Memristors are widely used to construct multi-scroll/wing chaotic systems with complex dynamics. However, the generation of a multi-scroll/wing attractor is typically not induced by the memristor but depends on other nonlinear functions in the system, which does not take advantage of the unique features of the memristor for chaos-based applications. To address this issue, the present paper introduces a memristor coupling (MC) method to construct a novel memristive Sprott A system (MSAS) through coupling a flux-controlled memristor with multi-piecewise linear memductance into the chaotic Sprott A system. From theoretical analysis and numerical simulations, the MSAS is shown to be able to generate any number of multi-type hidden attractors, including multi-one-scroll, multi-double-scroll and multi-double-wing hidden attractors. In addition, it has two kinds of multistabilities, that is, heterogeneous multistability and homogeneous multistability. Based on these unique properties, different numbers of coexisting heterogeneous hidden attractors and coexisting homogeneous hidden attractors are derived respectively by switching the memristor initial states. These interesting dynamical properties are comprehensively investigated using nonlinear analysis tools. Furthermore, hardware experiments are implemented to demonstrate the feasibility of the MSAS and the effectiveness of the MC method. Finally, a new pseudo-random number generator (PRNG) is proposed to explore the practical applications of the MSAS. Performance evaluation results verify the high-quality randomness of the designed PRNG.