The alkaline sodium sulphite reduction process for archaeological iron: a closer look

The alkaline sodium sulphite technique is one of the most successful for the treatment of archaeological iron but the mechanism by which it operates is rather different from that which has been assumed up to now. The chemistry of magnetite formation under reducing conditions is discussed, and experiments designed to confirm the mechanism are described. While treatment of freshly excavated material is most effective, the reason for the failure of the tech nique when artifacts have been allowed to dry out is explained. -- AATA -- AATA

[1]  B. Mcenaney,et al.  The reductive dissolution of γ-FeOOH in corrosion scales formed on cast iron in near-neutral waters , 1981 .

[2]  U. R. Evans,et al.  MECHANISM OF ATMOSPHERIC RUSTING , 1972 .

[3]  T. Misawa,et al.  The mechanism of atmospheric rusting and the effect of Cu and P on the rust formation of low alloy steels , 1971 .

[4]  G. Wranglén Pitting and sulphide inclusions in steel , 1974 .

[5]  V. Linnenbom The Reaction between lron and Water in the Absence of Oxygen , 1958 .

[6]  J. D. Bernal,et al.  The Oxides and Hydroxides of Iron and Their Structural Inter-Relationships , 1959 .

[7]  B. Mcenaney,et al.  The influence of dissolved oxygen concentration on the corrosion of grey cast iron in water at 50°C , 1979 .

[8]  J. Mayne,et al.  The breakdown of the air-formed oxide film on iron upon immersion in solutions of pH 6–13 , 1965 .

[9]  Joh.‐E. Hiller,et al.  Phasenumwandlungen im Rost , 1966 .

[10]  A. Mackay,et al.  β-Ferric Oxyhydroxide and Green Rust , 1959 .

[11]  T. Misawa,et al.  The mechanism of formation of iron oxide and oxyhydroxides in aqueous solutions at room temperature , 1974 .

[12]  D. L. Douglas,et al.  Stability of Ferrous Hydroxide Precipitates , 1956 .

[13]  D. Whittemore,et al.  Variations in the Stability of Precipitated Ferric Oxyhydroxides , 1971 .

[14]  Mark Gilberg,et al.  THE IDENTITY OF COMPOUNDS CONTAINING CHLORIDE IONS IN MARINE IRON CORROSION PRODUCTS: A CRITICAL REVIEW , 1981 .

[15]  B. Mcenaney,et al.  Corrosion of a cast iron boiler in a model central heating system , 1978 .

[16]  H. Weiser,et al.  x-Ray Studies on the Hydrous Oxides. V. Beta Ferric Oxide Monohydrate , 1935 .

[17]  H. Schwarz,et al.  Über die Wirkung des Magnetits beim atmosphärischen Rosten und beim Unterrosten von Anstrichen , 1972 .

[18]  G. Keller,et al.  Über Die dunkelgrünen Hydroxyverbindungen des Eisens , 1950 .

[19]  U. R. Evans,et al.  Evolution of Hydrogen from Ferrous Hydroxide , 1948, Nature.

[20]  Paul Keller,et al.  Vorkommen, Entstehung und Phasenumwandlung von β‐FeOOH in Rost , 1969 .

[21]  U. R. Evans The Economic Advantages of a Sound Painting Scheme , 1960 .

[22]  G. Schikorr Über die Reaktionen zwischen Eisen, Seinen Hydroxyden und Wasser , 1929 .

[23]  P. Keller Röntgenamorphe Phasen im Rost , 1971 .

[24]  Marcel Pourbaix,et al.  Some Applications of Potential‐pH Diagrams to the Study of Localized Corrosion , 1976 .