Opportunities and challenges for treating rare-earth elements

Rare-earth elements (REEs) have become an important group of metals used in various high-tech industries. In this paper, the authors have first reviewed and discussed various mineral-processing techniques used in the processing of these REE-containing ores. Because the majority of minerals from which REEs are extracted are monazite, bastnasite, and xenotime, the discussion has focused around the ores containing these three minerals. Following this discussion, various leaching technologies have been reviewed and problems associated with leaching technologies have been assessed again in the context of the afore-mentioned three minerals. The leaching technologies discussed here include leaching using various acids, and also leaching after acidic and alkaline roasting of the ores. Because of chemical similarities of these REEs, it is very difficult to separate the individual elements from each other. Various technologies used in this regard including chemical precipitation, ion exchange, and solvent extraction have been reviewed and discussed in detail. The effect of speciation of REEs in the solutions on the selective recovery has also been investigated.

[1]  C. A. Morais,et al.  Recovery of europium by chemical reduction of a commercial solution of europium and Gadolinium chlorides , 2001 .

[2]  Jinyoung Lee,et al.  Overview on the Technologies for Extraction of Rare Earth Metals , 2012 .

[3]  Fathi Habashi,et al.  Extractive metallurgy of rare earths , 2013 .

[4]  M. Černá,et al.  Extraction of light rare earth elements by amines at high inorganic nitrate concentration , 1992 .

[5]  F. H. Firsching,et al.  Solubility products of the rare-earth carbonates , 1986 .

[6]  E. I. Shabana,et al.  Solvent extraction of lanthanum(III) from sulphuric acid solutions by Primene JMT , 1985 .

[7]  G. M. Ritcey,et al.  Solvent extraction : principles and applications to process metallurgy , 1979 .

[8]  Adam Jordens,et al.  A review of the beneficiation of rare earth element bearing minerals , 2013 .

[9]  D. Dreisinger,et al.  A critical review on solvent extraction of rare earths from aqueous solutions , 2014 .

[10]  M. Goto,et al.  EXTRACTION OF RARE EARTH METALS WITH 2-ETHYLHEXYL PHOSPHONIC ACID MONO-2-ETHYLHEXYL ESTER IN THE PRESENCE OF DIETHYLENETRIAMINEPENTAACETIC ACID IN AQUEOUS PHASE , 1993 .

[11]  M. Reddy,et al.  Synergistic extraction of rare earths with bis(2,4,4-trimethyl pentyl) dithiophosphinic acid and trialkyl phosphine oxide. , 1999, Talanta.

[12]  C. Peirce An unpublished manuscript) , 2016 .

[13]  Pradip,et al.  The role of inorganic and organic reagents in the flotation separation of rare-earth ores , 1991 .

[14]  Hongyang Gao,et al.  Preparation of enriched cerium oxide from bastnasite with hydrochloric acid by two-step leaching , 2006 .

[15]  A. M. Abeidu The separation of monazite from zircon by flotation , 1972 .

[16]  A. Peres,et al.  Utilisation of hydroxamates in minerals froth flotation , 1996 .

[17]  Tian Jun,et al.  Kinetics on leaching rare earth from the weathered crust elution-deposited rare earth ores with ammonium sulfate solution , 2010 .

[18]  K. Kondo,et al.  Novel Separation of Samarium, Europium and Gadolinium Using a Column Packed with Microcapsules Containing 2_ethylexylphosphonic Acid Mono-2-ethylexyl Ester , 2013 .

[19]  Arthur E. Martell,et al.  Critical Stability Constants , 2011 .

[20]  H. Sakamoto,et al.  Magnetic Separation of Monazite and Xenotime , 1991 .

[21]  E. D. Cyan Handbook of Chemistry and Physics , 1970 .

[22]  G. Moldoveanu,et al.  Recovery of rare earth elements adsorbed on clay minerals: II. Leaching with ammonium sulfate , 2013 .

[23]  D. F. Peppard,et al.  Fractional extraction of the lanthanides as their di-alkyl orthophosphates , 1957 .

[24]  Vladimiros G. Papangelakis,et al.  Recovery of rare earth elements adsorbed on clay minerals: I. Desorption mechanism , 2012 .

