Au-free epitaxial growth of InAs nanowires.

III-V nanowires have been fabricated by metal-organic vapor-phase epitaxy without using Au or other metal particles as a catalyst. Instead, prior to growth, a thin SiOx layer is deposited on the substrates. Wires form on various III-V substrates as well as on Si. They are nontapered in thickness and exhibit a hexagonal cross-section. From high-resolution X-ray diffraction, the epitaxial relation between wires and substrates is demonstrated and their crystal structure is determined.

[1]  Lars Samuelson,et al.  Nanowire resonant tunneling diodes , 2002 .

[2]  James S. Harris,et al.  Ti-catalyzed Si nanowires by chemical vapor deposition: Microscopy and growth mechanisms , 2001 .

[3]  Lars Samuelson,et al.  Fabrication of individually seeded nanowire arrays by vapour–liquid–solid growth , 2003 .

[4]  Kenji Hiruma,et al.  Growth and optical properties of nanometer‐scale GaAs and InAs whiskers , 1995 .

[5]  Lars Samuelson,et al.  Growth of one-dimensional nanostructures in MOVPE , 2004 .

[6]  P. Yu,et al.  Vertically aligned, catalyst-free InP nanowires grown by metalorganic chemical vapor deposition , 2005 .

[7]  Shui-Tong Lee,et al.  Semiconductor nanowires: synthesis, structure and properties , 2000 .

[8]  L. Samuelson,et al.  Tunable effective g factor in InAs nanowire quantum dots , 2005 .

[9]  W. Ostwald Studien über die Bildung und Umwandlung fester Körper , 1897 .

[10]  Peter Lawætz Stability of the Wurtzite Structure , 1972 .

[11]  Philip J. Poole,et al.  Spatially controlled, nanoparticle-free growth of InP nanowires , 2003 .

[12]  Lars Samuelson,et al.  One-dimensional heterostructures in semiconductor nanowhiskers , 2002 .

[13]  Lars Samuelson,et al.  Defect-free InP nanowires grown in [001] direction on InP (001) , 2004 .

[14]  Lars Samuelson,et al.  Single-electron transistors in heterostructure nanowires. , 2003 .

[15]  Takashi Fukui,et al.  Controlled growth of highly uniform, axial/radial direction-defined, individually addressable InP nanowire arrays , 2005 .

[16]  Takashi Fukui,et al.  Catalyst-free selective-area MOVPE of semiconductor nanowires on (111)B oriented substrates , 2004 .

[17]  Lars Samuelson,et al.  Solid-phase diffusion mechanism for GaAs nanowire growth , 2004, Microscopy and Microanalysis.

[18]  Lars Samuelson,et al.  Size-, shape-, and position-controlled GaAs nano-whiskers , 2001 .

[19]  J. Venables Atomic processes in crystal growth , 1994 .

[20]  Lars Samuelson,et al.  Failure of the vapor-liquid-solid mechanism in Au-assisted MOVPE growth of InAs nanowires. , 2005, Nano letters.

[21]  R. S. Wagner,et al.  VAPOR‐LIQUID‐SOLID MECHANISM OF SINGLE CRYSTAL GROWTH , 1964 .

[22]  Kiyoshi Takahashi,et al.  Growth of InAs Whiskers in Wurtzite Structure , 1966 .