101]  Nigel P. Brandon,et al.  Review of gas diffusion cathodes for alkaline fuel cells , 2009 .

[102]  C. Liang,et al.  Synthesis of mesoporous carbon materials via enhanced hydrogen-bonding interaction. , 2006, Journal of the American Chemical Society.

[103]  Robin J. White,et al.  Borax‐Mediated Formation of Carbon Aerogels from Glucose , 2012 .

[104]  M. Antonietti,et al.  Tunable nitrogen-doped carbon aerogels as sustainable electrocatalysts in the oxygen reduction reaction , 2013 .

[105]  Zhengxiao Guo,et al.  Naturally derived porous carbon with selective metal- and/or nitrogen-doping for efficient CO2 capture and oxygen reduction , 2015 .

[106]  Andrew Dicks,et al.  Non precious metal catalysts for the PEM fuel cell cathode , 2012 .

[107]  A. Szczurek,et al.  The use of tannin to prepare carbon gels. Part I: Carbon aerogels , 2011 .

[108]  R. Mayes,et al.  Ionothermal carbonization of sugars in a protic ionic liquid under ambient conditions , 2010 .

[109]  Z. Tang,et al.  Hydrothermal transformation of dried grass into graphitic carbon-based high performance electrocatalyst for oxygen reduction reaction. , 2014, Small.

[110]  Changguo Chen,et al.  Design of a non-precious metal electrocatalyst for alkaline electrolyte oxygen reduction by using soybean biomass as the nitrogen source of electrocatalytically active center structures , 2014 .

[111]  M. Antonietti,et al.  Replication and Coating of Silica Templates by Hydrothermal Carbonization , 2007 .

[112]  F. J. Maldonado-Hódar,et al.  Carbon aerogels for catalysis applications: An overview , 2005 .

[113]  M. Antonietti,et al.  Efficient metal-free oxygen reduction in alkaline medium on high-surface-area mesoporous nitrogen-doped carbons made from ionic liquids and nucleobases. , 2011, Journal of the American Chemical Society.

[114]  S. Kingman,et al.  Microwave technology for energy-efficient processing of waste , 2005 .

[115]  Robin J. White,et al.  Functional hollow carbon nanospheres by latex templating. , 2010, Journal of the American Chemical Society.

[116]  E. Nxumalo,et al.  Nitrogen Doped Carbon Nanotubes from Organometallic Compounds: A Review , 2010, Materials.

[117]  Yuyan Shao,et al.  Nitrogen-doped carbon nanostructures and their composites as catalytic materials for proton exchange membrane fuel cell , 2008 .

[118]  K. S. Hui,et al.  Synthesis of nitrogen-doped multilayer graphene from milk powder with melamine and their application to fuel cells , 2014 .

[119]  Jie Yu,et al.  Nitrogen-doped activated carbon with micrometer-scale channels derived from luffa sponge fibers as electrocatalysts for oxygen reduction reaction with high stability in acidic media , 2014 .

[120]  Changguo Chen,et al.  A novel nitrogen-containing electrocatalyst for oxygen reduction reaction from blood protein pyrolysis , 2014 .

[121]  A. Manthiram,et al.  Mesoporous Carbon with Larger Pore Diameter as an Electrocatalyst Support for Methanol Oxidation , 2004 .

[122]  Gang Xu,et al.  Synthesis of Colloidal Carbon Spheres by Hydrothermal Carbonization of Glucose at Different Initial pH , 2011 .

[123]  Tom Welton,et al.  Room-temperature ionic liquids: solvents for synthesis and catalysis. 2. , 1999, Chemical reviews.

[124]  S. Ogale,et al.  Synthesis of an efficient heteroatom-doped carbon electro-catalyst for oxygen reduction reaction by pyrolysis of protein-rich pulse flour cooked with SiO2 nanoparticles. , 2014, Physical chemistry chemical physics : PCCP.

[125]  Haibo Li,et al.  Synthesis of three-dimensional flowerlike nitrogen-doped carbons by a copyrolysis route and the effect of nitrogen species on the electrocatalytic activity in oxygen reduction reaction , 2013 .

[126]  Y. Bando,et al.  Structure and nitrogen incorporation of carbon nanotubes synthesized by catalytic pyrolysis of dimethylformamide , 2004 .

[127]  Robin J. White,et al.  A sustainable synthesis of nitrogen-doped carbon aerogels , 2011 .

[128]  Monika Černá Seaweed proteins and amino acids as nutraceuticals. , 2011, Advances in food and nutrition research.

