Low-cost high-performance solid-state asymmetric supercapacitors based on MnO2 nanowires and Fe2O3 nanotubes.

A low-cost high-performance solid-state flexible asymmetric supercapacitor (ASC) with α-MnO2 nanowires and amorphous Fe2O3 nanotubes grown on flexible carbon fabric is first designed and fabricated. The assembled novel flexible ASC device with an extended operating voltage window of 1.6 V exhibits excellent performance such as a high energy density of 0.55 mWh/cm(3) and good rate capability. The ASC devices can find numerous applications as effective power sources, such as powering color-switchable sun glasses and smart windows.

[1]  Ching-Ping Wong,et al.  Superior Capacitance of Functionalized Graphene , 2011 .

[2]  G. Chen,et al.  Nanostructured materials for the construction of asymmetrical supercapacitors , 2010 .

[3]  Afriyanti Sumboja,et al.  Large Areal Mass, Flexible and Free‐Standing Reduced Graphene Oxide/Manganese Dioxide Paper for Asymmetric Supercapacitor Device , 2013, Advanced materials.

[4]  D. Bélanger,et al.  A Hybrid Fe3 O 4 ­ MnO2 Capacitor in Mild Aqueous Electrolyte , 2003 .

[5]  François Béguin,et al.  Optimisation of an asymmetric manganese oxide/activated carbon capacitor working at 2 V in aqueous medium , 2006 .

[6]  Caofeng Pan,et al.  Optical Fiber‐Based Core–Shell Coaxially Structured Hybrid Cells for Self‐Powered Nanosystems , 2012, Advanced materials.

[7]  Y. Gogotsi,et al.  Materials for electrochemical capacitors. , 2008, Nature materials.

[8]  Akihiko Hirata,et al.  Nanoporous metal/oxide hybrid electrodes for electrochemical supercapacitors. , 2011, Nature nanotechnology.

[9]  Jian Jiang,et al.  Iron Oxide-Based Nanotube Arrays Derived from Sacrificial Template-Accelerated Hydrolysis: Large-Area Design and Reversible Lithium Storage , 2010 .

[10]  Feng Li,et al.  High-energy MnO2 nanowire/graphene and graphene asymmetric electrochemical capacitors. , 2010, ACS nano.

[11]  A. Mansour,et al.  Electroless deposition of conformal nanoscale iron oxide on carbon nanoarchitectures for electrochemical charge storage. , 2010, ACS nano.

[12]  Xinliang Feng,et al.  2D Sandwich‐like Sheets of Iron Oxide Grown on Graphene as High Energy Anode Material for Supercapacitors , 2011, Advanced materials.

[13]  Zhian Zhang,et al.  Highly ordered iron oxide nanotube arrays as electrodes for electrochemical energy storage , 2011 .

[14]  Qiang Zhang,et al.  Advanced Asymmetric Supercapacitors Based on Ni(OH)2/Graphene and Porous Graphene Electrodes with High Energy Density , 2012 .

[15]  Zhenbo Cai,et al.  An Integrated "energy wire" for both photoelectric conversion and energy storage. , 2012, Angewandte Chemie.

[16]  Zexiang Shen,et al.  Synthesis of Single-Crystal Tetragonal α-MnO2 Nanotubes , 2008 .

[17]  Mao-Sung Wu,et al.  Electrochemical Growth of Iron Oxide Thin Films with Nanorods and Nanosheets for Capacitors , 2009 .

[18]  Teng Zhai,et al.  H‐TiO2@MnO2//H‐TiO2@C Core–Shell Nanowires for High Performance and Flexible Asymmetric Supercapacitors , 2013, Advanced materials.

[19]  Xu Xiao,et al.  Paper-based supercapacitors for self-powered nanosystems. , 2012, Angewandte Chemie.

[20]  Teng Zhai,et al.  WO3–x@Au@MnO2 Core–Shell Nanowires on Carbon Fabric for High‐Performance Flexible Supercapacitors , 2012, Advanced materials.

[21]  Candace K. Chan,et al.  Printable thin film supercapacitors using single-walled carbon nanotubes. , 2009, Nano letters.

[22]  Jun Zhou,et al.  Flexible solid-state supercapacitors based on carbon nanoparticles/MnO2 nanorods hybrid structure. , 2012, ACS nano.

[23]  Yi Shi,et al.  Preparation and characterization of flexible asymmetric supercapacitors based on transition-metal-oxide nanowire/single-walled carbon nanotube hybrid thin-film electrodes. , 2010, ACS nano.

