Gauche effect. Stereochemical consequences of adjacent electron pairs and polar bonds

[1]  H. Koch.  91. Absorption spectra and structure of organic sulphur compounds. Part II. Disulphides and polysulphides , 1949 .

[2]  M. T. Rogers,et al.  The Electric Moments of Some Aliphatic Peroxides, Disulfides and Diselenides , 1952 .

[3]  E. Nixon.  The Infrared Spectrum of Biphosphine , 1956 .

[4]  H. Brown,et al.  Steric Effects in Elimination Reactions. VII. The Effect of the Steric Requirements of Alkoxide Bases on the Direction of Bimolecular Elimination , 1956 .

[5]  L. Schmidt,et al.  Untersuchungen über Phosphorverbindungen. VIII. Das RAMAN‐Spektrum des Diphosphins , 1957 .

[6]  D. Swern,et al.  The Electric Moments of Crganic Peroxides. II. Aliphatic Peracids1 , 1958 .

[7]  Y. Murata,et al.  An Electron Diffraction Investigation on the Molecular Structure of Hydrazine , 1960 .

[8]  S. Rundqvist,et al.  The Crystal Structure of Hydrogen Peroxide Dihydrate. , 1960 .

[9]  F. Westheimer.  The Magnitude of the Primary Kinetic Isotope Effect for Compounds of Hydrogen and Deuterium. , 1961 .

[10]  Ralph G. Pearson,et al.  The Factors Determining Nucleophilic Reactivities , 1962 .

[11]  R. Jackson.  884. The microwave spectrum, structure, and dipole moment of dioxygen difluoride , 1962 .

[12]  L. Silbert.  Fatty peroxides: Synthesis, analysis, and reactions , 1962 .

[13]  Ernest L. Eliel,et al.  Stereochemistry of Carbon Compounds , 1962 .

[14]  D. Swern,et al.  Studies in the Structure of Organic Peroxides. , 1963 .

[15]  P. Garratt,et al.  The Cyclononatetraenyl Anion , 1963 .

[16]  T. Kasuya,et al.  Internal Motions of Hydrazine , 1963 .

[17]  S. Ōae,et al.  3d-orbital resonance in divalent sulphide—XIII , 1964 .

[18]  R. L. Kuczkowski.  The Mass and Microwave Spectra, Structures, and Dipole Moments of the Isomers of Sulfur Monofluoride , 1964 .

[19]  R. L. Klimisch,et al.  Preferential Formation of the cis Olefin in an E2 Elimination , 1965 .

[20]  D. Lide,et al.  Microwave Spectrum and Barrier to Internal Rotation in Methylsilylacetylene , 1965 .

[21]  R. Taylor,et al.  Fluorophosphine ligands. 3. Syntheses involving PF2I. The preparation and characterization of mu-oxo-bisdifluorophosphine, cyanodifluorophosphine, and tetrafluorodiphosphine. , 1966, Journal of the American Chemical Society.

[22]  R. Varma,et al.  Microwave Spectrum, Internal Barrier, Molecular Structure, and Dipole Moment of Disilanyl Fluoride , 1966 .

[23]  E. I. Snyder.  Studies in Magnetic Nonequivalence. A Model for Conformational Analysis of Acyclics from Spin-Coupling Constants , 1966 .

[24]  C. P. Lillya,et al.  Methylenebis(dialkylsulfonium) Salts , 1966 .

[25]  J. Coke,et al.  Hofmann elimination. I. An example of a cis E2 mechanism , 1967 .

[26]  W. Fink,et al.  Origin of Rotational Barriers. I. Many‐Electron Molecular Orbital Wavefunctions for Ethane, Methyl Alcohol, and Hydrogen Peroxide , 1967 .

[27]  G. Whitesides,et al.  Conformational Isomerism in 1-Substituted Derivatives of 3,3-Dimethylbutane , 1967 .

[28]  W. Fink,et al.  Internal Rotation Barriers for Hydrazine and Hydroxylamine from Ab Initio LCAO—MO—SCF Wavefunctions , 1967 .

[29]  J. Cornforth.  Olefin alkylation in biosynthesis. , 1968, Angewandte Chemie.

[30]  Manfred Winnewisser,et al.  Millimeter‐Wave Rotational Spectrum of HSSH and DSSD. I. Q Branches , 1968 .

[31]  D. Darwish,et al.  The preparation and racemization of an optically active sulfonium ylide. (-)-Ethylmethylsulfonium phenacylide , 1968 .

[32]  L. C. Allen.  Energy component analysis of rotational barriers , 1968 .

[33]  W. Green,et al.  Vibrational Spectra and Structure of Dimethyl Diselenide and Dimethyl Diselenide‐d6 , 1968 .

[34]  W. Ollis,et al.  Orbital symmetry control in the rearrangements of allylic sulphonium ylides , 1969 .

[35]  J. R. Wazer,et al.  Ab initio calculation of the barrier to internal rotation in propylene using a Guassian basis self-consistent field wave function , 1969 .

[36]  A. Veillard.  Distortional effects on the internal rotation in hydrogen peroxyde , 1969 .