[129]  Robin J. White,et al.  Carbohydrate-derived hydrothermal carbons: a thorough characterization study. , 2012, Langmuir : the ACS journal of surfaces and colloids.

[130]  S. Ji,et al.  Synthesis of Mesoporous Carbon from Okara and Application as Electrocatalyst Support , 2014 .

[131]  U. Larsson,et al.  Carbon, nitrogen and phosphorus stoichiometry of crustacean zooplankton in the Baltic Sea: implications for nutrient recycling , 1999 .

[132]  F. Collard,et al.  A review on pyrolysis of biomass constituents: Mechanisms and composition of the products obtained from the conversion of cellulose, hemicelluloses and lignin , 2014 .

[133]  J. Marais Relationship between nitrogen and other chemical components in kikuyu grass from long-established pastures , 1990 .

[134]  Shichun Mu,et al.  Egg derived nitrogen-self-doped carbon/carbon nanotube hybrids as noble-metal-free catalysts for oxygen reduction , 2014 .

[135]  F. Motasemi,et al.  A review on the microwave-assisted pyrolysis technique , 2013 .

[136]  Ferdi Schüth,et al.  Nanocasting: A Versatile Strategy for Creating Nanostructured Porous Materials , 2009 .

[137]  M. Titirici,et al.  Polypyrrole-derived mesoporous nitrogen-doped carbons with intrinsic catalytic activity in the oxygen reduction reaction , 2013 .

[138]  E. Liang,et al.  *Synthesis and correlation study on the morphology and Raman spectra of CNx nanotubes by thermal decomposition of ferrocene/ethylenediamine , 2003 .

[139]  Shichun Mu,et al.  An animal liver derived non-precious metal catalyst for oxygen reduction with high activity and stability , 2014 .

[140]  A. Mohamed,et al.  Preparation of carbon molecular sieve from lignocellulosic biomass: A review , 2010 .

[141]  Huan Wang,et al.  Nitrogen-doped ordered mesoporous carbons synthesized from honey as metal-free catalyst for oxygen reduction reaction , 2013 .

[142]  Yun Wang,et al.  Self-supported bimodal-pore structured nitrogen-doped carbon fiber aerogel as electrocatalyst for oxygen reduction reaction , 2015 .

[143]  S. Zignani,et al.  Evaluation of the stability and durability of Pt and Pt-Co/C catalysts for polymer electrolyte membrane fuel cells , 2008 .

[144]  Jianji Wang,et al.  Nitrogen-doped carbon shell structure derived from natural leaves as a potential catalyst for oxygen reduction reaction , 2015 .

[145]  B. Parker,et al.  Biochemical composition of three algal species proposed as food for captive freshwater mussels , 2004, Journal of Applied Phycology.

[146]  Huanlei Wang,et al.  Mesoporous nitrogen-rich carbons derived from protein for ultra-high capacity battery anodes and supercapacitors , 2013 .

[147]  S. Ji,et al.  Mesoporous nitrogen-doped carbon derived from carp with high electrocatalytic performance for oxygen reduction reaction , 2015 .

[148]  Ahmed M. Elkhatat,et al.  Advances in Tailoring Resorcinol‐Formaldehyde Organic and Carbon Gels , 2011, Advances in Materials.

[149]  S. Liao,et al.  High-Performance Doped Carbon Catalyst Derived from Nori Biomass with Melamine Promoter , 2014 .

[150]  L. Qu,et al.  Large scale production of biomass-derived N-doped porous carbon spheres for oxygen reduction and supercapacitors , 2014 .

[151]  S. Ji,et al.  Soybean-derived mesoporous carbon as an effective catalyst support for electrooxidation of methanol , 2014 .

[152]  Kun-Hong Lee,et al.  Synthesis of high carbon content microspheres using 2-step microwave carbonization, and the influence of nitrogen doping on catalytic activity , 2013 .

[153]  S. Joo,et al.  Synthesis and characterization of mesoporous carbon for fuel cell applications , 2007 .

[154]  A. Stein Advances in Microporous and Mesoporous Solids—Highlights of Recent Progress , 2003 .

[155]  S. Ji,et al.  Chicken bone-derived N-doped porous carbon materials as an oxygen reduction electrocatalyst , 2014 .

[156]  A. Lu,et al.  Synthesis of Polyacrylonitrile-Based Ordered Mesoporous Carbon with Tunable Pore Structures , 2004 .

[157]  Ermete Antolini,et al.  Alkaline direct alcohol fuel cells , 2010 .

[158]  Tie-hu Li,et al.  Preparation of activated carbons by microwave heating KOH activation , 2007 .