[25]  D. F. Peppard,et al.  Extraction of U(VI), Th(IV), Am(III) and Eu(III) by bis para-octylphenyl phosphoric acid in benzene diluent , 1978 .

[26]  Ishak Karakaya,et al.  Rare earth double sulfates from pre-concentrated bastnasite , 2008 .

[27]  Guangxian Xu,et al.  Rare earth separation in China , 2006 .

[28]  R. Vijayalakshmi,et al.  Processing of xenotime concentrate by sulphuric acid digestion and selective thorium precipitation for separation of rare earths , 2001 .

[29]  K. N. Han,et al.  Behavior of anions in association with metal ions under hydrometallurgical environments: Part I — OH− effect on various cations , 2014 .

[30]  F. H. Firsching,et al.  Solubility products of the trivalent rare-earth phosphates , 1991 .

[31]  B. Ramachandra Reddy,et al.  Solid‐Liquid Extraction of Terbium from Phosphoric Acid Medium using Bifunctional Phosphinic Acid Resin, Tulsion CH‐96 , 2009 .

[32]  Douglas W. Fuerstenau,et al.  Design and development of novel flotation reagents for the beneficiation of Mountain Pass rare-earth ore , 2013 .

[33]  R. Houot,et al.  Recovery of Rare Earth Minerals, with Emphasis on Flotation Process , 1991 .

[34]  The Synthesis and Characterization of Rare-Earth Fluocarbonates , 2013 .

[35]  M. C. Fuerstenau,et al.  Principles of mineral processing , 2003 .

[36]  C. A. Morais,et al.  Process development for the recovery of high-grade lanthanum by solvent extraction , 2004 .

[37]  T. Cheng,et al.  Froth flotation of monazite and xenotime , 1993 .

[38]  T. Wagner,et al.  An experimental study of the solubility and speciation of the Rare Earth Elements (III) in fluoride- and chloride-bearing aqueous solutions at temperatures up to 300 C , 2009 .

[39]  Shaoxian Song,et al.  Selective flotation of bastnaesite from monazite in rare earth concentrates using potassium alum as depressant , 2000 .

[40]  Shaoxian Song,et al.  A new collector for rare earth mineral flotation , 1997 .

[41]  유재형,et al.  Solubility of Rare Earth Oxalate in Oxalic and Nitric Acid Media , 1998 .

[42]  Eung-ho Kim,et al.  RESEARCH PAPERS : Solubility of Rare Earth Oxalate in Oxalic and Nitric Acid Media , 1998 .

[43]  H. Yamashita,et al.  Flotation of Rare-Earth Ions with Octadecyliminobis- methylenebisphosphonic Acid , 1992 .

[44]  RARE EARTHS,et al.  On the Rare Earths , 1926, Nature.

[45]  C. A. Morais,et al.  Purification of rare earth elements from monazite sulphuric acid leach liquor and the production of high-purity ceric oxide , 2010 .

[46]  F. H. Spedding,et al.  Conductances, Solubilities and Ionization Constants of Some Rare Earth Sulfates in Aqueous Solutions at 25° , 1954 .

[47]  D. S. Flett Solvent extraction in hydrometallurgy: the role of organophosphorus extractants , 2005 .

[48]  G. Yu,et al.  SOLVENT EXTRACTION OF CERIUM(IV) AND FLUORINE(I) FROM SULPHURIC ACID LEACHING OF BASTNASITE BY CYANEX 923 , 2001 .

[49]  Y. El-Nadi Lanthanum and neodymium from Egyptian monazite: Synergistic extractive separation using organophosphorus reagents , 2012 .

[50]  M. A. Hasan,et al.  Modeling of gadolinium recovery from nitrate medium with 8-hydroxyquinoline by emulsion liquid membrane. , 2009, Journal of hazardous materials.

[51]  J. Havel,et al.  Separation of rare earth elements by high performance liquid chromatography using a covalent modified silica gel column , 2001 .

[52]  Hui Zhang,et al.  Solvent extraction of lanthanides and yttrium from nitrate medium with CYANEX 925 in heptane , 2007 .

[53]  J. Rydberg,et al.  Solvent extraction principles and practice , 2004 .