Screen Printed Flexible Water Activated Battery on Woven Cotton Textile as a Power Supply for E-Textile Applications

Electronic textiles (e-textiles) development has been attracting significant research interest over the past two decades, especially in the field of wearable electronics. Fabric based flexible batteries are an attractive solution to the challenge of powering e-textiles. This work presents a simple and scalable textile primary battery, produced via a low-cost screen-printing manufacturing process. The device architecture is purposefully simple, based on a standard aluminum-silver redox reaction and a salt bridge. The battery as manufactured is inactive and requires the addition of water to be activated, and it can therefore be classified as a reserve battery. The battery is suitable for long-term storage, having negligible self-discharge rates. Initial batteries achieved a total area capacity of <inline-formula> <tex-math notation="LaTeX">$101.6~\mu $ </tex-math></inline-formula>Ah/cm<sup>2</sup> and an energy density of 2.178 mWh/cm<sup>3</sup> above 0.8 V. Further refinements of the battery include the inclusion of a novel membrane separator within the woven cotton textile layer and blending the metal salts with polyvinyl alcohol to reduce the number of textile layers. This optimization resulted in an improved performance of <inline-formula> <tex-math notation="LaTeX">$166.8~\mu $ </tex-math></inline-formula>Ah/cm<sup>2</sup> in area capacity and 3.686 mWh/cm<sup>3</sup> in energy density above 0.8 V. This work has demonstrated the feasibility of an aluminum-silver reserve textile battery and demonstrates a novel method for printing a phase inversion membrane separator into the textile. Following an encapsulation process, this flexible textile battery can be easily integrated into a standard woven textile, providing a robust, lightweight and flexible power supply.

[1]  V. Caron,et al.  United states. , 2018, Nursing standard (Royal College of Nursing (Great Britain) : 1987).

[2]  Alessandro Chiolerio,et al.  Wearable Electronics and Smart Textiles: A Critical Review , 2014, Sensors.

[3]  Kylie Peppler,et al.  Stitching Circuits: Learning About Circuitry Through E-textile Materials , 2013 .

[4]  Reinhard R. Baumann,et al.  Printed batteries and conductive patterns in technical textiles , 2018 .

[5]  Yvonne Freeh,et al.  Handbook Of Batteries , 2016 .

[6]  Sheng Yong,et al.  Wearable Textile Power Module Based on Flexible Ferroelectret and Supercapacitor , 2019, Energy Technology.

[7]  Guoqiang Liu,et al.  Flexible and stable high-energy lithium-sulfur full batteries with only 100% oversized lithium , 2018, Nature Communications.

[8]  Chris Craig,et al.  Water Activated Primary Textile Battery , 2019, 2019 IEEE International Conference on Flexible and Printable Sensors and Systems (FLEPS).

[9]  Russel Torah,et al.  Dispenser-printed sound-emitting fabrics for applications in the creative fashion and smart architecture industry , 2019 .

[10]  Miguel Carvalho,et al.  Design improvement of flexible textile aluminium-air battery , 2020 .

[11]  Gregorio López,et al.  A Review on Architectures and Communications Technologies for Wearable Health-Monitoring Systems , 2012, Sensors.

[12]  Genevieve Dion,et al.  Natural Fiber Welded Electrode Yarns for Knittable Textile Supercapacitors , 2015 .

[13]  Gozde Goncu-Berk,et al.  A Healthcare Wearable for Chronic Pain Management. Design of a Smart Glove for Rheumatoid Arthritis , 2017 .

[14]  Ki Bang Lee,et al.  Two-step activation of paper batteries for high power generation: design and fabrication of biofluid- and water-activated paper batteries , 2006 .

[15]  Hyun-Joong Chung,et al.  Two‐Layered and Stretchable e‐Textile Patches for Wearable Healthcare Electronics , 2018, Advanced healthcare materials.

[16]  R Martins,et al.  Self-Rechargeable Paper Thin-Film Batteries: Performance and Applications , 2010, Journal of Display Technology.

[17]  L. Castano,et al.  Smart fabric sensors and e-textile technologies: a review , 2014 .

[18]  Xiyuan Liu,et al.  A liquid-activated textile battery for wearable biosensors , 2015 .

[19]  Matthew Louis Mauriello,et al.  Social fabric fitness: the design and evaluation of wearable E-textile displays to support group running , 2014, CHI.

[20]  João Gomes,et al.  Wearable E-Textile Technologies: A Review on Sensors, Actuators and Control Elements , 2018 .

[21]  Jie Yu,et al.  Weavable, Conductive Yarn-Based NiCo//Zn Textile Battery with High Energy Density and Rate Capability. , 2017, ACS nano.

[22]  Yi Li,et al.  Solution Processed Organic Solar Cells on Textiles , 2018, IEEE Journal of Photovoltaics.

[23]  Asimina Kiourti,et al.  Power Generation for Wearable Electronics: Designing Electrochemical Storage on Fabrics , 2018, IEEE Access.

[24]  Qiongfeng Shi,et al.  Beyond energy harvesting - multi-functional triboelectric nanosensors on a textile , 2019, Nano Energy.

[25]  Howie N. Chu,et al.  Highly Stretchable Alkaline Batteries Based on an Embedded Conductive Fabric , 2012, Advanced materials.

[26]  Ki Bang Lee,et al.  Urine-activated paper batteries for biosystems , 2005 .

[27]  Zan Gao,et al.  Towards flexible lithium-sulfur battery from natural cotton textile , 2017 .

[28]  Anne Schwarz,et al.  A roadmap on smart textiles , 2010 .

[29]  Yun Jung Lee,et al.  Flexible Lithium-Ion Batteries with High Areal Capacity Enabled by Smart Conductive Textiles. , 2018, Small.