[24]  M. El‐Kady,et al.  Laser Scribing of High-Performance and Flexible Graphene-Based Electrochemical Capacitors , 2012, Science.

[25]  M. Chigane,et al.  Manganese Oxide Thin Film Preparation by Potentiostatic Electrolyses and Electrochromism , 2000 .

[26]  D. Bélanger,et al.  Asymmetric electrochemical capacitors—Stretching the limits of aqueous electrolytes , 2011 .

[27]  Hong Liu,et al.  Hierarchical porous carbon aerogel derived from bagasse for high performance supercapacitor electrode. , 2014, Nanoscale.

[28]  J. Xu,et al.  Flexible asymmetric supercapacitors based upon Co9S8 nanorod//Co3O4@RuO2 nanosheet arrays on carbon cloth. , 2013, ACS nano.

[29]  X. Zhao,et al.  Ultrathin MnO2 nanofibers grown on graphitic carbon spheres as high-performance asymmetric supercapacitor electrodes , 2012 .

[30]  Lingbo Zhu,et al.  Hierarchical silicon etched structures for controlled hydrophobicity/superhydrophobicity. , 2007, Nano letters.

[31]  Wei Wang,et al.  Three dimensional few layer graphene and carbon nanotube foam architectures for high fidelity supercapacitors , 2013 .

[32]  Zhong Lin Wang,et al.  A self-powered electrochromic device driven by a nanogenerator , 2012 .

[33]  Wen Chen,et al.  Polypyrrole-coated paper for flexible solid-state energy storage , 2013 .

[34]  G. Chen,et al.  Individual and Bipolarly Stacked Asymmetrical Aqueous Supercapacitors of CNTs / SnO2 and CNTs / MnO2 Nanocomposites , 2009 .

[35]  Teng Zhai,et al.  High energy density asymmetric quasi-solid-state supercapacitor based on porous vanadium nitride nanowire anode. , 2013, Nano letters.

[36]  R. Sun,et al.  Flexible Asymmetrical Solid-State Supercapacitors Based on Laboratory Filter Paper. , 2016, ACS nano.

[37]  K. Asami,et al.  The X-ray photo-electron spectra ofseveral oxides of iron and chromium , 1977 .

[38]  Zhong Lin Wang,et al.  Self-powered system with wireless data transmission. , 2011, Nano letters.

[39]  Mao-Sung Wu,et al.  Nanostructured Iron Oxide Films Prepared by Electrochemical Method for Electrochemical Capacitors , 2009 .

[40]  Xu Xiao,et al.  WO3−x/MoO3−x Core/Shell Nanowires on Carbon Fabric as an Anode for All‐Solid‐State Asymmetric Supercapacitors , 2012 .

[41]  Zhixiang Wei,et al.  Integrated energy storage and electrochromic function in one flexible device: an energy storage smart window , 2012 .

[42]  Ching-ping Wong,et al.  Graphene-based nitrogen self-doped hierarchical porous carbon aerogels derived from chitosan for high performance supercapacitors , 2015 .

[43]  Mathieu Toupin,et al.  Charge Storage Mechanism of MnO2 Electrode Used in Aqueous Electrochemical Capacitor , 2004 .

[44]  B. Conway Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications , 1999 .

[45]  Yuanyuan Li,et al.  Construction of high-capacitance 3D CoO@polypyrrole nanowire array electrode for aqueous asymmetric supercapacitor. , 2013, Nano letters.

[46]  Mao-Sung Wu,et al.  Electrodeposition of iron oxide nanorods on carbon nanofiber scaffolds as an anode material for lithium-ion batteries , 2010 .

[47]  R. Ruoff,et al.  Incorporation of manganese dioxide within ultraporous activated graphene for high-performance electrochemical capacitors. , 2012, ACS nano.

[48]  Yong Ding,et al.  Hydrogenated ZnO core-shell nanocables for flexible supercapacitors and self-powered systems. , 2013, ACS nano.

[49]  T. Yamashita,et al.  Analysis of XPS spectra of Fe2+ and Fe3+ ions in oxide materials , 2008 .

[50]  Yun Suk Huh,et al.  High performance of a solid-state flexible asymmetric supercapacitor based on graphene films. , 2012, Nanoscale.

[51]  Teng Zhai,et al.  Stabilized TiN nanowire arrays for high-performance and flexible supercapacitors. , 2012, Nano letters.

[52]  Yu-Lun Chueh,et al.  Fiber-based all-solid-state flexible supercapacitors for self-powered systems. , 2012, ACS nano.