[37]  J. Bunnett.  Olefin-Forming Elimination Reactions , 1969 .

[38]  R. J. Abraham,et al.  Rotational isomerism. Part VII. Effect of substituents on vicinal coupling constants in XCH2·CH2Y fragments , 1969 .

[39]  K. Mitchell.  Use of outer d orbitals in bonding , 1969 .

[40]  A. Rauk,et al.  The structure of an α-sulfonyl carbanion [29] , 1969 .

[41]  A. Rauk,et al.  A quantum mechanical study of proton exchange in sulfoxides with retention and inversion of configuration , 1969 .

[42]  S. Brois.  SECTION OF CHEMICAL SCIENCES: NITROGEN INVERSION IN AZIRIDINES* , 1969 .

[43]  J. D. Dunitz,et al.  Langsame Inversion am pyramidal gebundenen Stickstoff: Kristallstrukturanalyse des trans-N-Methoxy-3, 3-di-methoxycarbonyl-5-cyan-1, 2-oxazolidins , 1969 .

[44]  L. Chia,et al.  Conformation of 2,3-dicyano-2,3-dimethylbutane by electric dipole moment and Kerr effect measurements , 1969 .

[45]  A. Eschenmoser,et al.  Langsame Inversion am pyramidal gebundenen Stickstoff: Isolierung und Epimerisierung diastereomerer N‐Methoxy‐3,3‐di‐methoxycarbonyl‐5‐cyan‐1, 2‐oxazolidine. Vorläufige Mitteilung , 1969 .

[46]  P. Lansbury.  Stereochemistry and transannular reactions of 7,12-dihydropleiadenes , 1969 .

[47]  B. Munsch,et al.  Nitrogen inversion barriers and electronic structure of fluoramine and cyanamide: ab initio SCF–LCAO–MO study , 1970 .

[48]  M. Dewar,et al.  Barriers to rotation and nitrogen inversion in hydrazines , 1970 .

[49]  R. Bartsch,et al.  Reaction of 2-butyl halides with sodium ethoxide and 2,2,2-trifluoroethoxide. Evidence that orientation is not determined by the steric requirements of alkoxide bases. , 1970 .

[50]  Barrier to internal rotation in hydrogen persulphide , 1970 .

[51]  A. Rauk,et al.  On stabilization of pyramidal carbanionic centres by an adjacent sulphur 3d-orbital , 1970 .

[52]  R. R. Fraser,et al.  Assignments of configuration by nuclear Overhauser effects in some dibenzthiepin derivatives , 1970 .

[53]  J. McBride,et al.  .alpha.,.alpha.-Dichloroazoalkanes. II. Mechanism of stereospecific synthesis and substitution , 1970 .

[54]  F. Bordwell,et al.  Three types of base-initiated .beta.-elimination reactions involving carbanion intermediates , 1970 .

[55]  E. Clementi,et al.  Electronic Structure and Inversion Barrier of Ammonia , 1970 .

[56]  P. Corfield,et al.  Structure and stereochemical behavior of asymmetric .alpha.-sulfonyl carbanions , 1970 .

[57]  E. Eliel.  Conformational analysis in saturated heterocyclic compounds , 1970 .

[58]  O. Exner,et al.  Dipole moments and conformation of sulphinic acid esters , 1970 .

[59]  W. R. Jackson,et al.  The Stereochemistry of Aminophosphines , 1970 .

[60]  R. J. Abraham,et al.  Rotational isomerism. Part VIII. A calculation of the rotational barriers and rotamer energies of some halogenated compounds , 1970 .

[61]  Ronald J. Gillespie,et al.  The electron-pair repulsion model for molecular geometry , 1970 .

[62]  W. Tochtermann,et al.  Zur reaktivität diastereotoper substituenten am konformativ starren tetraphenyltribenzocycloheptatrien-system , 1970 .

[63]  R. Bartsch.  STEREOCHEMISTRY OF BASE-CATALYZED $beta$ ELIMINATION FROM 2-BROMOBUTANE. , 1971 .

[64]  E. Wagner.  Ab Initio versus CNDO barrier calculations , 1971 .

[65]  E. Wagner.  Ab Initio versus CNDO barrier calculations , 1971 .

[66]  W. J. Boyle,et al.  Kinetic isotope effects as guides to transition-state structures in deprotonation reactions , 1971 .

[67]  E. I. Snyder,et al.  elimination in 2-phenylethyl derivatives , 1971 .

[68]  W. Jennings,et al.  Barriers to nitrogen inversion in acyclic chloramines , 1971 .

[69]  G. Barbarella,et al.  Base‐Catalysed H‐D Exchange in 1 ‐Methylthiolanium Iodide , 1971 .

[70]  A. Rauk,et al.  A theoretical study of the Edward–Lemieux effect (the anomeric effect). The stereochemical requirements of adjacent electron pairs and polar bonds , 1971 .

[71]  I. Csizmadia,et al.  Stereochemical consequences of adjacent electron pairs. Theoretical study of rotation-inversion in ethylene dicarbanion , 1972 .